DataVXCellulose Chemistry and TechnologyPaper
journal article·2023-07-20Open access

COPPER ADSORPTION ONTO POMEGRANATE PEEL ACTIVATED CARBON AS A NEW ADSORBENT

National School of Engineers of Gabes, University of Gabes, 6029 Gabes, Tunisia, WAFA SAADI, SOUAD SOUISSI-NAJAR, National School of Engineers of Gabes, University of Gabes, 6029 Gabes, Tunisia, MARIEM OTHMAN, National School of Engineers of Gabes, University of Gabes, 6029 Gabes, Tunisia, ABDELMOTTALEB OUEDERNI, National School of Engineers of Gabes, University of Gabes, 6029 Gabes, Tunisia

Cellulose Chemistry and Technology· Volume 57· Issue 5-6
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Abstract

Pomegranate peel-based activated carbon was prepared using phosphoric acid impregnation for removing copper ions from aqueous solutions. The activated carbon sample was characterized using N2 adsorption–desorption isotherms, SEM, FTIR, and Boehm titration. Batch adsorption experiments were performed as a function of initial pH, contact time, initial ion concentration and temperature. The metal adsorption was found pH dependent, with maximum adsorption occurring at an initial pH of 5.4. Langmuir, Freundlich and Temkin isotherms were used to analyze the equilibrium data at different temperatures. The Freundlich isotherm was considered to be the best model for representing Cu(II) adsorption data. The kinetic studies were analyzed using pseudo-first order, pseudo-second order and intraparticle diffusion models, with good fitting to the pseudo-second-order model. The adsorption behavior of the binary solution system Cu(II)-Cd(II) showed that the adsorbent has higher selectivity towards copper ions than cadmium ions.
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OpenAlex topics: Adsorption and biosorption for pollutant removal

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