journal article·2022-11-11

Electrospun Cellulose Acetate/Polyethylenimine Porous Fibers toward Highly Efficient Removal of Cr(VI)

Dan Luo, Shao-zhong Hu, Ting Huang, Nan Zhang, Yan-zhou Lei, Yong Wang

ACS Applied Polymer Materials· Volume 4· Issue 11
Publisher page

Abstract

The development of an efficient, economical, and environmentally friendly monolithic adsorbent for the removal of toxic hexavalent chromium Cr(VI) has invariably been a topic of great concern to researchers. In this paper, cellulose acetate (CA) and polyethylenimine (PEI) homogeneously blending porous fiber membranes with high porosity were successfully prepared by electrospinning, and PEI was further immobilized by cross-linking to form a stable biological adsorbent. The adsorption behavior and eliminating mechanism toward Cr(VI) by the CA-c-PEI fibrous membranes were comprehensively explored. The maximum adsorption capacity was up to 285.7 mg/g (25 °C), higher than most of the biomass-based adsorbents. Specifically, the concentration of Cr(VI) could be dramatically reduced from the initial 50 mg/L to 0.03 mg/L, much lower than the concentration standard for drinking water recommended by the World Health Organization. Even after being reused several times, the fibrous membrane still exhibited high removal efficiency.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Graphene and Nanomaterials Applications · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science & Engineering, Key Laboratory of Advanced Technologies of Materials (Ministry of Education), Southwest Jiaotong University, Chengdu 610031, China

Analytical and Testing Center, Southwest Jiaotong University, Chengdu 610031, China

Funding

National Natural Science Foundation of China · Youth Science and Technology Innovation Team of Sichuan Province of Functional Polymer Composites · Sichuan Science and Technology Program

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