journal article·2025-12Open access

Evaluation of compressive strength of eco-friendly cementitious composites incorporating waste oyster shells under sodium chloride solution exposure

Jinwoong Kim, Inyeong Cha, Byungkyu Jo, Heeyoung Lee

Abstract

The development of the marine industry and the continuous increase in oyster production have caused the accumulation of large quantities of waste oyster shells, with only a small portion being recycled. Unrecycled waste oyster shells cause environmental problems, produce odors, and harm marine ecosystems. Simultaneously, aggregates such as sand are in high demand in the construction industry. Waste oyster shells, primarily comprising calcium carbonate (CaCO₃), have similar material characteristics to sand and can be used as a sand substitute. In this study, oyster shell cementitious composites were produced to assess the potential of waste oyster shells as a sand replacement. The experimental parameters included the use of admixtures, curing in either fresh water or sodium chloride solution, and various curing durations. The specimens were cured for 91 days in fresh water and 30, 60, or 91 days in sodium chloride solution. Nine oyster shell cementitious composite specimens measuring 50 mm × 50 mm × 50 mm were fabricated for each experimental condition, resulting in a total of 144 specimens. When cured in sodium chloride solution, the compressive strength decreased as the curing time increased, while the compressive strengths cured in fresh water and sodium chloride solution for 91 days were 38.8 and 34.55 MPa, respectively. Thus, the specimens cured in sodium chloride solution retained more than 80% of the strength of those cured in fresh water. Therefore, waste oyster shells can serve as an eco-friendly construction material and are a viable alternative to sand.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Materials Engineering and Processing · Magnesium Oxide Properties and Applications · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (70)

