journal article·2020-07-22Open access

Disorder recovers the Wiedemann-Franz law in the metallic phase of VO2

Lei Jin, Steven E. Zeltmann, Hwan Sung Choe, Huili Liu, Frances I. Allen, Andrew M. Minor, Junqiao Wu

Physical Review B· Volume 102· Issue 4

Abstract

At temperatures higher than 341 K, vanadium dioxide (${\mathrm{VO}}2$) is a strongly correlated metal with resistivity exceeding the Mott-Ioffe-Regel limit. Its electronic thermal conductivity is lower than that predicted by the Wiedemann-Franz (WF) law, and can be explained by nonquasiparticle transport where heat and charge currents follow separate diffusive modes. In contradiction, the Wiedemann-Franz law is a direct consequence of quasiparticle transport where charge carriers are elastically scattered. In this work, we enhance elastic electron scattering in ${\mathrm{VO}}2$ by introducing atomic disorder with ion irradiation. A gradual and eventually full recovery of the WF law is observed at high defect densities. This observation provides an example that connects hydrodynamic quasiparticle transport to nonquasiparticle transport in metallic systems.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · Electronic and Structural Properties of Oxides · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. N. W. Ashcroft · 1976
2. 10.1126/science.114076210.1126/science.1140762 ↗
3. 10.1126/science.aag041010.1126/science.aag0410 ↗
4. 10.1103/PhysRevB.88.12510710.1103/PhysRevB.88.125107 ↗
5. 10.1126/science.aad034310.1126/science.aad0343 ↗
6. 10.1103/PhysRevLett.115.05660310.1103/PhysRevLett.115.056603 ↗
7. 10.1038/ncomms140610.1038/ncomms1406 ↗
8. 10.1103/PhysRevLett.110.17640210.1103/PhysRevLett.110.176402 ↗
9. 10.1103/PhysRevB.48.435910.1103/PhysRevB.48.4359 ↗
10. 10.1103/PhysRevB.74.20511810.1103/PhysRevB.74.205118 ↗
11. U. Mizutani · 200110.1017/CBO9780511612626 ↗
12. 10.1103/PhysRevB.97.24512810.1103/PhysRevB.97.245128 ↗
13. 10.1063/1.369338110.1063/1.3693381 ↗
14. 10.1016/j.nimb.2010.02.09110.1016/j.nimb.2010.02.091 ↗
15. 10.1115/1.159761910.1115/1.1597619 ↗
16. 10.1021/ja400658u10.1021/ja400658u ↗
17. 10.1038/nnano.2009.26610.1038/nnano.2009.266 ↗
18. 10.1103/PhysRevB.91.20512310.1103/PhysRevB.91.205123 ↗
19. 10.1126/science.aam918910.1126/science.aam9189 ↗
20. 10.1021/acs.nanolett.6b0411810.1021/acs.nanolett.6b04118 ↗
21. 10.1016/j.apsusc.2014.10.05710.1016/j.apsusc.2014.10.057 ↗
22. 10.1126/science.123051210.1126/science.1230512 ↗
23. 10.1103/PhysRevApplied.7.03400810.1103/PhysRevApplied.7.034008 ↗
24. 10.1038/nature1386510.1038/nature13865 ↗
25. 10.1002/1521-3889(200210)11:9%3C650::AID-ANDP650%3E3.0.CO;2-K10.1002/1521-3889(200210)11:9%3C650::AID-ANDP650%3E3.0.CO;2-K ↗
26. 10.1103/PhysRevB.24.740410.1103/PhysRevB.24.7404 ↗
27. 10.1038/nphys317410.1038/nphys3174 ↗
28. 10.1103/PhysRevB.7.210910.1103/PhysRevB.7.2109 ↗
29. S. Kasap · 2001
30. 10.1103/PhysRevB.99.08510410.1103/PhysRevB.99.085104 ↗
31. 10.1103/PhysRevLett.67.208810.1103/PhysRevLett.67.2088 ↗
32. 10.1103/RevModPhys.81.4510.1103/RevModPhys.81.45 ↗
33. 10.1063/1.500993910.1063/1.5009939 ↗
34. 10.1103/PhysRevB.88.08530510.1103/PhysRevB.88.085305 ↗
35. 10.1002/adma.20150135010.1002/adma.201501350 ↗