journal article·2022-07-25

Strength of correlations in a silver-based cuprate analog

Riccardo Piombo, Daniel Jezierski, Henrique Perin Martins, Tomasz Jaroń, Maria N. Gastiasoro, Paolo Barone, Kamil Tokár, Przemysław Piekarz, Mariana Derzsi, Zoran Mazej, Miguel Abbate, Wojciech Grochala, José Lorenzana

Physical Review B· Volume 106· Issue 3
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Abstract

${\mathrm{AgF}}2$ has been proposed as a cuprate analog, which requires strong correlation and marked covalence. On the other hand, fluorides are usually quite ionic, and $4d$ transition metals tend to be less correlated than their $3d$ counterparts, which calls for further scrutiny. We combine valence band photoemission and Auger-Meitner spectroscopy of AgF and ${\mathrm{AgF}}2$ together with computations in small clusters to estimate values of the Ag $4d$ Coulomb interaction ${U}4d$ and charge-transfer energy ${\mathrm{\ensuremath{\Delta}}}pd$. Based on these values, ${\mathrm{AgF}}2$ can be classified as a charge-transfer correlated insulator according to the Zaanen-Sawatzky-Allen classification scheme. Thus, we confirm that the material is a cuprate analog from the point of view of correlations, suggesting that it should become a high-temperature superconductor if metallization is achieved by doping. We present also a computation of the Hubbard $U$ in density functional ``$+U$'' methods and discuss its relation to the Hubbard $U$ in spectroscopies.
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Research context

OpenAlex topics: Inorganic Fluorides and Related Compounds · Physics of Superconductivity and Magnetism · Advanced Condensed Matter Physics

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