journal article·2024-09-13Open access

CO2 Electrolysis Technologies: Bridging the Gap toward Scale-up and Commercialization

Blanca Belsa, Lu Xia, F. Pelayo García de Arquer

ACS Energy Letters· Volume 9· Issue 9

Abstract

High Resolution Image Download MS PowerPoint Slide CO 2 electroreduction (CO 2 E) converts CO 2 into carbon-based fuels and chemical feedstocks that can be integrated into existing chemical processes. After decades of research, CO 2 E is approaching commercialization with several startups, pilot plants, and large initiatives targeting different products. Here, we analyze the global efforts in scaling up CO 2 E, addressing implementation challenges and proposing methods for acceleration. We present a comparative analysis of key performance indicators (KPIs) between laboratory and industrial settings and suggest a stepwise technoeconomic analysis (TEA) framework, supported by industrial data, exploiting interactions within the academic and industrial communities. We identify the lack of systems-oriented standardization and durability as the main bottlenecks slowing down progress in the lab-to-prototype-to-market pathway of CO 2 E technologies. Inspired by electrolysis and fuel cell technologies, we outline protocols to advance fundamental research and aid catalyst development progress in performance, upscaling, and technology readiness level of CO 2 E.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Carbon dioxide utilization in catalysis · Carbon Dioxide Capture Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

The Barcelona Institute of Science and Technology, ICFO - Institut de Ciències Fotòniques, Castelldefels, Barcelona 08860, Spain

Funding

Ministerio de Ciencia e Innovaci?n · 'la Caixa' Foundation · H2020 Marie Sklodowska-Curie Actions · Generalitat de Catalunya · European Social Fund Plus · H2020 European Research Council · Fundaci? Mir-Puig · Fundaci? Cellex

References (100+)

