Crystalline LiPON as a Bulk-Type Solid Electrolyte
Source abstract
Abstract
In this work, a new bulk Li3.6PO3.4N0.6 crystalline polymorph has been prepared from low-cost precursors, following a simple ball-milling procedure. The densified powder exhibits a conductivity of 5.0 × 10–6 S cm–1 at 70 °C and an electrochemical stability allowing operation with high-voltage materials up to 5.0 V vs Li/Li+. Stripping and plating of lithium in a symmetric cell demonstrates the forthcoming bulk application of LiPON in electrochemical devices. Widening the use of lithium phosphorus oxynitride compositions to bulk solid-state batteries will have relevant implications because of its unique compatibility with both high-voltage electroactive materials and lithium metal and its low density.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Inorganic Chemistry and Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Center for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Parque Tecnológico de Álava, Albert Einstein, 48, 01510 Vitoria-Gasteiz, Spain
Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, 50-422 Wrocław, Poland
IKERBASQUE, Basque Foundation for Science, María Díaz de Haro 3, 48013 Bilbao, Spain
Funding
Ministry of Science, Innovation and Universities
References (39)
Show source-provided references
1. 10.1149/1.183744310.1149/1.1837443 ↗
2. 10.1016/0378-7753(93)80106-Y10.1016/0378-7753(93)80106-Y ↗
3. 10.1016/0167-2738(92)90442-R10.1016/0167-2738(92)90442-R ↗
4. 10.1002/aenm.20100000210.1002/aenm.201000002 ↗
5. 10.1016/j.jpowsour.2014.10.20210.1016/j.jpowsour.2014.10.202 ↗
6. 10.1016/j.jpowsour.2018.04.02210.1016/j.jpowsour.2018.04.022 ↗
7. 10.1038/s41560-017-0047-210.1038/s41560-017-0047-2 ↗
8. 10.1002/adma.20187012210.1002/adma.201870122 ↗
9. 10.1016/j.jpowsour.2018.02.06210.1016/j.jpowsour.2018.02.062 ↗
10. 10.1038/nenergy.2016.14110.1038/nenergy.2016.141 ↗
11. 10.2139/ssrn.364083710.2139/ssrn.3640837 ↗
12. 10.1038/s41467-020-19004-410.1038/s41467-020-19004-4 ↗
13. 10.1149/1.139322610.1149/1.1393226 ↗
14. 10.1016/S0167-2738(00)00327-110.1016/S0167-2738(00)00327-1 ↗
15. 10.1016/j.materresbull.2007.08.03110.1016/j.materresbull.2007.08.031 ↗
16. 10.1021/acs.jpclett.5b0181410.1021/acs.jpclett.5b01814 ↗
17. 10.1039/C8SE00273H10.1039/C8SE00273H ↗
18. 10.1038/s41560-019-0384-410.1038/s41560-019-0384-4 ↗
19. 10.1016/j.electacta.2017.08.13010.1016/j.electacta.2017.08.130 ↗
20. 10.1006/jssc.1995.114010.1006/jssc.1995.1140 ↗
21. 10.1016/j.ssi.2012.12.01310.1016/j.ssi.2012.12.013 ↗
22. 10.1016/0022-4596(82)90400-510.1016/0022-4596(82)90400-5 ↗
23. 10.1007/s11581-016-1643-z10.1007/s11581-016-1643-z ↗
24. 10.1149/1.212918010.1149/1.2129180 ↗
25. 10.1016/j.actamat.2012.10.03410.1016/j.actamat.2012.10.034 ↗
26. 10.1016/0022-3093(94)00665-210.1016/0022-3093(94)00665-2 ↗
27. 10.1021/jacs.8b0519210.1021/jacs.8b05192 ↗
28. 10.1023/A:102398683104910.1023/A:1023986831049 ↗
29. 10.1111/j.1551-2916.2010.03924.x10.1111/j.1551-2916.2010.03924.x ↗
30. 10.3389/fenrg.2016.0002810.3389/fenrg.2016.00028 ↗
31. 10.1006/jssc.1995.114010.1006/jssc.1995.1140 ↗
32. 10.1016/j.jpowsour.2003.08.03010.1016/j.jpowsour.2003.08.030 ↗
33. 10.1016/S0378-7753(00)00427-410.1016/S0378-7753(00)00427-4 ↗
34. Visco, S. J.; Chu, M.Y. Protective Coatings for Negative Electrodes. U.S. Patent No. US6025094A, Feb. 15, 2000.
35. 10.1039/C7TA07928A10.1039/C7TA07928A ↗
36. 10.1002/aenm.20140140810.1002/aenm.201401408 ↗
37. 10.1038/s41563-019-0431-310.1038/s41563-019-0431-3 ↗
38. 10.1016/j.jpowsour.2018.06.09610.1016/j.jpowsour.2018.06.096 ↗
39. 10.1021/acsami.6b0083110.1021/acsami.6b00831 ↗