Visible Light-Regulated Organocatalytic Ring-Opening Polymerization of Lactones Using Hydroxybenzophenones as Photocatalyst
Source abstract
Abstract
Visible light-regulated organocatalytic polymerization has attracted considerable attention in recent years due to its mild, metal-free reaction conditions and the capability of mediating polymerization with spatial and temporal controls. Here, we report the successful identification of hydroxybenzophenones (BPOHs) as an effective class of photoacid catalysts for the ring-opening polymerization of lactones, which could afford biodegradable polyester products with predictable molecular mass and low dispersity under the irradiation of visible light.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Photopolymerization techniques and applications · Advanced Polymer Synthesis and Characterization · biodegradable polymer synthesis and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou 350108, China
Beijing National Laboratory for Molecular Sciences, Beijing 100190, China
Funding
Fuzhou University · National Natural Science Foundation of China · Recruitment Program of Global Experts · Beijing National Laboratory for Molecular Sciences
References (63)
Show source-provided references
1. 10.1021/ma100754510.1021/ma1007545 ↗
2. 10.1021/acs.chemrev.5b0067110.1021/acs.chemrev.5b00671 ↗
3. 10.1021/acs.chemrev.5b0058610.1021/acs.chemrev.5b00586 ↗
4. 10.1016/j.progpolymsci.2016.06.00510.1016/j.progpolymsci.2016.06.005 ↗
5. 10.1039/C6CS00185H10.1039/C6CS00185H ↗
6. 10.1002/adma.20160400510.1002/adma.201604005 ↗
7. 10.1002/anie.20170142510.1002/anie.201701425 ↗
8. 10.1002/marc.20170014310.1002/marc.201700143 ↗
9. 10.1039/C8CS00259B10.1039/C8CS00259B ↗
10. 10.1002/anie.20180547310.1002/anie.201805473 ↗
11. 10.1016/j.progpolymsci.2019.10117810.1016/j.progpolymsci.2019.101178 ↗
12. 10.1126/science.119392810.1126/science.1193928 ↗
13. 10.1021/ja203608910.1021/ja2036089 ↗
14. 10.1002/anie.20151179310.1002/anie.201511793 ↗
15. 10.1021/ja505883u10.1021/ja505883u ↗
16. 10.1039/c1cc13117f10.1039/c1cc13117f ↗
17. 10.1021/ma402494410.1021/ma4024944 ↗
18. 10.1126/science.120235710.1126/science.1202357 ↗
19. 10.1021/jacs.8b0017310.1021/jacs.8b00173 ↗
20. 10.1021/jacs.8b0217110.1021/jacs.8b02171 ↗
21. 10.1016/S0079-6700(98)00010-010.1016/S0079-6700(98)00010-0 ↗
22. 10.1002/marc.20130089810.1002/marc.201300898 ↗
23. 10.1039/C4CY00344F10.1039/C4CY00344F ↗
24. 10.1038/nchem.16710.1038/nchem.167 ↗
25. 10.1038/nchem.263310.1038/nchem.2633 ↗
26. 10.1021/ja107620y10.1021/ja107620y ↗
27. 10.1021/acs.macromol.7b0159710.1021/acs.macromol.7b01597 ↗
28. 10.1039/C4SC01309C10.1039/C4SC01309C ↗
29. 10.1016/j.progpolymsci.2014.09.00110.1016/j.progpolymsci.2014.09.001 ↗
30. 10.1021/acs.chemrev.5b0053910.1021/acs.chemrev.5b00539 ↗
31. 10.1016/j.progpolymsci.2018.06.00610.1016/j.progpolymsci.2018.06.006 ↗
32. 10.1039/C9CC01431D10.1039/C9CC01431D ↗
33. 10.1021/acs.chemrev.9b0074410.1021/acs.chemrev.9b00744 ↗
34. 10.1016/j.progpolymsci.2019.10118610.1016/j.progpolymsci.2019.101186 ↗
35. 10.1016/j.progpolymsci.2020.10131110.1016/j.progpolymsci.2020.101311 ↗
36. 10.1021/ja017332410.1021/ja0173324 ↗
37. 10.1002/1521-3773(20010716)40:14<2712::AID-ANIE2712>3.0.CO;2-Z10.1002/1521-3773(20010716)40:14<2712::AID-ANIE2712>3.0.CO;2-Z ↗
38. 10.1039/c2cs35383k10.1039/c2cs35383k ↗
39. 10.1021/cr068415b10.1021/cr068415b ↗
40. 10.1021/ma902594810.1021/ma9025948 ↗
41. 10.1126/science.aaf746510.1126/science.aaf7465 ↗
42. 10.1021/mz300595610.1021/mz3005956 ↗
43. 10.1039/C6CC03084J10.1039/C6CC03084J ↗
44. 10.1002/cptc.20180025510.1002/cptc.201800255 ↗
45. 10.1038/s41929-018-0091-810.1038/s41929-018-0091-8 ↗
46. 10.1039/C6CC04090J10.1039/C6CC04090J ↗
47. 10.1039/D0PY00369G10.1039/D0PY00369G ↗
48. 10.1039/D0PY01715A10.1039/D0PY01715A ↗
49. 10.1021/ar990109f10.1021/ar990109f ↗
50. 10.1126/science.109308110.1126/science.1093081 ↗
51. 10.1039/C2CS35195A10.1039/C2CS35195A ↗
52. 10.1021/acs.chemrev.6b0034210.1021/acs.chemrev.6b00342 ↗
53. 10.1021/acs.accounts.7b0019010.1021/acs.accounts.7b00190 ↗
54. 10.1038/s41929-020-00553-210.1038/s41929-020-00553-2 ↗
55. 10.1021/ja410815u10.1021/ja410815u ↗
56. 10.1021/jacs.0c0028710.1021/jacs.0c00287 ↗
57. 10.1021/jacs.0c0506910.1021/jacs.0c05069 ↗
58. 10.1021/ma202168m10.1021/ma202168m ↗
59. 10.1002/marc.20120057810.1002/marc.201200578 ↗
60. 10.1039/C0PY00392A10.1039/C0PY00392A ↗
61. 10.1016/j.eurpolymj.2019.10944910.1016/j.eurpolymj.2019.109449 ↗
62. 10.1039/c3py00667k10.1039/c3py00667k ↗
63. 10.1002/anie.20180090910.1002/anie.201800909 ↗