FORMATION OF CORNCOB CELLULOSE FIBER WITH UNIFORM MORPHOLOGY IN ELECTROSPINNING BY USING Cu(OAc)2 AND METHYL HEXADECANOATE

Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China; HAINING NA; HAIZHEN CHEN; "School of Fashion, Zhejiang Fashion Institute of Technology, Ningbo, Zhejiang, 315211, China"; YUHONG TAO; Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China; JUNCHENG HUANG; Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China; FEI LIU; Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China; JIN ZHU; Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China

doi:10.35812/cellulosechemtechnol.2022.56.49

journal article·2022-06-21Open access

FORMATION OF CORNCOB CELLULOSE FIBER WITH UNIFORM MORPHOLOGY IN ELECTROSPINNING BY USING Cu(OAc)2 AND METHYL HEXADECANOATE

Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China, HAINING NA, HAIZHEN CHEN, "School of Fashion, Zhejiang Fashion Institute of Technology, Ningbo, Zhejiang, 315211, China", YUHONG TAO, Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China, JUNCHENG HUANG, Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China, FEI LIU, Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China, JIN ZHU, Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China

Cellulose Chemistry and Technology· Volume 56· Issue 5-6

Publisher page Open full text

Source abstract

Abstract

"Ultrafine corncob cellulose fibers with uniform morphology were electrospun, in the presence of Cu(OAc)2 and methyl hexadecanoate in the spinning solution. After adding Cu(OAc)2, both the conductivity of the solution and the chain entanglement of cellulose were controlled to impact the morphology of electrospun cellulose fibers. Uniform diameter distribution can be only obtained under proper conditions (namely, the concentration of Cu(OAc)2 of 0.1%). Then, methyl hexadecanoate was further used to reduce the chain entanglement of cellulose in the solution. Electrospun cellulose fibers with the diameters around ~500 nm and uniform diameter distribution were finally obtained. The use of organic salts and single functional group contained additive provides a feasible and important method to control fiber methodology of cellulose via electrospinning."

Source: crossref · Quality: baseline

Research context

OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Advanced Cellulose Research Studies · Silk-based biomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references

1. "1 J. A. Melero, J. Iglesias and A. Garcia, Energ. Environ. Sci., 5, 7393 (2012), https://doi.org/10.1039/c2ee21231e10.1039/c2ee21231e ↗

2. 2 H. Shaghaleh, X. Xu and S. F. Wang, RSC Adv., 8, 825 (2018), https://doi.org/10.1039/c7ra11157f10.1039/C7RA11157F ↗

3. 3 D. Klemm, B. Heublein, H. P. Fink and A. Bohn, Angew. Chem. Int. Edit., 44, 3358 (2005), https://doi.org/10.1002/anie.20046058710.1002/anie.200460587 ↗

4. 4 J. J. Xue, T. Wu, Y. Q. Dai and Y. N. Xia, Chem. Rev., 119, 5298 (2019), https://doi.org/10.1021/acs.chemrev.8b0059310.1021/acs.chemrev.8b00593 ↗

5. 5 R. A. Razali, Y. Lokanathan, S. R. Chowdhury, A. Saim and R. H. Idrus, Sains Malays., 47, 1787 (2018), https://doi.org/10.17576/jsm-2018-4708-1710.17576/jsm-2018-4708-17 ↗

6. 6 D. Lv, M. M. Zhu, Z. C. Jiang, S. H. Jiang, Q. L. Zhang et al., Macromol. Mater. Eng., 3, 1800336 (2018), https://doi.org/10.1002/mame.20180033610.1002/mame.201800336 ↗

7. 7 B. Sun, Y. Z. Long, H. D. Zhang, M. M. Li, J. L. Duvail et al., Prog. Polym. Sci., 39, 862 (2014), https://doi.org/10.1016/j.progpolymsci.2013.06.00210.1016/j.progpolymsci.2013.06.002 ↗

8. 8 J. Yoon, H. S. Yang, B. S. Lee and W. R. Yu, Adv. Mater., 30, 1704765 (2018), https://doi.org/10.1002/adma.20170476510.1002/adma.201704765 ↗

