journal article·2023-10-13Open access

Fluorosilicone Composites with Functionalized Graphene Oxide for Advanced Applications

Ernesto Aguila-Toledo, Santiago Maldonado-Magnere, Mehrdad Yazdani-Pedram, Allan Bascuñan-Heredia, Mohamed Redoine Dahrouch, Francisco Molina, Marianella Hernández Santana, Raquel Verdejo, Miguel A. Lopez-Manchado, Héctor Aguilar-Bolados

ACS Applied Polymer Materials· Volume 5· Issue 10

Abstract

In this work, we develop fluorosilicone elastomer (FSE) compounds with advanced properties by incorporating graphene oxides functionalized with vinyltrimethoxysilane (GO-V) and allyl isocyanate (GO-A). The morphology and structure of the graphene oxides were characterized confirming the successful functionalization, with contents of functional groups of 9.80 and 3.60% for GO-V and GO-A, respectively. The strong elastomer–graphene oxide interaction accelerates the crosslinking reaction and causes an important enhancement of the mechanical properties and thermal stability of composites. In addition, the swelling resistance to acid, base, and organic solvents is improved by more than 30%. These functional properties make FSE/GO composites a promising new class of advanced materials, expanding their potential application in edge technologies, spanning the manufacture of automotive components, aerospace and aviation parts, oil, gas, and petrochemical components, among others, particularly, seals, gaskets, valves and pipelines, or different components exposed to oil or solvent and high temperatures that require higher performance compared to conventional FSE products.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Tribology and Wear Analysis · Silicone and Siloxane Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Olivos 1007, Santiago 8380544, Chile

Departamento de Polímeros, Facultad de Ciencias Químicas, Universidad de Concepción, Concepción 3349001, Chile

Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Concepción, Concepción 3349001, Chile

Centro de Investigación en Física Nuclear y Espectroscopia de Neutrones CEFNen, Comisión Chilena de Energía Nuclear, Nueva Bilbao 12501, Santiago 7600713, Chile

Millennium Institute for Subatomic physics at high energy frontier − SAPHIR, Fernandez Concha 700, Santiago 7591538, Chile

Instituto de Ciencia y Tecnología de Polímeros (ICTP), CSIC, Juan de la Cierva, 3, 28006 Madrid, Spain

Funding

Fondo Nacional de Desarrollo Cient?fico y Tecnol?gico · Agencia Nacional de Investigaci?n y Desarrollo

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