journal article·2020-11-13Open access

Antimicrobial and Antibiofilm Properties of Fluorinated Polymers with Embedded Functionalized Nanodiamonds

João Nunes-Pereira, Pedro Costa, Liliana Fernandes, Estela O. Carvalho, Margarida M. Fernandes, Sónia A. C. Carabineiro, Josephus G. Buijnsters, Carmen R. Tubio, Senentxu Lanceros-Mendez

ACS Applied Polymer Materials· Volume 2· Issue 11

Abstract

Environmentally resilient antimicrobial coatings are becoming increasingly required for a wide range of applications. For this purpose, nanocomposite thin films of poly(vinylidene fluoride) (PVDF) filled with several types of functionalized nanodiamonds (NDs) were processed by solvent casting. The effects of ND inclusion and functionalization in their morphological, structural, optical, thermal, and electrical properties were evaluated taking into account the type of the nanofiller and a concentration up to 2 wt %. The morphology, structure, and thermal features of the polymer matrix are governed by the processing conditions, and no noticeable changes occurred due to the presence of the ND fillers. The polymer crystallized mainly in the α phase with a crystallinity of ≈60%. In turn, the optical transmittance from 200 to 800 nm and the dielectric constant effectively depended on the ND type and content. The inclusion of the ND particles effectively provided antimicrobial properties to the films, which depended on the ND functionalization. This study thus shows that the incorporation of functionalized NDs into PVDF allows the development of antimicrobial coatings with tailorable optical and dielectric properties, which could be of great importance to face nowadays pandemic crisis scenario.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Diamond and Carbon-based Materials Research · Polymer Nanocomposite Synthesis and Irradiation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre for Mechanical and Aerospace Science and Technologies (C-MAST), Universidade da Beira Interior, Rua Marquês d’Ávila e Bolama, 6200-001 Covilhã, Portugal

Centro de Física das Universidades do Minho e do Porto (CF-UM-UP), Campus de Gualtar, 4710-057 Braga, Portugal

Institute for Polymers and Composites IPC/I3N, University of Minho, 4800-058 Guimarães, Portugal

Centre of Biological Engineering, University of Minho, Campus de Gualtar, 4710-057 Braga, Portugal

LAQV-REQUIMTE, Department of Chemistry, NOVA School of Science and Technology, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal

Department of Precision and Microsystems Engineering, Micro and Nano Engineering, Delft University of Technology, 2628 CD Delft, The Netherlands

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

IKERBASQUE, Basque Foundation for Science, 48009 Bilbao, Spain

Funding

Ministerio de Ciencia, Innovaci?n y Universidades · European Regional Development Fund · European Social Fund · Funda??o para a Ci?ncia e a Tecnologia · Nederlandse Organisatie voor Wetenschappelijk Onderzoek · Basque Government Industry and Education Departments

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