journal article·2022-05-13

Fused Heterocyclic Polymers with Aggregation-Induced Emission: Synthesis and Applications

Dongyang Fan, Dong Wang, Ting Han, Ben Zhong Tang

ACS Applied Polymer Materials· Volume 4· Issue 5
Publisher page

Abstract

Fused heterocyclic polymers with aggregation-induced emission (AIE) have attracted much attention due to their unique photoelectric properties, efficient aggregate-state fluorescence, high thermal stability, and superamplification effect as fluorescence sensors as well as multiple functionalities. Among various synthetic methodologies toward fused heterocyclic AIE polymers, polymerization based on triple bond-containing monomers such as alkynes and (iso)cyanides is a powerful synthesis tool that can in situ generate fused heterocyclic units in polymer backbones in high efficiency. In this Review, we summarize the recent progress in the synthesis of nitrogen-, oxygen-, and multiple heteroatom-containing fused cyclic polymers with AIE features based on polymerizations of triple bond-containing monomers. Furthermore, the high-tech applications of the corresponding fused heterocyclic AIE polymers in the visualization of morphological structures, fluorescence chemo-sensors, stimuli-responsive materials, and photodynamic therapy are illustrated. Finally, perspectives on the challenges and future development directions of this field are discussed.
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Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Organic Light-Emitting Diodes Research · Organic Electronics and Photovoltaics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center for AIE Research, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China

College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China

Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong 999077, China

Shenzhen Institute of Aggregate Science and Technology, School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong 518172, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Guangdong Province · Science and Technology Plan of Shenzhen

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