journal article·2023-10-13

Tough, Healable, Photoresponsive Actuator Based on a Quadruple Hydrogen-Bond-Capped Slide-Ring Structure

Dandan Tian, Wenjing Ma, Lingji Zheng, Kaixuan Jiang, Hu He, Ruyi Sun

ACS Applied Polymer Materials· Volume 5· Issue 10
Publisher page

Abstract

A tough self-healing supramolecular photoresponsive actuator based on a 2-urea-4[1 H ]-pyrimidinone (UPy)-terminated host–guest slide-ring structure was designed. The supramolecular gel was revealed to be stretchable and tough. It achieved a tensile strength of 2.25 MPa with elongation at break of 533% and could lift beyond 900 times its own weight. Based on the special structure, its photoresponsive motion was as fast as 55° within 40 s under 365 nm irradiation. The gel also showed highly efficient self-healable ability and quick responsivity to temperature and humidity.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supramolecular Self-Assembly in Materials · Hydrogels: synthesis, properties, applications · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Molecular Engineering, East China Normal University, 500 Dongchuan Road, Shanghai 200241, People’s Republic of China

Hangzhou SynRx Therapeutics Biomedical Technology Co., Ltd, 1390 Cangxing Road, Cangqian Street, Yuhang District, Hangzhou, Zhejiang 311121, People’s Republic of China

Funding

Natural Science Foundation of Shanghai Municipality

References (29)

Show source-provided references
1. 10.1021/acs.chemrev.1c0033010.1021/acs.chemrev.1c00330 ↗
2. 10.1038/s41467-020-18520-710.1038/s41467-020-18520-7 ↗
3. 10.1039/D2SC00082B10.1039/D2SC00082B ↗
4. 10.1021/ja104446r10.1021/ja104446r ↗
5. 10.1002/smll.20220173710.1002/smll.202201737 ↗
6. 10.1039/C9PY01471C10.1039/C9PY01471C ↗
7. 10.1002/anie.20220354110.1002/anie.202203541 ↗
8. 10.1039/D0CS01166E10.1039/D0CS01166E ↗
9. 10.1016/j.matt.2020.11.01810.1016/j.matt.2020.11.018 ↗
10. 10.1021/acsami.7b0720410.1021/acsami.7b07204 ↗
11. 10.1248/cpb.c16-0087410.1248/cpb.c16-00874 ↗
12. 10.1002/adma.20190606410.1002/adma.201906064 ↗
13. 10.1039/C4RA13283A10.1039/C4RA13283A ↗
14. 10.1021/acs.chemmater.8b0120810.1021/acs.chemmater.8b01208 ↗
15. 10.1039/D0TC00551G10.1039/D0TC00551G ↗
16. 10.1021/acsapm.1c0023010.1021/acsapm.1c00230 ↗
17. 10.1021/acsapm.1c0133210.1021/acsapm.1c01332 ↗
18. 10.1021/ja500205v10.1021/ja500205v ↗
19. 10.1021/acs.macromol.1c0029510.1021/acs.macromol.1c00295 ↗
20. 10.1021/acs.biomac.1c0011110.1021/acs.biomac.1c00111 ↗
21. 10.1021/acsbiomaterials.0c0001010.1021/acsbiomaterials.0c00010 ↗
22. 10.1021/jacs.8b1135110.1021/jacs.8b11351 ↗
23. 10.1021/acs.macromol.8b0093910.1021/acs.macromol.8b00939 ↗
24. 10.1021/acsami.8b1000110.1021/acsami.8b10001 ↗
25. 10.1021/acsmacrolett.7b0072910.1021/acsmacrolett.7b00729 ↗
26. 10.1002/pola.2849010.1002/pola.28490 ↗
27. 10.1039/c4ra00165f10.1039/c4ra00165f ↗
28. 10.1002/marc.20200037110.1002/marc.202000371 ↗
29. 10.1021/acsmacrolett.9b0099610.1021/acsmacrolett.9b00996 ↗