Development of Intricate Aerogel Articles Using Fused Filament Fabrication

A fused filament fabrication process is used for conversion of polyimide aerogels into bicontinuous gyroid structures to obtain enhanced elasticity. A sacrificial hollow mold in an inverse gyroid shape is first fabricated from high impact polystyrene and is filled with the polyimide sol. After the sol–gel transition, the mold is dissolved in a solvent to yield the gel structure of a gyroid shape. The gel is supercritically dried to recover a free-standing aerogel structure with ultrahigh porosity (98.9%) and low bulk density (0.0146 g/cm3). The bicontinuous gyroid structure of the aerogel offers significant elasticity and high elongation at break compared to an otherwise brittle monolithic aerogel of polyimide. The ability to create intricate aerogel structures opens up a large potential in applications such as sensor housing and acoustic barriers of arbitrary shape and size and load-bearing porous thermally insulating structures that allow breathing.