journal article·2022-01-14

Methacrylated Quinizarin Derivatives for Visible-Light Mediated Photopolymerization: Promising Applications in 3D-Printing Biosourced Materials under LED@405 nm

Louise Breloy, Vlasta Brezová, Zuzana Barbieriková, Yoshihiro Ito, Jun Akimoto, Annalisa Chiappone, Samir Abbad-Andaloussi, Jean-Pierre Malval, Davy-Louis Versace

ACS Applied Polymer Materials· Volume 4· Issue 1
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Abstract

The high initiating properties of mono- (Q-1Ac) and dimethacrylated (Q-2Ac) quinizarin derivatives under visible-light irradiation are reported here. Associated with various co-initiators, such as iodonium salt (electron acceptor), an amine derivative (electron donor), or thiol cross-linker (H-donor), the quinizarin-derived photosensitizers lead to high conversions by radical photopolymerization in laminate or under air. Mechanisms of photoinitiation were deeply investigated by fluorescence, laser flash photolysis (LFP) and electron paramagnetic resonance (EPR) experiments. The use of soybean oil acrylate (SOA) as biobased monomer leads to highly cross-linked materials under visible-light, with comparable mechanical properties than UV-induced ones previously described in literature. Copolymerization of the photosensitizer (PS) with the polymer matrix not only prevents leakage, but also ensures antiadhesion properties of SOA materials against Staphylococcus aureus (S. aureus) under visible-light activation. Finally, complex 3D biobased structures are successfully obtained by 3D-printing under visible-light irradiation (LED@405 nm), opening opportunities to design photoinduced biosourced materials.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Photopolymerization techniques and applications · Dental materials and restorations · Advanced Polymer Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institut de Chimie et des Matériaux Paris-Est (ICMPE) − UMR-CNRS 7182, Equipe Systèmes Polymères Complexes (SPC), 2-8 rue Henri Dunant, 94320 Thiais, France

Faculty of Chemical and Food Technology, Institute of Physical Chemistry and Chemical Physics, Department of Physical Chemistry, Slovak University of Technology in Bratislava, Radlinského 9, SK-812 37 Bratislava, Slovak Republic

Nano Medical Engineering Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan

Politechnico di Torino, Dipartimento di Scienza Applicata e Tecnologia, C. so Duca degli Abruzzi 24, 10129 Torino, Italy

Laboratoire Eau, Environnement, Systèmes Urbains (LEESU), UMR-MA 102, Université Paris-Est Créteil (UPEC), 61 avenue Général de Gaulle, 94010 Créteil Cedex, France

Institut de Chimie et des Matériaux de Mulhouse (IS2M) -UMR 7361, 15 rue Jean Starcky, BP 2488, 68057 Mulhouse Cedex, France

Funding

Agence Nationale de la Recherche · Vedeck?? Grantov?? Agent??ra M??VVa?? SR a SAV · Ministerstvo ??kolstva, vedy, v??skumu a ??portu Slovenskej republiky · Universit?? Paris-Est Cr??teil Val-de-Marne

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