journal article·2019-12-02

Coexistence of two different atomic structures in the Σ13 pyramidal twin boundary in α-Al2O3

Saki Ishihara, Eita Tochigi, Ryo Ishikawa, Naoya Shibata, Yuichi Ikuhara

Philosophical Magazine Letters· Volume 99· Issue 12
Publisher page

Abstract

An α-Al2O3 bicrystal with a (101¯4)/[12¯10] Σ13 grain boundary was fabricated by joining two pieces of single crystal at 1500°C in an Ar–H2 mixture gas. The resultant grain boundary was characterised by scanning transmission electron microscopy (STEM) at the atomic level. STEM observations revealed that the grain boundary consists of two regions with different atomic structures. These two structures were identified to be the most and second-most stable structures by theoretical calculations and STEM image simulation. The coexistence of two different structures in the Σ13 grain boundary is discussed.
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Research context

OpenAlex topics: Microstructure and mechanical properties · X-ray Diffraction in Crystallography · High-pressure geophysics and materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Bunkyo, Tokyo, Japan

Japan Science and Technology Agency, Precursory Research for Embryonic Science and Technology, Kawaguchi, Saitama, Japan

Nanostructures Research Laboratory, Japan Fine Ceramic Center, Nagoya, Aichi, Japan

Center for Elements Strategy Initiative for Structure Materials, Kyoto University, Sakyo, Kyoto, Japan

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