Show source-provided references
1. Oyster shell as substitute for aggregate in mortar10.1177/0734242X04042456 ↗
2. Synthesis and characterization of cement clinker using recycled pulverized oyster and scallop shell as limestone substitutes10.1016/j.jclepro.2020.123987 ↗
3. Engineering performances of permeable concrete blocks using oyster shell, bottom ash, and biochar10.1016/j.conbuildmat.2024.137374 ↗
4. Oyster shell recycling and marine ecosystems: a comparative analysis in the Republic of Korea and Japan10.2112/JCR-SI114-071.1 ↗
5. Exploring the potential of pulverized oyster shell as a limestone substitute in limestone calcined clay cement (LC3) and its implications for performance10.1016/j.conbuildmat.2024.135918 ↗
6. Calcined oyster shell powder as an expansive additive in cement mortar10.3390/ma12081322 ↗
7. Strength and microstructural changes in cementitious composites containing waste oyster shell powder10.3390/buildings13123078 ↗
8. Comparative analysis of the effects of waste shell aggregates on the material properties of cement mortars10.1016/j.conbuildmat.2024.134887 ↗
9. A hydration-based integrated model to evaluate properties development and sustainability of oyster shell powder–cement binary composites10.3390/buildings14061578 ↗
10. Potential use of oyster shell waste in the composition of construction composites: a review10.3390/buildings13061546 ↗
11. United Nations Environment Programme (UNEP), S. Geas, Rarer than one thinks, 2014. 〈https://na.unep.net/geas/archive/pdfs/GEAS_Mar2014_Sand_Mining.pdf〉 (accessed 29 May 2024).
12. United Nations Environment Programme (UNEP), GRID-Geneva, Sand and sustainability: 10 strategic recommendations to avert a crisis, 2022. 〈https://www.unep.org/resources/report/sand-and-sustainability-10-strategic-recommendations-avert-crisis〉 (accessed 21 June 2024).
13. Public perspective on the environmental impacts of sea sand mining: Evidence from a choice experiment in South Korea10.1016/j.resourpol.2020.101811 ↗
14. Properties of cement-based bricks with oyster-shells ash10.1016/j.jclepro.2014.12.023 ↗
15. Optimization of wet flue gas desulfurization system using recycled waste oyster shell as high-grade limestone substitutes10.1016/j.jclepro.2021.128492 ↗
16. Properties of concrete containing recycled seashells as cement partial replacement: a review10.1016/j.jclepro.2019.117723 ↗
17. Sustainable use of seashells as binder in concrete production: prospect and challenges
18. Evaluation of the eco-friendly crushed waste oyster shell mortars containing supplementary cementitious materials10.1016/j.jclepro.2019.117811 ↗
19. Properties of seashell aggregate concrete: a review10.1016/j.conbuildmat.2018.10.096 ↗
20. Properties of mortar containing polyvinyl alcohol pretreated waste oyster shells with various concentrations10.1016/j.conbuildmat.2022.129879 ↗
21. Engineering properties of controlled low-strength materials containing waste oyster shells10.1016/j.conbuildmat.2013.04.020 ↗
22. Effect of partial replacement of sand with dry oyster shell on the long-term performance of concrete10.1016/j.conbuildmat.2009.10.032 ↗
23. Experimental study on the shear performance of brick masonry strengthened with modified oyster shell ash mortar
24. Effect of waste oyster shell powder content on properties of cement-metakaolin mortar
25. Research on properties of waste oyster shell mortar: The effect of calcination temperature of oyster shell powder
26. Enhancing compressive strength in cementitious composites through effective use of wasted oyster shells and admixtures10.3390/buildings13112787 ↗
27. Characteristics of mortar containing oyster shell as fine aggregate10.3390/ma15207301 ↗
28. Chemical–mechanical characteristics of crushed oyster-shell10.1016/S0956-053X(02)00159-9 ↗
29. Effect of oyster shell substituted for fine aggregate on concrete characteristics: Part I. Fundamental properties10.1016/j.cemconres.2005.03.016 ↗
30. Properties of hardened mortars containing crushed waste oyster shells10.1089/ees.2018.0465 ↗
31. Effect of oyster shell as an aggregate replacement on the characteristics of concrete10.1680/macr.14.00383 ↗
32. Oyster shell waste as a concrete ingredient: A review10.1016/j.matpr.2021.02.208 ↗
33. Effects of crushed oyster shell on strength and durability of marine concrete containing fly ash and blastfurnace slag
34. Particle size effect of oyster shell on mortar: Experimental investigation and modeling10.3390/ma14226813 ↗
35. Examining the potential of calcined oyster shell waste as additive in high volume slag cement10.1016/j.conbuildmat.2019.116973 ↗
36. Hardened properties of mortar mixtures containing pre-treated waste oyster shells10.1016/j.jclepro.2020.121729 ↗
37. Influence of the usage of waste oyster shell powder on mechanical properties and durability of mortar10.1016/j.apt.2022.103503 ↗
38. A review of chloride binding in cementitious systems
39. Compressive strength reduction of cement pastes exposed to sodium chloride solutions: Secondary ettringite formation10.1016/j.conbuildmat.2021.123965 ↗
40. A. Rösli, Combined influence of freezing and deicing salt on concrete-Physical aspects
41. Durability performance of reinforced waste-based geopolymer foam concrete under exposure to various corrosive environments
42. Investigation of long-term corrosion resistance of reinforced concrete structures constructed with various types of concretes in marine and various climate environments10.1016/j.conbuildmat.2019.117701 ↗
43. Meso-scale mechanical deterioration of mortar due to sodium chloride attack10.1016/j.cemconcomp.2018.11.021 ↗
44. Damage in cement pastes exposed to NaCl solutions10.1016/j.conbuildmat.2018.03.123 ↗
45. Comparing chloride ingress from seawater and NaCl solution in Portland cement mortar10.1016/j.cemconres.2018.09.014 ↗
46. Enhanced seawater corrosion resistance of reinforcement in nanophase modified fly ash concrete10.1016/j.conbuildmat.2019.06.070 ↗
47. Seawater-mixed lightweight aggregate concretes with dune sand, waste glass and nanosilica: Experimental and life cycle analysis10.1186/s40069-023-00613-4 ↗
48. An empirical model to predict chloride penetrations in concrete containing palm oil fuel ash based on 10-year exposure under marine environment10.1186/s40069-023-00621-4 ↗
49. Chloride ion penetration resistance of concrete containing fly ash and silica fume against combined freezing-thawing and chloride attack10.1016/j.conbuildmat.2018.03.038 ↗
50. Causes and mechanisms of deterioration in reinforced concrete
51. Durability of concrete—Degradation phenomena involving detrimental chemical reactions10.1016/j.cemconres.2007.09.015 ↗
52. A. Astm, Standard Specification for Steel Fibers for Fiber-Reinforced Concrete, ASTM International, West Conshohocken, Pennsylvania, 2021.
53. ASTM C989, Standard Specification for Slag Cement for Use in Concrete and Mortars, ASTM International, West Conshohocken, Pennsylvania, 2020.
54. ASTM C1240-20, Standard Specification for Silica Fume Used in Cementitious Mixtures, ASTM International, West Conshohocken, Pennsylvania, 2019.
55. ASTM C494, Standard Specification for Chemical Admixtures for Concrete, ASTM International, West Conshohocken, Pennsylvania, 2019.
56. M.F.M. Zain, Md. Safiuddin, K.M. Yusof, Influence of different curing conditions on strength and durability of high-performance concrete, in: SP-193: Repair, Rehabilitation, and Maintenance of Concrete Structures, and Innovations in Design and Construction – Pro, American Concrete Institute, 2000, pp. 275–292. https://doi.org/10.14359/5827.10.14359/5827 ↗
57. ASTM C109, Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-In, or [50-mm] Cube Specimens), ASTM International, West Conshohocken, Pennsylvania, 2016.
58. Fracture behavior and mechanical properties of engineered cementitious composites exposed to long-term sulfate and chloride environments
59. Tension performance of precast bridge deck longitudinal joints with different configurations10.3390/app122412892 ↗
60. Fracture behavior of environmentally friendly high-strength concrete using recycled rubber powder and steel fibers: Experiment and modeling
61. Thermal, electrical, and mechanical performances of ultrahigh-performance cementitious composites with multiwalled carbon nanotubes
62. Time-varying damage evolution of concrete under cyclic disturbance loading- an experimental observation utilizing AE and DIC
63. Coupled effect of waste tire rubber and steel fibers on the mechanical properties of concrete10.2478/msp-2022-0009 ↗
64. ISO 19749:2021, Nanotechnologies—Measurements of Particle Size and Shape Distributions by Scanning Electron Microscopy, International Organization for Standardization, Geneva, Switzerland, 2021.
65. ASTM E1508-12a, Standard Guide for Quantitative Analysis by Energy-Dispersive Spectroscopy, ASTM International, West Conshohocken, Pennsylvania, 2012.
66. ASTM E915-96, Test Method for Verifying the Alignment of X-ray Diffraction Instrumentation for Residual Stress Measurement, ASTM International, West Conshohocken, Pennsylvania, 2002.
67. ASTM C1872, Standard Test Method for Thermogravimetric Analysis of Hydraulic Cement, ASTM International, West Conshohocken, Pennsylvania, 2018.
68. High-performance fiber-reinforced concrete: a review10.1007/s10853-016-9917-4 ↗
69. Effect of low temperatures on fracture properties of steel fibre reinforced rubberised concrete10.1016/j.jclepro.2024.140968 ↗
70. Performance evaluation of bond strength and fiber type on the mechanical properties of polyurethane-based polymer mortar