9. 9 K. B. R. Teodoro, R. C. Sanfelice, F. L. Migliorini, A. Pavinatto, M. H. M. Facure et al., ACS Sensors, 6, 2473 (2021), https://doi.org/10.1021/acssensors.1c0047310.1021/acssensors.1c00473 ↗

10. 10 C. W. Kim, D. S. Kim, S. Y. Kang, M. Marquez and Y. L. Joo, Polymer, 47, 5097 (2006), https://doi.org/10.1016/j.polymer.2006.05.03310.1016/j.polymer.2006.05.033 ↗

11. 11 A. Frenot, M. W. Henriksson and P. Walkenström, J. Appl. Polym. Sci., 103, 1473 (2007), https://doi.org/10.1002/app.2491210.1002/app.24912 ↗

12. 12 R. P. Swatloski, S. K. Spear, J. D. Holbrey and R. D. Rogers, J. Am. Chem. Soc., 124, 4974 (2002), https://doi.org/10.1021/ja025790m10.1021/ja025790m ↗

13. 13 M. W. Frey, Polym. Rev., 48, 378 (2008), https://doi.org/10.1080/1558372080202228110.1080/15583720802022281 ↗

14. 14 J. Cai, L. Zhang, S. L. Liu, Y. T. Liu, X. J. Xu et al., Macromolecules, 41, 9345 (2008), https://doi.org/10.1021/ma801110g10.1021/ma801110g ↗

15. 15 H. Z. Chen, J. P. Ni, J. Chen, W. W. Xue, J. G. Wang et al., Carbonhyd. Polym., 123, 174 (2015), https://doi.org/10.1016/j.carbpol.2015.01.02310.1016/j.carbpol.2015.01.023 ↗

16. 16 H. Z. Chen, J. Chen, N. Teng, H. N. Na and J. Zhu, Cellulose, 24, 863 (2017), https://doi.org/10.1007/s10570-016-1127-310.1007/s10570-016-1127-3 ↗

17. 17 J. Kerwald, C. F. de Moura, E. D. Freitas, J. D. P. D. Segundo, R. S. Vieira et al., Cellulose, 29, 25 (2021), https://doi.org/10.1007/s10570-021-04303-w10.1007/s10570-021-04303-w ↗

18. 18 S. L. Quan, S. G. Kang and I. J. Chin, Cellulose, 17, 223 (2010), https://doi.org/10.1007/s10570-009-9386-x10.1007/s10570-009-9386-x ↗

19. 19 Y. Ahn, D. H. Hu, J. H. Hong, S. H. Lee, H. J. Kim et al., Carbohyd. Polym., 89, 340 (2012), https://doi.org/10.1016/j.carbpol.2012.03.00610.1016/j.carbpol.2012.03.006 ↗

20. 20 P. Gupta, C. Elkins, T. E. Long and G. L. Wilkes, Polymer, 46, 4799 (2005), https://doi.org/10.1016/j.polymer.2005.04.02110.1016/j.polymer.2005.04.021 ↗

21. 21 Y. H. Wei, S. Chen, B. Kowalczyk, S. Huda, T. P. Gray et al., J. Phys. Chem. C, 114, 15612 (2010), https://doi.org/10.1021/jp105568310.1021/jp1055683 ↗

22. 22 J. Demuynck, A. Veillard and U. Wahlgren, J. Am. Chem. Soc., 3, 5563 (1973), https://doi.org/10.1021/ja00798a02210.1021/ja00798a022 ↗

23. 23 M. Sharnoff, J. Chem. Phys., 42, 3383 (1965), https://doi.org/10.1063/1.169726310.1063/1.1697263 ↗

24. 24 X. F. Sun, R. C. Sun, J. Tomkinson and M. S. Baird, Polym. Degrad. Stabil., 83, 47 (2004), https://doi.org/10.1016/S0141-3910(03)00205-210.1016/S0141-3910(03)00205-2 ↗

25. 25 N. Teng, J. P. Ni, H. Z. Chen, Q. H. Ren, H. N. Na et al., ACS Sustain. Chem. Eng., 4, 1507 (2016), https://doi.org/10.1021/acssuschemeng.5b0146410.1021/acssuschemeng.5b01464 ↗

26. "