journal article·2022-04-08

Hydrophilic Channel Volume Behavior on Proton Transport Performance of Proton Exchange Membrane in Fuel Cells

Xiangyu Huang, Shengqiu Zhao, Hao Liu, Rui Wang, Haolin Tang

ACS Applied Polymer Materials· Volume 4· Issue 4
Publisher page

Abstract

Inadequate water balance causes water flooding in a fuel cell, leading to performance degradation. The hydrophilic channel volume is crucial to the proton conductivity of PEM, especially under a high water concentration gradient. Herein, the volume of the hydrophilic channel was controlled and optimized through adjusting the collocation of resins with different side-chain lengths, with the length acting as a key parameter for the in-depth research on the proton conductivity performance of PEMs. Membranes with different hydrophilic channel volumes were prepared and suggested that the volume of the hydrophilic channel boosted as the increase of the length gap between the matched side chains, which would benefit to proton conductivity of membrane. This study provides guidance for the structural design of proton exchange membrane with cell-flooding resistance and efficient proton conduction at a high water concentration gradient.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fuel Cells and Related Materials · Electrocatalysts for Energy Conversion · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

State Power Investment Corporation Hydrogen Energy Technology Development Company, Ltd., Beijing 102209, China

Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, China

Guangdong Hydrogen Energy Institute of WHUT, Xianhu Hydrogen Valley, Foshan 528200, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Guangdong Province · Guangdong Basic and Applied Basic Research Foundation · Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory

References (49)

Show source-provided references
1. 10.1016/j.rser.2017.09.08110.1016/j.rser.2017.09.081 ↗
2. 10.1039/C9RE00142E10.1039/C9RE00142E ↗
3. 10.1016/j.jpowsour.2019.22703510.1016/j.jpowsour.2019.227035 ↗
4. 10.1021/acs.chemrev.6b0015910.1021/acs.chemrev.6b00159 ↗
5. 10.1016/j.jpowsour.2020.22783910.1016/j.jpowsour.2020.227839 ↗
6. 10.3390/membranes1106039510.3390/membranes11060395 ↗
7. 10.1016/j.memsci.2016.09.03310.1016/j.memsci.2016.09.033 ↗
8. Majsztrik P. W. · Dissertations & Theses Gradworks · 2008 · 141 · 235
9. 10.1021/jp111212510.1021/jp1112125 ↗
10. 10.1021/acsenergylett.0c0208910.1021/acsenergylett.0c02089 ↗
11. 10.1016/j.jpowsour.2018.05.01310.1016/j.jpowsour.2018.05.013 ↗
12. 10.1016/j.memsci.2010.03.02510.1016/j.memsci.2010.03.025 ↗
13. 10.1021/acs.nanolett.1c0081310.1021/acs.nanolett.1c00813 ↗
14. 10.1021/acsami.8b0151310.1021/acsami.8b01513 ↗
15. 10.1038/nmat207410.1038/nmat2074 ↗
16. 10.1002/pol.1981.18019110310.1002/pol.1981.180191103 ↗
17. 10.1021/jp911972e10.1021/jp911972e ↗
18. 10.1002/cphc.20060070410.1002/cphc.200600704 ↗
19. 10.1021/jp504714d10.1021/jp504714d ↗
20. 10.1021/jp400693g10.1021/jp400693g ↗
21. 10.1016/j.memsci.2007.03.02610.1016/j.memsci.2007.03.026 ↗
22. 10.1039/c2cp24132c10.1039/c2cp24132c ↗
23. 10.1016/j.memsci.2018.09.06310.1016/j.memsci.2018.09.063 ↗
24. 10.1039/C6RA17477A10.1039/C6RA17477A ↗
25. 10.1039/c3ra41976b10.1039/c3ra41976b ↗
26. 10.1016/j.polymer.2018.05.03310.1016/j.polymer.2018.05.033 ↗
27. 10.1002/polb.2354010.1002/polb.23540 ↗
28. 10.1007/s10853-020-05678-010.1007/s10853-020-05678-0 ↗
29. 10.1149/2.1361805jes10.1149/2.1361805jes ↗
30. 10.1021/jp710843410.1021/jp7108434 ↗
31. 10.1016/j.jpowsour.2019.22690610.1016/j.jpowsour.2019.226906 ↗
32. 10.1021/ma991270910.1021/ma9912709 ↗
33. 10.1016/j.polymer.2018.09.01410.1016/j.polymer.2018.09.014 ↗
34. 10.1016/j.polymer.2005.06.01010.1016/j.polymer.2005.06.010 ↗
35. 10.1016/j.jpowsour.2017.04.05110.1016/j.jpowsour.2017.04.051 ↗
36. 10.1021/ma000464h10.1021/ma000464h ↗
37. 10.1021/acsomega.9b0243610.1021/acsomega.9b02436 ↗
38. Hosemann R. · 1962
39. 10.1021/ma60033a00710.1021/ma60033a007 ↗
40. 10.1016/j.ssi.2009.11.00110.1016/j.ssi.2009.11.001 ↗
41. 10.1021/la051926t10.1021/la051926t ↗
42. 10.1016/j.memsci.2019.11724710.1016/j.memsci.2019.117247 ↗
43. 10.1039/C3RA43735C10.1039/C3RA43735C ↗
44. 10.1016/j.memsci.2016.07.02110.1016/j.memsci.2016.07.021 ↗
45. 10.1016/j.memsci.2011.12.00410.1016/j.memsci.2011.12.004 ↗
46. 10.1149/1.139387910.1149/1.1393879 ↗
47. 10.1016/j.jpowsour.2006.06.02310.1016/j.jpowsour.2006.06.023 ↗
48. 10.1016/j.jpowsour.2014.01.09610.1016/j.jpowsour.2014.01.096 ↗
49. 10.1002/polb.2379410.1002/polb.23794 ↗