Strength of correlations in a silver-based cuprate analog
Source abstract
Abstract
${\mathrm{AgF}}2$ has been proposed as a cuprate analog, which requires strong correlation and marked covalence. On the other hand, fluorides are usually quite ionic, and $4d$ transition metals tend to be less correlated than their $3d$ counterparts, which calls for further scrutiny. We combine valence band photoemission and Auger-Meitner spectroscopy of AgF and ${\mathrm{AgF}}2$ together with computations in small clusters to estimate values of the Ag $4d$ Coulomb interaction ${U}4d$ and charge-transfer energy ${\mathrm{\ensuremath{\Delta}}}pd$. Based on these values, ${\mathrm{AgF}}2$ can be classified as a charge-transfer correlated insulator according to the Zaanen-Sawatzky-Allen classification scheme. Thus, we confirm that the material is a cuprate analog from the point of view of correlations, suggesting that it should become a high-temperature superconductor if metallization is achieved by doping. We present also a computation of the Hubbard $U$ in density functional ``$+U$'' methods and discuss its relation to the Hubbard $U$ in spectroscopies.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Inorganic Fluorides and Related Compounds · Physics of Superconductivity and Magnetism · Advanced Condensed Matter Physics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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