journal article·2024-04-08

Anisotropic optical conductivity accompanied by a small energy gap in the one-dimensional thermoelectric telluride Ta4SiTe4

Fumiya Matsunaga, Yoshihiko Okamoto, Yasunori Yokoyama, Kanji Takehana, Yasutaka Imanaka, Yuto Nakamura, Hideo Kishida, Shoya Kawano, Kazuyuki Matsuhira, Koshi Takenaka

Physical Review B· Volume 109· Issue 16
Publisher page

Abstract

We investigated the optical properties of single crystals of one-dimensional van der Waals crystal ${\mathrm{Ta}}4{\mathrm{SiTe}}4$, which exhibited high thermoelectric performance below room temperature. Optical conductivity estimated from reflectivity spectra indicates the presence of a small energy gap of 0.1--0.15 eV at the Fermi energy. At the lowest energy, optical conductivity along the ${\mathrm{Ta}}4{\mathrm{SiTe}}4$ chain is an order of magnitude higher than that perpendicular to this direction, reflecting anisotropic electron conduction in ${\mathrm{Ta}}4{\mathrm{SiTe}}4$. These results suggest that the coexistence of a small band gap and moderate anisotropy in electron conduction is a promising strategy for developing high-performance thermoelectric materials for low-temperature applications.
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Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · 2D Materials and Applications · Topological Materials and Phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Physics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464–8603, Japan

Institute for Solid State Physics, University of Tokyo, Kashiwanoha 5-1-5, Kashiwa 277–8581, Japan

National Institute for Materials Science (NIMS), Sakura 3–13, Tsukuba 305-0003, Japan

Graduate School of Engineering, Kyushu Institute of Technology, Kitakyushu 804–8550, Japan

Funding

Japan Society for the Promotion of Science · Japan Science and Technology Corporation · Research Foundation for the Electrotechnology of Chubu · University of Tokyo

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