DataVXACS Energy LettersPaper
journal article·2021-11-12

Phase Diagram Determined Lithium Plating/Stripping Behaviors on Lithiophilic Substrates

Simeng Zhang, Gaojing Yang, Zepeng Liu, Suting Weng, Xiaoyun Li, Xuefeng Wang, Yurui Gao, Zhaoxiang Wang, Liquan Chen

ACS Energy Letters· Volume 6· Issue 11
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Source abstract

Abstract

Many lithiophilic materials have been proposed as substrates to homogenize the lithium plating, but fundamental understandings are still lacking to the drastically different behaviors of lithium on them. Herein we studied the phase transition process of a series of lithiophilic materials and the lithium plating/stripping behaviors on them. A close correlation was found between the binary phase diagrams and the lithium cycling behaviors. The substrate (such as Ag and Mg) that only forms solid solutions with lithium shows high structural stability during repeated alloying and dealloying because the (lithium-removed porous) particles can guide the lithium deposition and support the interphase layer. In contrast, the materials (such as Au, Al, Zn, Si, and Sn) that form lithium intermetallic compounds become lithium-saturated and cannot modulate the lithium plating thereafter, resulting in poor structural stability and cycling behavior. These findings provide important guidance for the rational selection and design of the substrate in the secondary metal batteries.
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Research context

Energy storageMetals & alloysMaterials processing

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing Key Laboratory for New Energy Materials and Devices, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100190, China

School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, China

Laboratory for Advanced Materials & Electron Microscopy, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Tianmu Lake Institute of Advanced Energy Storage Technologies Co. Ltd., Liyang 213300, Jiangsu, China

Laboratory of Theoretical and Computational Nanoscience, CAS Key Laboratory for Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Chinese Academy of Sciences, Beijing 100190, China

Funding

National Natural Science Foundation of China

References (42)

Show source-provided references
1. 10.1038/3510464410.1038/35104644 ↗
2. 10.1016/j.nanoen.2020.10448610.1016/j.nanoen.2020.104486 ↗
3. 10.1021/acs.chemrev.7b0011510.1021/acs.chemrev.7b00115 ↗
4. 10.1021/acs.nanolett.1c0084810.1021/acs.nanolett.1c00848 ↗
5. 10.1021/acs.nanolett.1c0143610.1021/acs.nanolett.1c01436 ↗
6. 10.1002/adma.20190551710.1002/adma.201905517 ↗
7. 10.1002/adma.20180608210.1002/adma.201806082 ↗
8. 10.1002/anie.20191172410.1002/anie.201911724 ↗
9. 10.1002/aenm.20190329210.1002/aenm.201903292 ↗
10. 10.1016/j.ensm.2021.01.02210.1016/j.ensm.2021.01.022 ↗
11. 10.1021/acs.nanolett.8b0437610.1021/acs.nanolett.8b04376 ↗
12. 10.1016/j.carbon.2019.08.02310.1016/j.carbon.2019.08.023 ↗
13. 10.1002/aenm.20190234310.1002/aenm.201902343 ↗
14. 10.1126/sciadv.aax558710.1126/sciadv.aax5587 ↗
15. 10.1021/acs.nanolett.9b0362610.1021/acs.nanolett.9b03626 ↗
16. 10.1002/aenm.20190176410.1002/aenm.201901764 ↗
17. 10.1002/anie.20181195510.1002/anie.201811955 ↗
18. 10.1016/j.nanoen.2019.10414410.1016/j.nanoen.2019.104144 ↗
19. 10.1016/j.nanoen.2020.10447110.1016/j.nanoen.2020.104471 ↗
20. 10.1039/D0TA06126C10.1039/D0TA06126C ↗
21. 10.1002/advs.20190264310.1002/advs.201902643 ↗
22. 10.1038/s41467-020-14550-310.1038/s41467-020-14550-3 ↗
23. 10.1016/j.nanoen.2019.04.08710.1016/j.nanoen.2019.04.087 ↗
24. 10.1002/aenm.20190227810.1002/aenm.201902278 ↗
25. 10.1002/adma.20200095210.1002/adma.202000952 ↗
26. 10.1038/nenergy.2016.1010.1038/nenergy.2016.10 ↗
27. 10.1021/jacs.0c0181110.1021/jacs.0c01811 ↗
28. 10.1016/j.ensm.2020.05.00910.1016/j.ensm.2020.05.009 ↗
29. 10.1016/j.ensm.2019.06.01010.1016/j.ensm.2019.06.010 ↗
30. 10.1016/j.joule.2018.02.00110.1016/j.joule.2018.02.001 ↗
31. 10.1016/j.ensm.2018.04.03210.1016/j.ensm.2018.04.032 ↗
32. 10.1016/j.jpowsour.2003.07.00410.1016/j.jpowsour.2003.07.004 ↗
33. 10.1021/acs.chemmater.5b0471910.1021/acs.chemmater.5b04719 ↗
34. 10.1007/BF0284170510.1007/BF02841705 ↗
35. 10.1149/1.139113310.1149/1.1391133 ↗
36. 10.1016/0167-2738(88)90394-310.1016/0167-2738(88)90394-3 ↗
37. 10.1002/adma.20180749510.1002/adma.201807495 ↗
38. 10.1002/aenm.20130088210.1002/aenm.201300882 ↗
39. 10.1039/b823474d10.1039/b823474d ↗
40. 10.1021/acsaem.9b0212510.1021/acsaem.9b02125 ↗
41. 10.1021/acs.nanolett.6b0475510.1021/acs.nanolett.6b04755 ↗
42. 10.1016/j.nanoen.2016.12.00110.1016/j.nanoen.2016.12.001 ↗