journal article·2020-03-13

Understanding Photoelectrochemical Water Oxidation with X-ray Absorption Spectroscopy

Jiujun Deng, Qingzhe Zhang, Xiaoxin Lv, Duo Zhang, Hui Xu, Dongling Ma, Jun Zhong

ACS Energy Letters· Volume 5· Issue 3
Publisher page

Abstract

Synchrotron radiation-based X-ray absorption spectroscopy (XAS) has been demonstrated to be a powerful and effective characterization tool in comprehensively and deeply understanding the photoelectrochemical (PEC) water-splitting process owing to its unique capability in probing the electronic structure changes of photoelectrodes. In this Review, we present the most recent achievements in the past few years of synchrotron XAS techniques for the advanced investigation of hematite and other commonly used photoanodes. By focusing on the unique and powerful roles that XAS played in identifying the chemical compositions and exploring the working mechanism of various photoanodes, we will provide an in-depth understanding on how the XAS technique can guide the design of efficient photoanodes and contribute to the further development of PEC water splitting. The Review is also expected to stimulate more interest from the PEC community in general for taking advantage of XAS to facilitate their research.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Iron oxide chemistry and applications · Advanced Photocatalysis Techniques · Mine drainage and remediation techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China

Institut National de la Recherche Scientifique (INRS), Centre Énergie Materiaux et TÉlÉcommunications, 1650 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S2, Canada

Automotive Engineering Research Institute, Jiangsu University, Zhenjiang 212013, China

State Key Laboratory of Radiation Medicine and Protection, School of Radiation Medicine and Protection, Soochow University, Suzhou 215123, China

Institute of Functional Nano and Soft Materials Laboratory (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China

Funding

Suzhou University of Science and Technology · Jiangsu University · China Postdoctoral Science Foundation · Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada · National Natural Science Foundation of China

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