journal article·2024-05-10

Thermodynamics and Kinetics of Conversion Reaction in Zinc Batteries

Xianhong Chen, Xuefang Xie, Pengchao Ruan, Shuquan Liang, Wai-Yeung Wong, Guozhao Fang

ACS Energy Letters· Volume 9· Issue 5
Publisher page

Abstract

Aqueous zinc-based batteries (AZBs) based on the conversion-type mechanism have become a hot spot now due to their low cost, high safety, and large capacity, which provides a significant opportunity for large-scale energy storage. However, conversion reactions in AZBs face serious thermodynamic and kinetic challenges. Rather than the common advances, this review focuses on fundamental aspects of reaction thermodynamics and kinetics for AZBs that lack systematic attention and understanding. The conversion reaction mechanisms of AZBs including anode conversion reaction, manganese-based, chalcogenide-based, halogen-based, copper-based, and iron-based conversion reaction were discussed. The fundamental issues and perspectives of the battery system are further highlighted. The final section proposes significant directions to discuss how to better understand and design effective conversion battery systems via combining thermodynamics and kinetics.
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Research context

OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, P.R. China

College of Physical Science and Technology, Xinjiang University, Urumqi, Xinjiang 830017, P.R. China

National Energy Metal Resources and New Materials Key Laboratory, Central South University, Changsha 410083, P.R. China

Funding

Research Grants Council, University Grants Committee · Central South University · Natural Science Foundation of Xinjiang Uygur Autonomous Region · Xinjiang Tianchi Doctoral Project · Science and Technology Program of Hunan Province · National Natural Science Foundation of China · Hong Kong Polytechnic University

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