journal article·2020-04-10

Effect of Crystallinity in Stretched PVA Films on Triplet–Triplet Annihilation Photon Upconversion

Tomohiro Mori, Takeshi Mori, Akira Fujii, Akane Saito, Hitoshi Saomoto, Kenji Kamada

ACS Applied Polymer Materials· Volume 2· Issue 4
Publisher page

Abstract

A wet-stretching technique was applied to chromophore-blended poly(vinyl alcohol) (PVA) films to control the agglomeration of chromophores and improve the triplet–triplet annihilation (TTA) photon upconversion (UC) performance of the solid-state system. By using the stretching technique, a maximum UC quantum yield of ∼3% and lowest threshold intensity of 90 mW/cm2 were obtained under atmospheric conditions. It was found that a decrease in the crystallinity of the PVA matrix induced by stretching caused specific localization of the chromophores and accelerated triplet energy transfer and triplet exciton migration.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Luminescence Properties of Advanced Materials · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Industrial Technology Center of Wakayama Prefecture, Ogura 60, Wakayama, Wakayama 649-6261, Japan

IFMRI, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan

Funding

National Institute of Advanced Industrial Science and Technology

References (31)

Show source-provided references
1. 10.1021/jp309636m10.1021/jp309636m ↗
2. 10.1021/jz401050u10.1021/jz401050u ↗
3. 10.1039/C1CC16015J10.1039/C1CC16015J ↗
4. 10.1021/ja308789u10.1021/ja308789u ↗
5. 10.1021/ja310426810.1021/ja3104268 ↗
6. 10.1021/jacs.7b0546210.1021/jacs.7b05462 ↗
7. 10.1039/C4CP03936J10.1039/C4CP03936J ↗
8. 10.1039/C6MH00413J10.1039/C6MH00413J ↗
9. 10.1039/C8MH90022A10.1039/C8MH90022A ↗
10. 10.1021/acsami.9b0414810.1021/acsami.9b04148 ↗
11. 10.1038/nature0165010.1038/nature01650 ↗
12. 10.1039/C6CC00089D10.1039/C6CC00089D ↗
13. 10.1021/acs.nanolett.9b0054310.1021/acs.nanolett.9b00543 ↗
14. 10.1021/jacs.6b0469210.1021/jacs.6b04692 ↗
15. 10.1002/adma.20170299210.1002/adma.201702992 ↗
16. 10.1021/cm301241410.1021/cm3012414 ↗
17. 10.1021/acsami.7b1778910.1021/acsami.7b17789 ↗
18. 10.1016/j.jlumin.2008.10.01310.1016/j.jlumin.2008.10.013 ↗
19. 10.1088/1367-2630/10/10/10300210.1088/1367-2630/10/10/103002 ↗
20. 10.1039/c3tc30878b10.1039/c3tc30878b ↗
21. 10.1021/acsami.6b0388810.1021/acsami.6b03888 ↗
22. 10.1039/C8SC02151A10.1039/C8SC02151A ↗
23. 10.1039/C8ME00041G10.1039/C8ME00041G ↗
24. 10.1016/j.polymer.2005.05.12910.1016/j.polymer.2005.05.129 ↗
25. 10.1021/ma070731k10.1021/ma070731k ↗
26. 10.1002/pen.2391310.1002/pen.23913 ↗
27. 10.1103/PhysRevB.78.19511210.1103/PhysRevB.78.195112 ↗
28. 10.1021/jz300012u10.1021/jz300012u ↗
29. 10.1039/c2cp23900k10.1039/c2cp23900k ↗
30. 10.1002/pol.1966.15004032110.1002/pol.1966.150040321 ↗
31. 10.1063/1.174228110.1063/1.1742281 ↗