A Zn-Based Coordination Polymer with Homogeneous Catalyst Properties for Efficient CO2 Fixation
Source abstract
Abstract
The development of efficient catalysts for the catalytic conversion of CO 2 is extremely important in the process of CO 2 chemistry. In this work, a Zn-based coordination polymer (ZnBr 2 -CP) was synthesized from a tridentate pyridine ligand bearing an imidazolium salt ligated with ZnBr 2 . It possesses not only the high activity of homogeneous catalysts but also the recoverable features of heterogeneous catalysts. More importantly, configured double active sites allow the catalyst ZnBr 2 -CP to exhibit excellent activity in the cycloaddition of CO 2 with epoxides under solvent- and co-catalyst-free conditions, achieving yields as high as 99% for a variety of cyclic carbonates at 80 °C for 24 h. This study provides insight into the design of efficient catalysts for conversion of CO 2 .
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Carbon dioxide utilization in catalysis · Metal-Organic Frameworks: Synthesis and Applications · Chemical Synthesis and Reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Green Chemical and Clean Energy Technology, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang, Guizhou 550025, P. R. China
Engineering Research Center of Efficient Utilization for Industrial Waste, Guizhou University, Guiyang, Guizhou 550025, China
Funding
Department of Education of Guizhou Province · Guizhou University · National Natural Science Foundation of China · Innovation and Entrepreneurship Training Program for College Students in Guizhou Province · Key Laboratory of Carbon-Based Energy and Molecular Chemical Engineering Utilization Technology in Higher Education Institutions in Guizhou Province
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