Supramolecular Cross-Linking of Thiophenylene Polymers via Multiple Hydrogen Bonds toward High Refractive Index
Source abstract
Abstract
Dihydroxy-substituted poly(phenylene sulfide) ( DOHPPS ) was synthesized via oxidative polymerization of bis(2,6-dimethoxyphenyl) disulfide and subsequent deprotection. The synergistic effect of multiple-hydrogen-bond cross-links and the rigidity of the thiophenylene backbone afforded dense yet amorphous supramolecular networks, resulting in a polymer with visible transparency and an ultrahigh refractive index ( n D = 1.85).
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Synthesis and properties of polymers · Silicone and Siloxane Chemistry · Epoxy Resin Curing Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Applied Chemistry and Research Institute for Science and Engineering, Waseda University, Tokyo, 169-8555, Japan
Funding
Ministry of Education, Culture, Sports, Science and Technology · Waseda Research Institute for Science and Engineering
References (29)
Show source-provided references
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