DataVXACS Applied Polymer MaterialsPaper
journal article·2019-02-08

Sub-100 nm Cocontinuous Structures Fabricated in Immiscible Commodity Polymer Blend with Extremely Low Volume/Viscosity Ratio

Fei Li, Xuewen Zhao, Hengti Wang, Qin Chen, Shuhua Wang, Zhenhua Chen, Xiaoyong Zhou, Wenchun Fan, Yongjin Li, Jichun You

ACS Applied Polymer Materials· Volume 1· Issue 2
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Source abstract

Abstract

Sub-100 nm cocontinuous structures were prepared successfully in poly(vinylidene fluoride)/poly(l-lactic acid) (PVDF/PLLA) blend with extremely low volume/viscosity ratio by melting blending. The reactive compatibilizer with poly(methyl methacrylate) (PMMA) side chains and random epoxide groups plays an important role in the formation and the size decrease of these structures. On one hand, PMMA side chains exhibit excellent entanglement with PVDF; on the other hand, the epoxide groups can react with carboxyl group of PLLA. The resultant comb-like compatibilizer exhibits greater capacity to maintain the stress balance on two sides. The repulsion state of the binary brushes enlarges the interface curvature radius, dominating the formation of cocontinuous structures.
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Research context

Polymers

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · biodegradable polymer synthesis and properties · Surface Modification and Superhydrophobicity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, People’s Republic of China

Zhejiang Juhua Technology Center Co., Ltd, Quzhou 324004, People’s Republic of China

Zhejiang Juhua Research Institute of New Materials Co., Ltd. No. 258, Juxian Street, Hanghzou 311321, People’s Republic of China

Funding

Ministry of Science and Technology of the People's Republic of China · Science and Technology Department of Zhejiang Province · National Natural Science Foundation of China · Natural Science Foundation of Zhejiang Province

References (30)

Show source-provided references
1. 10.1016/j.biomaterials.2004.01.06510.1016/j.biomaterials.2004.01.065 ↗
2. 10.1038/pj.2012.1510.1038/pj.2012.15 ↗
3. 10.1016/j.polymer.2005.10.02210.1016/j.polymer.2005.10.022 ↗
4. 10.1016/j.polymer.2017.02.09310.1016/j.polymer.2017.02.093 ↗
5. 10.1002/pen.76028120510.1002/pen.760281205 ↗
6. 10.1002/pen.76026080210.1002/pen.760260802 ↗
7. 10.1021/acs.iecr.6b0030410.1021/acs.iecr.6b00304 ↗
8. 10.1122/1.490571410.1122/1.4905714 ↗
9. 10.1016/j.polymer.2008.06.00310.1016/j.polymer.2008.06.003 ↗
10. 10.1002/marc.20080057910.1002/marc.200800579 ↗
11. 10.1021/ma102671910.1021/ma1026719 ↗
12. 10.1016/0032-3861(88)90388-610.1016/0032-3861(88)90388-6 ↗
13. 10.1021/ma801390s10.1021/ma801390s ↗
14. 10.1021/acs.langmuir.8b0250310.1021/acs.langmuir.8b02503 ↗
15. 10.1021/acssuschemeng.6b0142010.1021/acssuschemeng.6b01420 ↗
16. 10.1021/ie503645a10.1021/ie503645a ↗
17. 10.1039/C4RA03936J10.1039/C4RA03936J ↗
18. 10.1016/j.polymer.2017.02.09310.1016/j.polymer.2017.02.093 ↗
19. 10.1021/ma402603b10.1021/ma402603b ↗
20. 10.1016/S0032-3861(99)00337-710.1016/S0032-3861(99)00337-7 ↗
21. 10.1021/ma60048a04010.1021/ma60048a040 ↗
22. 10.1016/0032-3861(94)90691-210.1016/0032-3861(94)90691-2 ↗
23. 10.1016/j.polymertesting.2015.04.00810.1016/j.polymertesting.2015.04.008 ↗
24. 10.1016/S0032-3861(97)10200-210.1016/S0032-3861(97)10200-2 ↗
25. 10.1021/ma960248210.1021/ma9602482 ↗
26. 10.1021/ma010104+10.1021/ma010104+ ↗
27. 10.1016/S0032-3861(99)00038-510.1016/S0032-3861(99)00038-5 ↗
28. 10.1016/0032-3861(95)91438-D10.1016/0032-3861(95)91438-D ↗
29. 10.1002/pen.2003710.1002/pen.20037 ↗
30. Paul, D. R.; Barlow, J. W. Polymer Blends and Alloys; Blackie Academic & Professional: 1980; Vol 18, pp 109–168.10.1080/00222358008080917 ↗