Honeycomb-Ordered Na₃Ni_{1.5}M_{0.5}BiO₆ (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries

Peng-Fei Wang; Yu-Jie Guo; Hui Duan; Tong-Tong Zuo; Enyuan Hu; Klaus Attenkofer; Hongliang Li; Xiu Song Zhao; Ya-Xia Yin; Xiqian Yu; Yu-Guo Guo

doi:10.1021/acsenergylett.7b00930

journal article·2017-12-08Open access

Honeycomb-Ordered Na₃Ni_1.5M_0.5BiO₆ (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries

Peng-Fei Wang, Yu-Jie Guo, Hui Duan, Tong-Tong Zuo, Enyuan Hu, Klaus Attenkofer, Hongliang Li, Xiu Song Zhao, Ya-Xia Yin, Xiqian Yu, Yu-Guo Guo

ACS Energy Letters· Volume 2· Issue 12

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Source abstract

Abstract

Developing high-voltage layered cathodes for sodium-ion batteries (SIBs) has always been a severe challenge. Herein, a new family of honeycomb-layered Na 3 Ni 1.5 M 0.5 BiO 6 (M = Ni, Cu, Mg, Zn) with a monoclinic superstructure has been shown to combine good Na + (de)intercalation activity with a competitive 3.3 V high voltage. By coupling the electrochemical process with ex situ X-ray absorption spectroscopy as well as in situ X-ray diffraction, the charge compensation mechanism and structural evolution of these new cathodes are clearly investigated. Interestingly, both Ni 2+ /Ni 3+ and Cu 2+ /Cu 3+ participate in the redox reaction upon cycling, and the succession of single-phase, two-phase, or three-phase regions upon Na + extraction/insertion were identified with rather good accuracy. This research strategy could provide insights into the structure–function–property relationships on a new series of honeycomb-ordered materials with the general formula Na 3 Ni 1.5 M 0.5 BiO 6 and also serve as a bridge to guide future design of high-performance cathodes for SIBs.

Source: openalex_inverted_index · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China

University of Chinese Academy of Sciences, Beijing 100049, China

Brookhaven National Laboratory, Upton, New York 11973, United States

Institute of Materials for Energy and Environment, Laboratory of New Fiber Materials and Modern Textile, Growing Basis for State Key Laboratory, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences (CAS), Beijing 100190, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Chinese Academy of Sciences

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