journal article·2019-02-08

Highly Efficient Recovery of Water-Soluble Polymers in Synergistic Kinetic Inhibition of Gas Hydrate Formation

Ye Won Bae, Jeongtak Kim, Sung Hwan Ju, Kyuchul Shin, In Woo Cheong

ACS Applied Polymer Materials· Volume 1· Issue 2
Publisher page

Abstract

The recovery of synthetic water-soluble polymers is of high environmental and economic importance. We report that these polymers are completely recovered using thermoresponsive polymer-brushed superparamagnetic nanoparticles. Thermoresponsive poly(N-isopropylacrylamide-ran-N,N-dimethylacrylamide) (RCP) and poly(N-isopropylacrylamide-ran-N,N-dimethylacrylamide)-block-poly(acrylic acid) (BCP) were used as the water-soluble polymer to be recovered and as the corona layer of iron oxide nanoparticles (IONPs), respectively. Both IONPs-BCP and RCP were simply collected by a magnet after heating, and the IONP-BCP/RCP mixture allowed for good kinetic inhibition of methane hydrate formation. This work reveals that the synergistic behavior of IONPs as recovery agents is practically utilized for the recovery of synthetic water-soluble polymers.
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Research context

OpenAlex topics: Characterization and Applications of Magnetic Nanoparticles · Solar and Space Plasma Dynamics · Micro and Nano Robotics

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Affiliations

Department of Applied Chemistry, School of Applied Chemical Engineering, Kyungpook National University, 80 Daehak-ro, Buk-gu, Daegu 41566, Republic of Korea

Funding

National Research Foundation of Korea · Ministry of Trade, Industry and Energy

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