journal article·2025-04-25

Construction of a Photoelectrochemical Biosensor Based on Ti3C2/Cu2O Nanocomposite Photocathode and Ti3C2/Bi2S3 Nanocomposite Photoanode

Ming Gao, Bingdong Yan, Nan Zhang, Chide Zhang, Yang Cao, Xiaohong Wang, Yuanyuan Wang, Qiang Wu

ACS Applied Nano Materials· Volume 8· Issue 16
Publisher page

Abstract

Photoanodic photoelectrochemical (PEC) analysis is known for its high photocurrent and low detection limits but can be susceptible to interference from reducing agents. Conversely, photocathode analyses offer greater stability but typically exhibit lower light responses. In this study, we developed a PEC biosensor for glucose detection, utilizing Ti 3 C 2 /Bi 2 S 3 as the photoanode and Ti 3 C 2 /Cu 2 O as the photocathode. The dual-photoelectrode system operates efficiently without an external power supply, leveraging the inherent difference in Fermi energy levels between the photoanode and photocathode. Ti 3 C 2 served as an electron transport channel at the photoanode and as a hole transport medium at the photocathode. The sensor exhibited excellent selectivity and stability and a detection limit of 0.0790 mM. This work highlights the potential of dual-photoelectrode PEC systems in enzyme sensing applications.
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Research context

OpenAlex topics: Advanced biosensing and bioanalysis techniques · Advanced Nanomaterials in Catalysis · Electrochemical sensors and biosensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering

Hainan University

College of Science

Qiongtai Normal University

NHC Key Laboratory of Tropical Disease Control, School of Tropical Medicine & The Second Affiliated Hospital

Hainan Medical University

Key Laboratory of Emergency and Trauma of Ministry of Education, The First Affiliated Hospital

Funding

Natural Science Foundation of Hainan Province · National Natural Science Foundation of China · Hainan Province Science and Technology Special Fund · CAMS Innovation Fund for Medical Sciences · Key Laboratory of Emergency and Trauma of Ministry of Education

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