Show source-provided references
1. IRENA · 2020
2. IRENA · 2020
3. 10.1038/s41586-019-1681-610.1038/s41586-019-1681-6 ↗
4. International Energy Agency · 2020
5. 10.1038/s41467-019-13638-910.1038/s41467-019-13638-9 ↗
6. 10.1016/j.biombioe.2012.12.01910.1016/j.biombioe.2012.12.019 ↗
7. 10.3389/fenrg.2020.0011110.3389/fenrg.2020.00111 ↗
8. 10.1039/D0CS00597E10.1039/D0CS00597E ↗
9. 10.1039/D0CS00230E10.1039/D0CS00230E ↗
10. 10.1016/j.actaastro.2009.03.05810.1016/j.actaastro.2009.03.058 ↗
11. 10.1021/acsenergylett.0c0224910.1021/acsenergylett.0c02249 ↗
12. Annual Ethanol Production. https://ethanolrfa.org/markets-and-statistics/annual-ethanol-production (accessed 2021-12-14).
13. 10.1021/cen-09909-feature310.1021/cen-09909-feature3 ↗
14. 10.1016/j.rser.2021.11150210.1016/j.rser.2021.111502 ↗
15. 10.1016/j.gloenvcha.2020.10219410.1016/j.gloenvcha.2020.102194 ↗
16. 10.1126/science.aay421710.1126/science.aay4217 ↗
17. 10.1038/s41565-020-00823-x10.1038/s41565-020-00823-x ↗
18. About Sunfire: Renewables Everywhere. https://www.sunfire.de/en/about-us (accessed 2021-12-14).10.1016/S1464-2859(21)00573-3 ↗
19. eCOs - CO from CO2. Topsoe. https://www.topsoe.com/our-resources/knowledge/our-products/equipment/ecos-co-from-co2 (accessed 2021-12-30).
20. Mittal C. · Chem. Eng. World · 2017 · 52 · 44
21. Ravn, S. DeLille Oxygen Co leases two eCOs units for cost-competitive onsite CO production. Topsoe, 2019. https://blog.topsoe.com/delille-oxygen-co.leases-two-ecos-units-for-cost-competitive-onsite-co-production (accessed 2021-12-30).
22. 10.1149/1945-7111/ab709910.1149/1945-7111/ab7099 ↗
23. Nørskov J. K. · 2019
24. 10.3389/fchem.2018.0026310.3389/fchem.2018.00263 ↗
25. Twelve. https://www.twelve.co/ (accessed 2021-12-30).
26. SoCalGas. SoCalGas RD&D & Opus 12 present: “Utilization of CO2 emissions to make renewable fuels & chemicals”. YouTube. https://www.youtube.com/watch?app=desktop&v=ZLSltwMp3Vs (accessed 2021-12-22).10.1016/S1464-2859(21)00043-2 ↗
27. Avantium. https://www.avantium.com/ (accessed 2023-07-27).
28. Gruter, G.J. In Innovation Management (choosing options) both from Industrial and Academic Perspective; 2020. http://www.elcorel.org/files/Aventium/GRUTER%20Avantium%20ELCOREL%20INNOVATION%20MANAGEMENT%2014%20Oct%202020%20PART%201.pdf (accessed 2021-12-22).
29. Siemens Energy. https://www.siemens-energy.com/global/en.html (accessed 2023-07-27).
30. About Us. VoltaChem. https://www.voltachem.com/voltachem (accessed 2023-07-25).
31. Power-2-Chemicals. VoltaChem. https://www.voltachem.com/research/power-2-chemicals (accessed 2022-01-03).
32. eChemicles - Electrolysis for a Better Tomorrow! https://echemicles.com/ (accessed 2023-11-27).
33. 10.1021/acsenergylett.3c0244610.1021/acsenergylett.3c02446 ↗
34. 10.1021/acs.accounts.1c0061410.1021/acs.accounts.1c00614 ↗
35. DNV. https://www.dnv.com/ (accessed 2023-07-27).
36. 2011
37. Rode, E.; Agarwal, A.; Sridhar, N. In Renewable feedstocks supplying the petrochemical industry; NARA, Seattle, WA, USA, 2016.
38. Halliburton Labs. OCOChem Spotlight. YouTube. https://www.youtube.com/watch?v=KhwmyNgkOvc (accessed 2022-01-03).
39. CO2 Utilisation: Power-2-Formic Acid. VoltaChem. https://www.voltachem.com/projects/co2-utilisation-power-2-formid-acid (accessed 2023-07-25).
40. Driving on CO2: VoltaChem scales up sustainable production of formic acid. VoltaChem. https://www.voltachem.com/news/driving-on-co2-voltachem-scales-up-sustainable-production-of-formic-acid (accessed 2022-01-03).
41. Pilot for synthesis of formic acid from CO2 at Twence waste incineration site. VoltaChem. https://www.voltachem.com/news/pilot-for-synthesis-of-formic-acid-from-co2-at-twence-waste-incineration-site (accessed 2022-01-03).
42. Opus 12 and SoCalGas simplify conversion of CO2 into storable renewable energy. JWN Energy. https://www.renewco2.com/chemical-products (accessed 2022-01-10).
43. CO2-based electrosynthesis of ethylene oXIDE | CO2EXIDE Project. European Commission. https://cordis.europa.eu/project/id/768789 (accessed 2022-01-05).
44. Tzekova, E. Toronto-based XPRIZE Finalist shows how to turn carbon emissions into renewable fuel. TAF, 2018. https://taf.ca/toronto-xprize-finalist-turn-carbon-emissions-renewable-fuel/(accessed 2022-01-05).
45. CERT. XPRIZE. https://carbon.xprize.org/prizes/carbon/teams/cert (accessed 2022-01-05).
