journal article·2023-01-27

Silver Nanoparticles Embedded within a Silicon Photocathode for Photoelectrochemical Fixation of CO2 to Synthesize Intermediates of Profen Drugs

Jiacheng Yu, Haoyue Zhang, Tong Cai, Wei Wang, Lixuan Mu, Guangwei She, Wensheng Shi

ACS Applied Nano Materials· Volume 6· Issue 2
Publisher page

Abstract

Photoelectrochemical (PEC) fixation of carbon dioxide (CO 2 ) into intermediates of Profen drugs, a kind of nonsteroidal antiinflammatory drug, is a useful and important technology for the utilization of CO 2 . In this work, we successfully designed and prepared a silver nanoparticles (AgNPs)-embedded silicon photocathode for PEC-fixating CO 2 to synthesize intermediates of Profen drugs with high efficiency and stability. AgNPs endow the photocathode with extremely high catalytic activity, the Schottky junction between Ag and Si promotes the separation and transfer of photogenerated carriers, the AgNPs-embedded structure greatly improves the stability of the photocathode, and the nanohole structure improves light absorption.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Carbon dioxide utilization in catalysis · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100049, China

China Power Construction Group, Jiangxi Power Construction Company, Ltd., Nanchang 330001, China

Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341000, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Chinese Academy of Sciences

References (30)

Show source-provided references
1. 10.1039/D0EE01860K10.1039/D0EE01860K ↗
2. 10.1038/s41586-019-1681-610.1038/s41586-019-1681-6 ↗
3. 10.1016/j.apcatb.2017.02.04910.1016/j.apcatb.2017.02.049 ↗
4. 10.1039/D2CC01888H10.1039/D2CC01888H ↗
5. 10.1002/anie.20180318610.1002/anie.201803186 ↗
6. 10.1002/anie.20180628510.1002/anie.201806285 ↗
7. 10.1002/cjoc.20170074210.1002/cjoc.201700742 ↗
8. 10.1002/sstr.20220008610.1002/sstr.202200086 ↗
9. 10.1021/acsaem.0c0072810.1021/acsaem.0c00728 ↗
10. 10.1002/anie.20200195310.1002/anie.202001953 ↗
11. 10.1002/anie.20120256910.1002/anie.201202569 ↗
12. 10.1007/s40843-022-2236-810.1007/s40843-022-2236-8 ↗
13. 10.1016/j.isci.2019.10080610.1016/j.isci.2019.100806 ↗
14. 10.1002/anie.20121022810.1002/anie.201210228 ↗
15. 10.1039/C7GC00199A10.1039/C7GC00199A ↗
16. 10.1021/acsenergylett.7b0003410.1021/acsenergylett.7b00034 ↗
17. 10.1021/acsanm.9b0059010.1021/acsanm.9b00590 ↗
18. 10.1016/j.cej.2021.12945910.1016/j.cej.2021.129459 ↗
19. 10.1021/acsphotonics.7b0004710.1021/acsphotonics.7b00047 ↗
20. 10.1038/ncomms1133510.1038/ncomms11335 ↗
21. 10.1002/solr.20180000710.1002/solr.201800007 ↗
22. 10.1021/ja106049c10.1021/ja106049c ↗
23. 10.1021/acssuschemeng.9b0464710.1021/acssuschemeng.9b04647 ↗
24. 10.1021/ja102463910.1021/ja1024639 ↗
25. 10.1021/ja910082y10.1021/ja910082y ↗
26. 10.1021/acsami.0c0088110.1021/acsami.0c00881 ↗
27. 10.1186/1556-276X-8-8810.1186/1556-276X-8-88 ↗
28. 10.1021/acsami.9b1471310.1021/acsami.9b14713 ↗
29. 10.1016/j.cocis.2019.01.00110.1016/j.cocis.2019.01.001 ↗
30. 10.1021/nl203564s10.1021/nl203564s ↗