journal article·2024-02-26

Effect of physical and chemical pressure on the superconductivity of cage-type compound Lu5Rh6Sn18

Chao Xiong, Cuiying Pei, Qi Wang, Juefei Wu, Yi Zhao, Yuyang Jiang, Changhua Li, Weizheng Cao, Na Yu, Lili Zhang, Yanpeng Qi

Physical Review B· Volume 109· Issue 7
Publisher page

Abstract

${\mathrm{Lu}}5{\mathrm{Rh}}6{\mathrm{Sn}}18$ is one of the cage-type superconductors with superconducting transition temperature ${T}c=4.12$ K. Here we investigate the effect of pressure on the superconductivity in ${\mathrm{Lu}}5{\mathrm{Rh}}6{\mathrm{Sn}}18$ by combining high-pressure electrical transport, synchrotron x-ray diffraction (XRD), and chemical doping. Application of high pressure can enhance both the metallicity and the superconducting transition temperature in ${\mathrm{Lu}}5{\mathrm{Rh}}6{\mathrm{Sn}}18$. ${T}c$ is found to show a continuous increase reaching up to 5.50 K at 11.4 GPa. Our high-pressure synchrotron XRD measurements demonstrate the stability of the pristine crystal structure up to 12.0 GPa. In contrast, ${T}c$ is suppressed after the substitution of La ions in Lu sites, inducing negative chemical pressure. Our study provides valuable insights into the improvement of superconductivity in caged compounds.
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Research context

OpenAlex topics: Rare-earth and actinide compounds · High-pressure geophysics and materials · Iron-based superconductors research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

ShanghaiTech Laboratory for Topological Physics, ShanghaiTech University, Shanghai 201210, China

Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, China

Shanghai Key Laboratory of High-Resolution Electron Microscopy, ShanghaiTech University, Shanghai 201210, China

Funding

National Natural Science Foundation of China · National Key Research and Development Program of China

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