journal article·2022-05-05Open access

"EVALUATION OF OPUNTIA FICUS INDICA AS AN ECONOMIC ADSORBENT FOR ANIONIC RED BEMACID DYE FROM AQUEOUS SOLUTION "

", AIDA FEKAOUNI, Department of Process Engineering, Faculty of Technology, University Hassiba Ben Bouali, Chlef, Algeria ", GHANIA HENINI, "Department of Process Engineering, Faculty of Technology, University Hassiba Ben Bouali, Chlef, Algeria ", YKHLEF LAIDANI, "Department of Process Engineering, Faculty of Technology, University Hassiba Ben Bouali, Chlef, Algeria "

Cellulose Chemistry and Technology· Volume 56· Issue 3-4

Abstract

Opuntia ficus indica cladodes (OFIC) were used as an adsorbent for the removal of anionic Bemacid Red (RB) dye from an aqueous solution. The study was performed in a batch reactor under different experimental conditions. The adsorption process was very fast during the first 60 min of phases’ contact at 25 °C, the adsorbent being characterized by an adsorption capacity of 16.721 mg/g at pH 2. The experimental data fitted very well with the pseudo-second-order kinetic model (R2 = 0.994), and the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich adsorption models were applied to describe the adsorption equilibrium isotherms. The thermodynamic parameters: enthalpy (-20.739 kJ/mol), entropy (-0.226 kJ/K.mol) and the Gibbs free energy (-14 to -13.557 kJ/mol) were determined over the selected temperature range (25 to 45 °C). The adsorption using the studied system (OFI cladodes/RB) proved to be an exothermic and spontaneous process.
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