Low-Basis Weight Polyacrylonitrile/Polyvinylpyrrolidone Blend Nanofiber Membranes for Efficient Particulate Matter Capture

Particulate matter (PM) in air frequently poses a serious threat to human health. Smaller PM can easily enter into the alveolus and blood vessels with airflow. This work reports the first polyacrylonitrile (PAN)/polyvinylpyrrolidone (PVP) polymer blend nanofiber filter media for effectively capturing PM. Density functional theory (DFT) calculations are used to investigate the effect of the blending of two polymers on the dipole moment and the electrostatic potential. Based on the DFT calculations of the intermolecular interactions between nanofibers and PM, the PAN/PVP heteromolecular percentage is considered for experimental synthesis, which can provide better performance in the filtration of pollutants. The composite PAN/PVP fiber network was successfully developed and optimized to cope with complex environments during the actual filtration process. The role of the blending ratio of PAN and PVP in wt % was explored on PM2.5 capture, and the refined ratio overcame the conflict between high filtration efficiency and low air pressure resistance. The air filter medium PAN/PVP (6:2) possesses an extremely high air filtration efficiency of 92% under a very low pressure drop of 18 Pa for a 0.5 g m–2 basis weight. Both polar and nonpolar functional groups in blend nanofibers promoted significantly the electrostatic attraction and improved the filtration efficiency under static and dynamic airflow. The PAN/PVP nanofiber membranes maintain outstanding air filtration under different temperature and humidity conditions. This study will shed light on the fabrication of high-efficiency low-basis weight nanofiber filter media as an end product.