journal article·2025-10-24

Continuous Heat Generation during Polymer Friction: Aperiodic Conformational Fluctuations of Molecular Chains

Gai Zhao, Tianqiang Yin, Jingfu Song, Guoqing Wang, Fan Xue, Qingjun Ding

ACS Applied Polymer Materials· Volume 7· Issue 20
Publisher page

Abstract

The accumulation of frictional heat significantly influences the tribological properties of polymeric materials. However, the microscopic mechanism underlying its generation remains unclear, which poses a major obstacle to the investigation and development of polymer-based friction materials. To address this, we investigated the frictional heating behavior of polymers using molecular dynamics simulations. The results reveal that the conversion between potential and kinetic energy, driven by the aperiodic conformational fluctuations of polymer molecular chains, contributes to the continuous generation of frictional heat. Building on this finding, we further examined the microscopic mechanisms by which various friction conditions─namely, sliding velocity, contact pressure, and ambient temperature─affect thermogenesis. This study not only establishes a theoretical foundation for the design and development of advanced polymer friction materials but also offers potential insights for the development of thermal management strategies in polymer-based friction systems.
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Research context

OpenAlex topics: Force Microscopy Techniques and Applications · Adhesion, Friction, and Surface Interactions · Polymer crystallization and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Mechanics and Control for Aerospace Structures

Nanjing University of Aeronautics and Astronautics

School of Naval Architecture & Ocean Engineering

Jiangsu Maritime Institute

College of Mechanical and Electronic Engineering

Nanjing Forestry University

Funding

National Natural Science Foundation of China · Priority Academic Program Development of Jiangsu Higher Education Institutions · State Key Laboratory of Mechanics and Control for Aerospace Structures (Nanjing University of Aeronautics and astronautics)

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