journal article·2017-10-13

Copper Nanoparticles Installed in Metal–Organic Framework Thin Films are Electrocatalytically Competent for CO2 Reduction

Chung-Wei Kung, Cornelius O. Audu, Aaron W. Peters, Hyunho Noh, Omar K. Farha, Joseph T. Hupp

ACS Energy Letters· Volume 2· Issue 10
Publisher page

Abstract

Copper nanoparticles are embedded into a solvothermally grown thin film of a zirconium metal–organic framework (MOF), NU-1000, by installing single-site Cu(II) into the NU-1000 thin film via solvothermal deposition in MOFs (SIM) followed by electrochemical reduction of Cu(II) to metallic Cu. The obtained Cu nanoparticles are electrochemically addressable and exhibit promising electrocatalytic activity for CO 2 reduction in an aqueous electrolyte.
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Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Metal-Organic Frameworks: Synthesis and Applications · Ionic liquids properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States

Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States

Funding

Ministry of Science and Technology · Basic Energy Sciences · Directorate for Education and Human Resources · U.S. Department of Defense

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