journal article·2024-12-27

Polyrotaxane-Based Solid Polymer Electrolyte with a Macromolecular Crosslinker

Rui-Dong Wang, Yi-Fei Zhang, Xiao-Long Han, Xiao-Yang Fan, Jun Tian, Yu-Kun Gao, Ting-Ting You, Peng-Gang Yin

ACS Applied Polymer Materials· Volume 6· Issue 24
Publisher page

Abstract

This study explores an approach to incorporating polyrotaxane into solid polymer electrolytes (SPEs) through crosslinking with poly(ethylene glycol) (PEG). By leveraging the unique properties of polyrotaxane and the flexibility of PEG, we have developed SPEs with enhanced ionic conductivity, mechanical strength, and thermal stability. Our results indicate that the SPE film, containing equal weights of hydroxypropyl polyrotaxane (HyPR) and PEG with a molecular weight of 10000 Da, exhibits high thermal resistance above 150 °C, impressive flexibility with an elongation at break exceeding 550%, and an ionic conductivity of 2.715 × 10 –5 S cm –1 at 30 °C.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry

Beihang University

Funding

National Natural Science Foundation of China

References (68)

Show source-provided references
1. 10.1038/451652a10.1038/451652a ↗
2. 10.1039/C6CS00491A10.1039/C6CS00491A ↗
3. 10.1002/aenm.20170141510.1002/aenm.201701415 ↗
4. 10.1146/annurev-matsci-071312-12170510.1146/annurev-matsci-071312-121705 ↗
5. 10.1038/3510464410.1038/35104644 ↗
6. 10.3390/polym1011123710.3390/polym10111237 ↗
7. 10.1021/acsami.7b0603810.1021/acsami.7b06038 ↗
8. 10.1021/acs.nanolett.7b0033010.1021/acs.nanolett.7b00330 ↗
9. 10.1016/j.gee.2016.04.00610.1016/j.gee.2016.04.006 ↗
10. Painter, P. C.; Coleman, M. M. Essentials of Polymer Science and Engineering; DEStech Publications, 2009; pp. 205–237.
11. 10.1002/adma.20190562910.1002/adma.201905629 ↗
12. 10.1016/j.ensm.2020.08.01410.1016/j.ensm.2020.08.014 ↗
13. 10.1039/C5TA03471J10.1039/C5TA03471J ↗
14. Cowie J. M. G. · 1991
15. 10.1016/S0013-4686(99)00365-510.1016/S0013-4686(99)00365-5 ↗
16. 10.1016/0013-4686(92)80113-Z10.1016/0013-4686(92)80113-Z ↗
17. 10.1002/app.1994.07053120210.1002/app.1994.070531202 ↗
18. 10.1002/cssc.20150111010.1002/cssc.201501110 ↗
19. 10.1016/j.polymer.2017.06.07410.1016/j.polymer.2017.06.074 ↗
20. 10.1021/ma951909i10.1021/ma951909i ↗
21. 10.1021/ma981436q10.1021/ma981436q ↗
22. 10.1016/S0013-4686(00)00775-110.1016/S0013-4686(00)00775-1 ↗
23. 10.1002/app.3042310.1002/app.30423 ↗
24. 10.1021/acs.nanolett.5b0060010.1021/acs.nanolett.5b00600 ↗
25. 10.1002/adma.20180266110.1002/adma.201802661 ↗
26. 10.1016/S0167-2738(02)00036-X10.1016/S0167-2738(02)00036-X ↗
27. 10.1295/polymj.38.110.1295/polymj.38.1 ↗
28. 10.1021/jp304035q10.1021/jp304035q ↗
29. 10.1039/b705688e10.1039/b705688e ↗
30. 10.1295/polymj.PJ200623910.1295/polymj.PJ2006239 ↗
31. 10.1021/acs.chemrev.9b0083910.1021/acs.chemrev.9b00839 ↗
32. 10.1002/pola.2171710.1002/pola.21717 ↗
33. 10.1021/ma05029010.1021/ma050290 ↗
34. 10.1016/j.polymer.2018.05.07210.1016/j.polymer.2018.05.072 ↗
35. 10.1023/A:100920860367310.1023/A:1009208603673 ↗
36. 10.1002/(SICI)1521-3935(19981001)199:10<2311::AID-MACP2311>3.0.CO;2-T10.1002/(SICI)1521-3935(19981001)199:10<2311::AID-MACP2311>3.0.CO;2-T ↗
37. 10.1021/acs.biomac.0c0014810.1021/acs.biomac.0c00148 ↗
38. 10.1021/jo00414a03810.1021/jo00414a038 ↗
39. 10.1002/celc.20210010810.1002/celc.202100108 ↗
40. 10.1007/s10008000019010.1007/s100080000190 ↗
41. 10.1177/155892502098256910.1177/1558925020982569 ↗
42. 10.1021/ma100259t10.1021/ma100259t ↗
43. 10.1021/ma902161d10.1021/ma902161d ↗
44. 10.1021/acs.chemmater.8b0120810.1021/acs.chemmater.8b01208 ↗
45. 10.1021/ma00212a03910.1021/ma00212a039 ↗
46. 10.1016/j.ensm.2021.05.02310.1016/j.ensm.2021.05.023 ↗
47. 10.1007/978-94-015-7797-710.1007/978-94-015-7797-7 ↗
48. Tang, C. Chemical Modification Effects on Molecular Dynamics of Complex Poly(rotaxane) Investigated by Solid-state NMR, Master’s thesis, University of Akron, OhioLINK Electronic Theses and Dissertations Center, 2013.10.1021/ma401476g ↗
49. 10.1016/S0141-3910(00)00084-710.1016/S0141-3910(00)00084-7 ↗
50. 10.1007/BF0270676810.1007/BF02706768 ↗
51. Carraher C. E. · 2003
52. 10.1007/BF0155308510.1007/BF01553085 ↗
53. 10.1021/acs.macromol.0c0200910.1021/acs.macromol.0c02009 ↗
54. Smith B. C. · Spectroscopy · 2018 · 33 · 20
55. Smith B. C. · 1998
56. 10.1016/j.memsci.2015.10.00810.1016/j.memsci.2015.10.008 ↗
57. 10.3390/polym1008090210.3390/polym10080902 ↗
58. 10.1016/S0032-3861(02)00305-110.1016/S0032-3861(02)00305-1 ↗
59. 10.1063/1.45924010.1063/1.459240 ↗
60. 10.6028/jres.067A.04610.6028/jres.067A.046 ↗
61. 10.1021/acs.jpcc.6b1136210.1021/acs.jpcc.6b11362 ↗
62. 10.1016/0079-6700(94)00001-I10.1016/0079-6700(94)00001-I ↗
63. 10.1002/polb.2238410.1002/polb.22384 ↗
64. 10.1016/S0014-3057(98)00132-310.1016/S0014-3057(98)00132-3 ↗
65. 10.1016/j.polymer.2017.12.04610.1016/j.polymer.2017.12.046 ↗
66. 10.1016/j.electacta.2016.12.11310.1016/j.electacta.2016.12.113 ↗
67. 10.1016/j.memsci.2019.01.02510.1016/j.memsci.2019.01.025 ↗
68. 10.1016/j.jpowsour.2019.02.09010.1016/j.jpowsour.2019.02.090 ↗