VISCOSITY OF HYDROXYPROPYL CELLULOSE SOLUTIONS IN THE PRESENCE OF POLY(N-VINYLPYRROLIDONE)
Source abstract
Abstract
The paper reports viscosity data for aqueous solutions of hydroxypropyl cellulose (HPC) in the presence of poly(N-vinylpyrrolidone) (PVP) in dilute, semidilute and concentrated regimes. The two polymers are miscible over the entire range of composition. In dilute solution, mixed isolated coils with more extended chain conformation are formed and binary polymer-polymer interactions are favored when a small amount of PVP is added to HPC solutions. The viscosity increases in semidilute and concentrated regimes due to chain entanglements and a pronounced synergistic effect was observed upon the addition of a small amount of PVP to the HPC isotropic solution. The intermolecular hydrogen bonding between the hydroxyl groups of HPC and the carbonyl groups of PVP influences the overall flow behavior.
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Research context
OpenAlex topics: Polymer Nanocomposites and Properties · Synthesis and properties of polymers · Epoxy Resin Curing Processes
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References (45)
Show source-provided references
1. "1 P. Harrison and P. Navard, Rheol. Acta, 38, 569 (1999), https://doi.org/10.1007/s00397005020910.1007/s003970050209 ↗
2. 2 L. Walker and N. Wagner, J. Rheol., 38, 1525 (1994), https://doi.org/10.1122/1.55055710.1122/1.550557 ↗
3. 3 M. Yoshida, H. Hozumi, Y. Horikawa and T. Shikata, Biomacromolecules, 26, 1294 (2025), https://doi.org/10.1021/acs.biomac.4c0164610.1021/acs.biomac.4c01646 ↗
4. 4 M. Bercea and P. Navard, Cellulose Chem. Technol., 52, 603 (2018), https://www.cellulosechemtechnol.ro/pdf/CCT7-8(2018)/p.603-608.pdf
5. 5 S. Guido, Macromolecules, 28, 4530 (1995), https://doi.org/10.1021/ma00117a02310.1021/ma00117a023 ↗
6. 6 S. Guido and N. Grizzuti, Rheol. Acta, 34, 137 (1995), https://doi.org/10.1007/BF0039843310.1007/BF00398433 ↗
7. 7 S. Fujii, N. Sasaki and M. Nakata, J. Polym. Sci. B: Polym. Phys., 39, 1976 (2001), https://doi.org/10.1002/polb.117310.1002/polb.1173 ↗
8. 8 D. Cholakova, K. Tsvetkova, V. Yordanova, K. Rusanova, N. Denkov et al., Gels, 11, 113 (2025), https://doi.org/10.3390/gels1102011310.3390/gels11020113 ↗
9. 9 Z. Shi, Y. Li, H. Duan, Y. Wang, X. Zhang et al., Int. J. Biol. Macromol., 318, 145223 (2025), https://doi.org/10.1016/j.ijbiomac.2025.14522310.1016/j.ijbiomac.2025.145223 ↗
10. 10 I. A. Plugariu, L. M. Gradinaru, M. Avadanei, I. Rosca, L. E. Nita et al., Pharmaceuticals, 16, 1510 (2023), https://doi.org/10.3390/ph1611151010.3390/ph16111510 ↗
11. 11 E. D. Klug, J. Polym. Sci. C, Polym. Symp., 9, 491 (1971), https://doi.org/10.1002/polc.507036013710.1002/polc.5070360137 ↗
12. 12 J. Gao, G. Haidar, X. Lu and Z. Hu, Macromolecules, 34, 2242 (2001), https://doi.org/10.1021/ma001631g10.1021/ma001631g ↗
13. 13 X. Lu, X. Hu and J. Schwartz, Macromolecules, 35, 9164 (2002), https://doi.org/10.1021/ma020884210.1021/ma0208842 ↗
14. 14 A. Nakamura, R. Ogai and K. Murakami, Sol. Energ. Mater. Sol. Cells, 232, 111348 (2021), https://doi.org/10.1016/j.solmat.2021.11134810.1016/j.solmat.2021.111348 ↗
15. 15 A. R. D. Amaral, L. J. D. Danda, H. C. Rigonatto, A. F. Silva-Neto, J. L. Soares-Sobrinho et al., J. Drug Deliv. Sci. Technol., 106, 106708 (2025), https://doi.org/10.1016/j.jddst.2025.10670810.1016/j.jddst.2025.106708 ↗
16. 16 M. Teodorescu and M. Bercea, Polym. Plast. Technol. Eng., 54, 923 (2015), https://doi.org/10.1080/03602559.2014.97950610.1080/03602559.2014.979506 ↗
17. 17 https://www.ashland.com/industries/pharmaceutical/oral-solid-dose/klucel-hydroxypropylcellulose
18. 18 M. L. Huggins, J. Am. Chem. Soc., 64, 2716 (1942), https://doi.org/10.1021/ja01263a05610.1021/ja01263a056 ↗
19. 19 B. A. Wolf, Ind. Eng. Chem. Res., 54, 4672 (2015), https://doi.org/10.1021/acs.iecr.5b0084510.1021/acs.iecr.5b00845 ↗
