Realizing High Volumetric Lithium Storage by Compact and Mechanically Stable Anode Designs
Source abstract
Abstract
With the continuing demand for the minimization of electrochemical energy storage devices, the volumetric performance has become equally important as the gravimetric metrics for rechargeable batteries used in limited spaces. High-capacity anode materials promise to significantly improve the volumetric performance of lithium-ion batteries, but the issues of nanosizing and mechanical instability induced by their large volume changes during cycling generally prevent their practical use. In this Perspective, we focus on the importance of mechanical stability designs and highlight internal densification as an ideal solution for the large-volume-change anode nanomaterials to achieve both good gravimetric and volumetric performance. We discuss the strategies based on the use of carbons in high-density material construction, precise void preservation, and stress management to address the mechanical instability issues in terms of materials, electrodes, and devices. Finally, future ways of solving these issues with compact lithium storage are suggested.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology; Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
School of Marine Science and Technology, Tianjin University, Tianjin 300072, China
Beijing Advanced Innovation Center for Materials Genome Engineering, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207, China
Funding
National Natural Science Foundation of China
References (72)
Show source-provided references
1. 10.1038/451652a10.1038/451652a ↗
2. 10.1007/s11426-019-9610-310.1007/s11426-019-9610-3 ↗
3. 10.1016/j.joule.2019.03.02810.1016/j.joule.2019.03.028 ↗
4. 10.1002/adma.20180056110.1002/adma.201800561 ↗
5. 10.1039/C5EE00389J10.1039/C5EE00389J ↗
6. 10.1038/s41560-019-0338-x10.1038/s41560-019-0338-x ↗
7. 10.1002/cey2.1010.1002/cey2.10 ↗
8. 10.1038/s41565-019-0371-810.1038/s41565-019-0371-8 ↗
9. 10.1002/adma.20180119010.1002/adma.201801190 ↗
10. 10.1126/science.121300310.1126/science.1213003 ↗
11. 10.1038/natrevmats.2016.1310.1038/natrevmats.2016.13 ↗
12. 10.1039/C8CS00426A10.1039/C8CS00426A ↗
13. 10.1021/acsenergylett.6b0059410.1021/acsenergylett.6b00594 ↗
14. 10.1126/science.aba916810.1126/science.aba9168 ↗
15. 10.1021/acsenergylett.8b0243310.1021/acsenergylett.8b02433 ↗
16. 10.1038/nenergy.2017.9110.1038/nenergy.2017.91 ↗
17. 10.1016/j.joule.2019.01.00510.1016/j.joule.2019.01.005 ↗
18. 10.1038/s41578-019-0166-410.1038/s41578-019-0166-4 ↗
19. 10.1038/nnano.2014.610.1038/nnano.2014.6 ↗
20. 10.1007/s41918-018-0001-410.1007/s41918-018-0001-4 ↗
21. 10.1149/1.139089910.1149/1.1390899 ↗
22. 10.1038/nenergy.2016.7110.1038/nenergy.2016.71 ↗
23. 10.1007/s41918-018-0006-z10.1007/s41918-018-0006-z ↗
24. 10.1002/adma.20180086310.1002/adma.201800863 ↗
25. 10.1016/j.ensm.2015.10.00210.1016/j.ensm.2015.10.002 ↗
26. 10.1002/cey2.210.1002/cey2.2 ↗
27. 10.1021/acs.nanolett.8b0306510.1021/acs.nanolett.8b03065 ↗
28. 10.1039/C6EE02685K10.1039/C6EE02685K ↗
29. 10.1002/adma.20170571310.1002/adma.201705713 ↗
30. 10.1002/advs.20180235510.1002/advs.201802355 ↗
31. 10.1038/nchem.180210.1038/nchem.1802 ↗
32. 10.1002/cey2.1210.1002/cey2.12 ↗
33. 10.1016/j.nanoen.2012.02.00410.1016/j.nanoen.2012.02.004 ↗
34. 10.1021/acsenergylett.7b0028610.1021/acsenergylett.7b00286 ↗
35. 10.1016/j.ensm.2016.09.00510.1016/j.ensm.2016.09.005 ↗
36. 10.1002/aenm.20160148110.1002/aenm.201601481 ↗
37. 10.1038/srep0297510.1038/srep02975 ↗
38. 10.1002/adma.20150415110.1002/adma.201504151 ↗
39. 10.1007/s40843-019-1227-710.1007/s40843-019-1227-7 ↗
40. 10.1002/adfm.20190031110.1002/adfm.201900311 ↗
41. 10.1038/s41467-017-02808-210.1038/s41467-017-02808-2 ↗
42. 10.1039/C6EE00941G10.1039/C6EE00941G ↗
43. 10.1002/aenm.20190007910.1002/aenm.201900079 ↗
44. 10.1038/s41578-018-0069-910.1038/s41578-018-0069-9 ↗
45. 10.1002/aenm.20190145710.1002/aenm.201901457 ↗
46. 10.1021/acsenergylett.8b0111410.1021/acsenergylett.8b01114 ↗
47. 10.1016/j.ensm.2019.01.02010.1016/j.ensm.2019.01.020 ↗
48. 10.1002/cey2.810.1002/cey2.8 ↗
49. 10.1038/s41467-018-05398-910.1038/s41467-018-05398-9 ↗
50. 10.1002/aenm.20190215010.1002/aenm.201902150 ↗
51. 10.1126/science.aal437310.1126/science.aal4373 ↗
52. 10.1021/acsenergylett.9b0081510.1021/acsenergylett.9b00815 ↗
53. 10.1021/acsnano.8b0808810.1021/acsnano.8b08088 ↗
54. 10.1021/jacs.8b0069310.1021/jacs.8b00693 ↗
55. 10.1038/s41467-019-08383-y10.1038/s41467-019-08383-y ↗
56. 10.1038/s41560-019-0398-y10.1038/s41560-019-0398-y ↗
57. 10.1021/nn505410q10.1021/nn505410q ↗
58. 10.1038/s41467-019-10289-810.1038/s41467-019-10289-8 ↗
59. 10.1021/acsenergylett.8b0082910.1021/acsenergylett.8b00829 ↗
60. 10.1038/s41467-019-09510-510.1038/s41467-019-09510-5 ↗
61. 10.1002/adma.20190097010.1002/adma.201900970 ↗
62. 10.1002/aenm.20180264510.1002/aenm.201802645 ↗
63. 10.1002/anie.20190370910.1002/anie.201903709 ↗
64. 10.1021/acsenergylett.9b0251410.1021/acsenergylett.9b02514 ↗
65. 10.1038/s41565-019-0604-x10.1038/s41565-019-0604-x ↗
66. 10.1021/acsenergylett.8b0190410.1021/acsenergylett.8b01904 ↗
67. 10.1002/cey2.2110.1002/cey2.21 ↗
68. 10.1038/nenergy.2016.9910.1038/nenergy.2016.99 ↗
69. 10.1038/s41586-018-0109-z10.1038/s41586-018-0109-z ↗
70. 10.1038/nenergy.2016.9710.1038/nenergy.2016.97 ↗
71. 10.1038/s41586-018-0347-010.1038/s41586-018-0347-0 ↗
72. 10.1038/s41560-019-0405-310.1038/s41560-019-0405-3 ↗