Processable Sub-5 Nanometer Organosilica Hybrid Particles for Dye Stabilization
Source abstract
Abstract
A method for the synthesis of uniform dye-embedded organosilica nanoparticles with a size of sub-5 nm via cocondensation of the dye and atom transfer radical polymerization (ATRP) initiator-functionalized organosilanes is presented. Hybrid particles are amenable to direct grafting of polymer chains from the nanoparticle surface without the need for additional anchoring of initiating groups. The dye-embedded organosilica–poly(methyl methacrylate) brush particles were processed into flexible films and demonstrated outstanding stability enhancement against halochromism as compared to the pristine dye.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Polymer Synthesis and Characterization · TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials Science & Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States
College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, People’s Republic of China
Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States
Funding
Basic Energy Sciences
References (20)
Show source-provided references
1. 10.1021/acsomega.8b0115110.1021/acsomega.8b01151 ↗
2. 10.1021/am401328f10.1021/am401328f ↗
3. 10.1002/wnan.135110.1002/wnan.1351 ↗
4. 10.1007/s11051-018-4227-110.1007/s11051-018-4227-1 ↗
5. 10.1016/j.copbio.2004.11.00310.1016/j.copbio.2004.11.003 ↗
6. 10.1080/01496395.2011.64737410.1080/01496395.2011.647374 ↗
7. 10.1080/1064338930938845310.1080/10643389309388453 ↗
8. 10.1021/la00048a01310.1021/la00048a013 ↗
9. 10.1006/jcis.1993.130610.1006/jcis.1993.1306 ↗
10. 10.1021/nl048247810.1021/nl0482478 ↗
11. 10.1038/nrd259110.1038/nrd2591 ↗
12. 10.1002/adma.20170644110.1002/adma.201706441 ↗
13. 10.1016/j.progpolymsci.2019.10118010.1016/j.progpolymsci.2019.101180 ↗
14. 10.1039/C6SM00095A10.1039/C6SM00095A ↗
15. 10.1021/acsmacrolett.0c0050210.1021/acsmacrolett.0c00502 ↗
16. 10.1177/17.11.73410.1177/17.11.734 ↗
17. 10.1016/0891-5849(94)E0139-A10.1016/0891-5849(94)E0139-A ↗
18. 10.1021/la063402e10.1021/la063402e ↗
19. 10.1016/j.progpolymsci.2019.10118510.1016/j.progpolymsci.2019.101185 ↗
20. 10.1002/chem.20110363310.1002/chem.201103633 ↗