journal article·2023-07-14

Photo-Degradable Functional Polyesters from an o-Nitrobenzyl Dithiol: Synthesis and Applications in Herbicide Delivery

Pengfei Shan, Daai Li, Wen Lu, Weilin Lu, Xiangping Yin, Xiaoyue Lian, Yingwen Lu, Yuxi Qi, Ming Zhang, Kaicheng Du, Guoquan Ma, Xuehao Wen, Ge Xin, Jiabin Jiang, Zhihui Li, Zhongyu Li

ACS Applied Polymer Materials· Volume 5· Issue 7
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Abstract

An o -nitrobenzyl dithiol and a group of diacrylates containing one or two functional groups were designed for facile synthesis of a series of linear photo-labile functional and heterobifunctional poly(β-thioester)s via thiol-ene click polymerization. These o -nitrobenzyl thioether-containing polyesters show excellent photo-degradation properties under UV light. Photo-responsive polymeric nanoparticles from a functional polyester exhibit good weeding performance as a herbicide delivery system. The possible photo-degradation mechanism of the polyesters was studied and proposed. The o -nitrobenzyl dithiol and its corresponding photo-labile polyesters could be used in smart drug or pesticide delivery, photo-labile graft copolymers synthesis, and even photolithography.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Photochromic and Fluorescence Chemistry · Advanced Polymer Synthesis and Characterization · Photopolymerization techniques and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325027, China

School of Optometry and Ophthalmology and Eye Hospital, State Key Laboratory of Optometry & Vision Science, Wenzhou Medical University, Wenzhou 325027, China

Funding

National Natural Science Foundation of China

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