journal article·2019-02-08

In-Operando Study of the Effects of Solvent Additives on the Stability of Organic Solar Cells Based on PTB7-Th:PC71BM

Dan Yang, Franziska C. Löhrer, Volker Körstgens, Armin Schreiber, Sigrid Bernstorff, Jillian M. Buriak, Peter Müller-Buschbaum

ACS Energy Letters· Volume 4· Issue 2
Publisher page

Abstract

Degradation of organic solar cells is among the fundamental problems that hinder their successful breakthrough. We probe in-operando the degradation behavior of organic solar cells based on the high-efficiency low-bandgap benzodithiophene copolymer PTB7-Th and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). The influence of the solvent additives 1,8-diiodooctane and o-chlorobenzaldehyde on the degradation mechanism is studied with in situ grazing incidence small-angle X-ray scattering during operation. Changes in the IV characteristics are correlated for the first time in situ with changes in the morphology showing that the use of a solvent additive causes a change in device degradation.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Lehrstuhl für Funktionelle Materialien, Physik-Department, Technische Universität München, James-Franck-Strasse 1, 85748 Garching, Germany

Elettra-Sincrotrone Trieste S.C.p.A., Strada Statale 14 km 163.5, AREA Science Park, Basovizza, 34149 Trieste, Italy

Department of Chemistry, University of Alberta, Edmonton, AB T6G 2G2, Canada

Heinz Maier-Leibnitz Zentrum (MLZ), Technische Universität München, Lichtenbergstrasse 1, 85748 Garching, Germany

Funding

Deutsche Forschungsgemeinschaft · Center for NanoScience, Ludwig-Maximilians-Universit?t M?nchen · Bayerisches Staatsministerium f?r Bildung und Kultus, Wissenschaft und Kunst · China Scholarship Council · Canada First Research Excellence Fund

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