journal article·2021-10-08

Synthesis and Characterization of Polyphosphonates and Polyurethanes Using Chalcone and DOPO-Chalcone as a Flame Retardant

Ilay C. Çetinkaya, Gamze Yüksel, Caner Macit, Mustafa E. Üreyen, Tarik Eren

ACS Applied Polymer Materials· Volume 3· Issue 10
Publisher page

Abstract

We synthesized a series of chalcone-based polyphosphonates and polyurethanes as self-extinguishing flame-retardant polymers and characterized them via FTIR, 1H, 13C, 31P NMR, HRMS, gel permeation chromatography, and inductively coupled plasma–optical emission spectrometry. The thermal stability of the synthesized polymer series was tested by thermogravimetric and evolved gas analysis under both N2 and air atmospheres as well as microscale combustion calorimetry analysis. After thermal treatment, residue analysis was carried out using scanning electron microscopy with energy-dispersive X-ray analysis and X-ray photoelectron spectroscopy, and decomposition mechanisms are proposed.
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Research context

OpenAlex topics: Flame retardant materials and properties · Synthesis and properties of polymers · Synthesis of Organic Compounds

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Faculty of Arts and Science, Yildiz Technical University, Davutpaşa Campus, Esenler, Istanbul 34220, Turkey

Department of Materials Science and Engineering, Institute of Graduate Programs, Eskisehir Technical University, Iki Eylul Campus, Eskisehir 26555, Turkey

Department of Fashion and Textile Design, Faculty of Architecture and Design, Eskisehir Technical University, Eskisehir 26555, Turkey

Advanced Technologies Research Centre (ITAM), Eskisehir Technical University, Eskisehir 26555, Turkey

Funding

Yildiz Teknik ??niversitesi

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