In Situ Vertical Growth of Fe–Ni Layered Double-Hydroxide Arrays on Fe–Ni Alloy Foil: Interfacial Layer Enhanced Electrocatalyst with Small Overpotential for Oxygen Evolution Reaction
Source abstract
Abstract
Layer double hydroxide (LDH) has been widely applied to electrocatalysis, especially toward the oxygen evolution reaction (OER), owing to its flexible layered structure and multifunctionality. Herein, FeNi LDH nanosheet arrays are directly synthesized on various metal foils by a facile hydrothermal method. Compared with single Fe or Ni substrates, the obtained FeNi LDH/FeNi foil exhibited an ultrasmall onset overpotential of ∼90 mV, high catalytic activity (overpotential of 130 mV @ 10 mA/cm2), and durable stability in 0.1 M KOH electrolyte. We also demonstrate, by utilizing density functional theory calculations, that the growth of the hydroxide interfacial layer between LDH and FeNi foil makes the LDH possess more favorable adsorption to the OH intermediate during OER than the pure LDH. This reveals that the vertical FeNi LDH arrays on the FeNi alloy substrate are prone to be an efficient catalyst toward OER.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, PR China
University of Michigan - Shanghai Jiao Tong University Joint Institute, Shanghai Jiao Tong University, Shanghai 200240, PR China
Materials Genome Initiative Center, Shanghai Jiao Tong University, Shanghai 200240, PR China
Hydrogen Science Research Center, Shanghai Jiao Tong University, Shanghai 200240, PR China
Funding
Shanghai Jiao Tong University · Ministry of Science and Technology of the People's Republic of China · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China
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