20. 20 B. A. Wolf, Macromolecules, 52, 3231 (2019), https://doi.org/10.1021/acs.macromol.9b0028210.1021/acs.macromol.9b00282 ↗
21. 21 B. A. Wolf, Macromol. Chem. Phys., 219, 1800249 (2018), https://doi.org/10.1002/macp.20180024910.1002/macp.201800249 ↗
22. 22 M. Bercea and B. A. Wolf, Macromolecules, 51, 7483 (2018), https://doi.org/10.1021/acs.macromol.8b0142210.1021/acs.macromol.8b01422 ↗
23. 23 S. L. Law and J. B. Kayes, Int. J. Pharm., 15, 251 (1983), https://doi.org/10.1016/0378-5173(83)90159-X10.1016/0378-5173(83)90159-X ↗
24. 24 A. A. A. Abdel-Azim, H. Tenhu, J. Merta, F. Sundholm and H. Tenhy, Polym. J., 25, 671 (1993), https://doi.org/10.1295/polymj.25.67110.1295/polymj.25.671 ↗
25. 25 A. A. Tager, A. P. Safronov, E. A. Berezyuk and I. Yu. Galaev, Colloid Polym. Sci., 272, 1234 (1994), https://doi.org/10.1007/BF0065777510.1007/BF00657775 ↗
26. 26 S. Costanzo, R. Pasquino, R. Donato and N. Grizzuti, Polymer, 132, 157 (2017), https://doi.org/10.1016/j.polymer.2017.10.06610.1016/j.polymer.2017.10.066 ↗
27. 27 C. G. Lopez, L. Voleske and W. Richtering, Carbohyd. Polym., 234, 115886 (2020), https://doi.org/10.1016/j.carbpol.2020.11588610.1016/j.carbpol.2020.115886 ↗
28. 28 N. Pakuro, A. Yakimansky, F. Chibirova and A. Arest-Yakubovich, Polymer, 50, 148 (2009), https://doi.org/10.1016/j.polymer.2008.10.03710.1016/j.polymer.2008.10.037 ↗
29. 29 M. T. Cook, P. Haddow, S. B. Kirton and W. J. McAuley, Adv. Funct. Mater., 31, 2008123 (2021), https://doi.org/10.1002/adfm.20200812310.1002/adfm.202008123 ↗
30. 30 K. Sudarsan Reddy, M. N. Prabhakar, V. Nagamaheswara Reddy, G. Sathyamaiah, Y. Maruthi et al., J. Appl. Polym. Sci., 125, 2289 (2012), https://doi.org/10.1002/app.3646410.1002/app.36464 ↗
31. 31 W. W. Graessley, Polymer, 21, 258 (1980), https://doi.org/10.1016/0032-3861(80)90266-910.1016/0032-3861(80)90266-9 ↗
32. 32 P. Štěpánek and W. Brown, Macromolecules, 31, 1889 (1998), https://doi.org/10.1021/ma970458u10.1021/ma970458u ↗
33. 33 M. Bercea, C. Ioan, S. Ioan, B. C. Simionescu and C. I. Simionescu, Prog. Polym. Sci., 24, 379 (1999), https://doi.org/10.1016/S0079-6700(99)00007-610.1016/S0079-6700(99)00007-6 ↗
34. 34 R. P. Wool, Macromolecules, 26, 1564 (1993), https://doi.org/10.1021/ma00059a01210.1021/ma00059a012 ↗
35. 35 B. A. Wolf, Polymer, 212, 123149 (2021), https://doi.org/10.1016/j.polymer.2020.12314910.1016/j.polymer.2020.123149 ↗
36. 36 M. Bercea, M. Cazacu and B. A. Wolf, Macromol. Chem. Phys., 204, 1371 (2003), https://doi.org/10.1002/macp.20035000110.1002/macp.200350001 ↗
37. 37 C. Carotenuto and N. Grizzuti, Rheol. Acta, 45, 468 (2006), https://doi.org/10.1007/s00397-005-0075-x10.1007/s00397-005-0075-x ↗
38. 38 K. George, N. Taheri-Qazvini, P. D. Olmsted and M. Sadati, Small, 21, 2407658 (2025), https://doi.org/10.1002/smll.20240765810.1002/smll.202407658 ↗
39. 39 A. Urtti, M. Juslin and O. Miinalainen, Int. J. Pharm., 25, 165 (1985), https://doi.org/10.1016/0378-5173(85)90090-010.1016/0378-5173(85)90090-0 ↗
40. 40 A. Sarode, P. Wang, C. Cote and D. R. Worthen, AAPS PharmSciTech, 14, 151 (2013), https://doi.org/10.1208/s12249-012-9897-x10.1208/s12249-012-9897-x ↗
41. 41 I. Esentürk-Güzel, E. A. Yapar, S. Cavalu, B. T. Şeker, E. İnal et al., Farmacia, 72, 200 (2024), https://doi.org/10.31925/farmacia.2024.1.2210.31925/farmacia.2024.1.22 ↗
42. 42 G. C. S. Girsang, F. Khoerunnisa and B. Anwar, J. Fiber. Polym. Compos., 3, 101 (2024), https://doi.org/10.55043/jfpc.v3i2.201
43. 43 F. Reséndez-González, C. F. Castro-Guerrero, A. B. Morales-Cepeda, J. L. Rivera-Armenta and O. Solís-Canto, Cellulose Chem. Technol., 58, 323 (2024), https://doi.org/10.35812/CelluloseChemTechnol.2024.58.3110.35812/CelluloseChemTechnol.2024.58.31 ↗
44. 44 L. Jiang, K. Li, H. Yang, X. Liu, W. Li et al., Cellulose, 27, 955 (2020), https://doi.org/10.1007/s10570-019-02830-110.1007/s10570-019-02830-1 ↗
45. "