journal article·2020-12-11

A Pillar[5]arene Conjugated Polymer for Removal of Low-Molecular-Weight Organic Acids, Amines, and Alcohols from Water

Zhuo Wang, Tao Chen, Guo Wang, Wei-Bo Hu, Yahu A. Liu, Hui Yang, Ke Wen

ACS Applied Polymer Materials· Volume 2· Issue 12
Publisher page

Abstract

We have fabricated a pillar[5]arene-based conjugated polymer, pillar[4]arene[1]terephthalic acid-derivatized poly-p-phenylene pillar[4]arene[1]terephthamide (P[5]-PPTA), which demonstrated exceptional adsorption capability toward low-molecular-weight alkylamines, alcohols, and carboxylic acids in water. In addition, P[5]-PPTA could be thermally reactivated and reused at least five times without obvious decrease of adsorption capability. A mechanistic study indicated that the absorption results from the host–guest interaction between the pillar[5]arene rings in P[5]-PPTA and the low-molecular-weight short-chain alkyl derivatives.
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Research context

OpenAlex topics: Supramolecular Chemistry and Complexes · Supramolecular Self-Assembly in Materials · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

University of Chinese Academy of Sciences, Beijing 100049, China

Medicinal Chemistry, ChemBridge Research Laboratories, San Diego, California 92127, United States

Funding

Ministry of Science and Technology of the People's Republic of China · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China

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