Functionally Graded Adhesives via High-Energy Irradiation
Source abstract
Abstract
A thermally cured epoxy/anhydride system is shown to exhibit dose-dependent increases in cross-link density, glass transition temperature, and modulus. The addition of various sensitizers further boosts sensitivity toward radiation-induced cross-linking. A theory proposed by Shibayama relating Tg with cross-link density provides a useful means to predict the dose at which a particular set of properties may be produced. This combination of an approach to materials formulation and processing and the identification of simple analytical models to predict resultant properties provides a useful strategy for the generation of functionally graded materials.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Epoxy Resin Curing Processes · Silicone and Siloxane Chemistry · Photopolymerization techniques and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Plastics Engineering, University of Massachusetts Lowell, Lowell, Massachusetts 01854, United States
Department of Mechanical Engineering, University of Massachusetts Lowell, Lowell, Massachusetts 01854, United States
Department of Materials Research & Technology, Luxembourg Institute of Science & Technology, L-4940 Hautcharage, Luxembourg
Funding
Division of Civil, Mechanical and Manufacturing Innovation
References (30)
Show source-provided references
1. 10.1126/science.105971610.1126/science.1059716 ↗
2. 10.1021/ja400271310.1021/ja4002713 ↗
3. 10.1016/j.ijadhadh.2013.09.04510.1016/j.ijadhadh.2013.09.045 ↗
4. 10.1002/marc.20150063710.1002/marc.201500637 ↗
5. 10.1016/j.ijadhadh.2017.02.00810.1016/j.ijadhadh.2017.02.008 ↗
6. 10.1016/j.ijadhadh.2017.02.00610.1016/j.ijadhadh.2017.02.006 ↗
7. 10.1021/ie100321h10.1021/ie100321h ↗
8. 10.1002/1097-4628(20001220)78:13<2398::AID-APP170>3.0.CO;2-K10.1002/1097-4628(20001220)78:13<2398::AID-APP170>3.0.CO;2-K ↗
9. 10.1023/A:101850220100010.1023/A:1018502201000 ↗
10. 10.1038/pj.2015.7310.1038/pj.2015.73 ↗
11. 10.1021/am507725k10.1021/am507725k ↗
12. 10.1080/00218464.2018.145633810.1080/00218464.2018.1456338 ↗
13. 10.1080/00218464.2015.111352510.1080/00218464.2015.1113525 ↗
14. 10.1016/j.ijadhadh.2017.02.00410.1016/j.ijadhadh.2017.02.004 ↗
15. 10.1080/00218464.2019.164664710.1080/00218464.2019.1646647 ↗
16. 10.1080/01694243.2013.79029410.1080/01694243.2013.790294 ↗
17. 10.1016/j.conbuildmat.2017.02.06310.1016/j.conbuildmat.2017.02.063 ↗
18. 10.1016/S0168-583X(01)00966-110.1016/S0168-583X(01)00966-1 ↗
19. 10.1016/j.radphyschem.2017.01.00810.1016/j.radphyschem.2017.01.008 ↗
20. 10.1016/1359-0197(92)90051-G10.1016/1359-0197(92)90051-G ↗
21. 10.1021/acsami.5b0586310.1021/acsami.5b05863 ↗
22. 10.1002/app.1966.07010120210.1002/app.1966.070101202 ↗
23. 10.1016/S0300-9440(97)00081-710.1016/S0300-9440(97)00081-7 ↗
24. 10.1295/koron1944.18.18310.1295/koron1944.18.183 ↗
25. 10.1016/0300-9440(75)80009-910.1016/0300-9440(75)80009-9 ↗
26. 10.1002/cssc.20160039210.1002/cssc.201600392 ↗
27. 10.1021/acs.macromol.6b0196410.1021/acs.macromol.6b01964 ↗
28. 10.1163/15685610332239672110.1163/156856103322396721 ↗
29. Kamon T. · 1986 · 80 · 17310.1007/3-540-16423-5_15 ↗
30. 10.1520/CTR10859J10.1520/CTR10859J ↗