46. 10.1021/acsenergylett.3c0062010.1021/acsenergylett.3c00620 ↗
47. 10.1021/acssuschemeng.3c0437310.1021/acssuschemeng.3c04373 ↗
48. 10.1038/s41929-021-00707-w10.1038/s41929-021-00707-w ↗
49. About us | Dioxycle. https://dioxycle.com/about-us/ (accessed 2023-06-26).
50. Chemicals ─ RenewCO2. https://www.rngcoalition.com/news/2018/4/26/opus-12-socalgas-simplify-conversion-of-co2-into-storable-renewable-energy (accessed 2022-01-05).
51. RenewCO2 Electrolyzer Recycles CO2 waste and helps fight climate change. Chain Reaction Innovations. https://chainreaction.anl.gov/renewco2-electrolyzer-recycles-co2-waste-and-helps-fight-climate-change/ (accessed 2022-01-04).
52. Carbon Corp. https://carboncorp.org/ (accessed 2023-07-27).
53. 10.1021/acs.accounts.9b0040510.1021/acs.accounts.9b00405 ↗
54. 10.1016/j.mtsust.2019.10002310.1016/j.mtsust.2019.100023 ↗
55. Prometheus Fuels. https://www.prometheusfuels.com/on-the-road/meet-our-v3-faraday-reactor (accessed 2022-01-04).
56. 10.1016/j.joule.2020.01.00210.1016/j.joule.2020.01.002 ↗
57. Service, R. F. This former playwright aims to turn solar and wind power into gasoline. Science, 2019. 10.1126/science.aay5994.10.1126/science.aay5994 ↗
58. P2X: Utilising electricity for follow-on products - for example for eFuels. Kopernikus-Projekte. https://www.kopernikus-projekte.de/en/projects/p2x (accessed 2021-12-30).
59. Doyle, A. Integrated power-to-liquid test facility produces first fuel. The Chemical Engineer. https://www.thechemicalengineer.com/news/integrated-power-to-liquid-test-facility-produces-first-fuel/ (accessed 2021-12-30).
60. Dioxide Materials and LanzaTech. https://arpa-e.energy.gov/technologies/scaleup-launch-pad-2020/dioxide-materials-and-lanzatech (accessed 2021-12-30).
61. 10.1038/s41929-017-0005-110.1038/s41929-017-0005-1 ↗
62. 10.1021/acs.iecr.0c0584810.1021/acs.iecr.0c05848 ↗
63. 10.1021/acs.iecr.8b0634010.1021/acs.iecr.8b06340 ↗
64. The VoltaChem Delft facilities: fully equipped for dedicated electrochemistry research. VoltaChem. https://www.voltachem.com/news/the-voltachem-delft-facilities-fully-equipped-for-dedicated-electrochemistry-research (accessed 2022-01-03).
65. 10.1016/j.rser.2018.01.00710.1016/j.rser.2018.01.007 ↗
66. 10.1002/adma.20180716610.1002/adma.201807166 ↗
67. 10.1021/acssuschemeng.2c0450110.1021/acssuschemeng.2c04501 ↗
68. 10.1016/j.joule.2022.07.00210.1016/j.joule.2022.07.002 ↗
69. 10.1038/s41467-022-35239-910.1038/s41467-022-35239-9 ↗
70. 10.1038/s41893-021-00739-x10.1038/s41893-021-00739-x ↗
71. 10.1021/acsenergylett.0c0263310.1021/acsenergylett.0c02633 ↗
72. Nock, W.; Day, L.; Chang, F. In Deliverable 1.1: H2 production and consumption profiles; HyPSTER, 2021.
73. Ulsh M. · 202110.2172/1837958 ↗
74. 10.1038/s41586-020-2242-810.1038/s41586-020-2242-8 ↗
75. 10.1002/aenm.20220416910.1002/aenm.202204169 ↗
76. 10.1002/adfm.20220352010.1002/adfm.202203520 ↗
77. 10.1016/j.coche.2021.10071910.1016/j.coche.2021.100719 ↗
78. 10.1002/aenm.20190404110.1002/aenm.201904041 ↗
79. 10.1016/j.coelec.2019.08.00810.1016/j.coelec.2019.08.008 ↗
80. 10.1039/D2EE00273F10.1039/D2EE00273F ↗
81. 10.1016/j.cej.2021.13050110.1016/j.cej.2021.130501 ↗
82. 10.1016/j.apenergy.2019.01.00110.1016/j.apenergy.2019.01.001 ↗
83. 10.1038/s41893-022-00879-810.1038/s41893-022-00879-8 ↗
84. 10.1038/s41467-020-19731-810.1038/s41467-020-19731-8 ↗
85. 10.1038/s41929-018-0125-210.1038/s41929-018-0125-2 ↗
86. 10.1016/j.compchemeng.2023.10826010.1016/j.compchemeng.2023.108260 ↗
87. Electrolysers. IEA. https://www.iea.org/reports/electrolysers (accessed 2023-05-16).
88. 10.1016/j.jpowsour.2007.11.01910.1016/j.jpowsour.2007.11.019 ↗
89. 10.1039/D3EE01208E10.1039/D3EE01208E ↗
90. Siemens. Rheticus: World’s-first-automated-CO2-electrolyzer. Siemens Energy Germany, 2020. https://www.siemens-energy.com.
91. 10.1126/science.aav350610.1126/science.aav3506 ↗
92. 10.1016/j.ijhydene.2023.11.35910.1016/j.ijhydene.2023.11.359 ↗
93. 10.1016/j.biortech.2020.12286310.1016/j.biortech.2020.122863 ↗
94. 10.3389/fchem.2018.0026310.3389/fchem.2018.00263 ↗
95. 10.1021/acsenergylett.9b0114210.1021/acsenergylett.9b01142 ↗
96. 10.1002/ente.20160063610.1002/ente.201600636 ↗
97. 10.1016/j.jpowsour.2009.02.09310.1016/j.jpowsour.2009.02.093 ↗
98. 10.1149/2.011209jes10.1149/2.011209jes ↗
99. 10.1149/1.330859610.1149/1.3308596 ↗
100. 10.1021/acsenergylett.9b0150910.1021/acsenergylett.9b01509 ↗