Effects of glass and cement powder additions on martensitic stainless steel microstructure, thermal and magnetic properties
Source abstract
Abstract
X12Cr13 martensitic stainless steels (MSS), widely used in pumps, valves and shafts, are low-carbon alloys and have high-temperature strengths and magnetic behaviours. This study investigates the effects of incorporating 20 wt% glass powder (GP) and Portland limestone cement (PLC) on the structural, thermophysical and magnetic properties of MSS processed via powder metallurgy. Both additives enhanced the hardness and thermal capacity of the composites, while reducing density and magnetic performance. The MSS-20PLC composite exhibited the highest hardness (126.45 N/mm²), specific heat capacity (0.98 J/g°C at 565°C temperatures) and enthalpy (473.74 J/g at 565 °C), but also showed the lowest density (4.086 g/cm³) and saturation magnetisation (130.08 emu/g at 380 K), attributed to reduced Fe content and increased Na incorporation. In contrast, the MSS control sample achieved the highest saturation magnetisation (178.93 emu/g at 300 K) due to its iron-rich, denser microstructure. All samples displayed soft magnetic behaviour, with decreasing magnetisation as the temperature increased. These findings demonstrate that GP and PLC additives can significantly tailor the multifunctional properties of MSS for potential applications in thermal management and structural components requiring magnetic softness.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metallic Glasses and Amorphous Alloys · Magnetic Properties and Applications · Microstructure and Mechanical Properties of Steels
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Çukurova University
Funding
Cukurova University
References (80)
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1. 10.1016/j.mtcomm.2022.10492410.1016/j.mtcomm.2022.104924 ↗
2. 10.4283/JMAG.2016.21.2.18310.4283/JMAG.2016.21.2.183 ↗
3. A. Rivaz, S.M. Anijdan, and M. Moazami-Goudarzi, Failure analysis and damage causes of a steam turbine blade of 410 martensitic stainless steel after 165,000 h of working. Eng. Fail. Anal. 113 (2020), pp. 104557.10.1016/j.engfailanal.2020.104557 ↗
4. 10.1016/j.matdes.2020.10917910.1016/j.matdes.2020.109179 ↗
5. C.d. Silva, D. Godinho, A. Ribeiro, A. Ferronato, A. dos Santos Neto, and E. Angioletto, Influence of substitution of Portland cement CP-II-Z32 by refractory cement on residual properties of high-temperature concrete. Cerâmica 66 (2020), pp. 330–339.10.1590/0366-69132020663792913 ↗
6. 10.3390/molecules2817629610.3390/molecules28176296 ↗
7. V. Sandu, S. Greculeasa, A. Kuncser, M.S. Nicolescu, and V. Kuncser, Effect of Cr 2 O 3 on the magnetic properties of magnetite-based glass-ceramics obtained by controlled crystallization of Fe-containing aluminoborosilicate glass. J. Eur. Ceram. Soc. 37 (2017), pp. 3089–3099.10.1016/j.jeurceramsoc.2017.03.055 ↗
8. Y. Cai, H. Ling, and T. Jiang, Effect of industrial raw materials on the glass-forming ability, magnetic and mechanical properties of Fe-based bulk metallic glasses. Metall. Mater. Trans. B 46 (2015), pp. 2484–2489.10.1007/s11663-015-0436-5 ↗
9. 10.1016/j.ceramint.2016.12.07210.1016/j.ceramint.2016.12.072 ↗
10. 10.1016/j.conbuildmat.2018.09.08810.1016/j.conbuildmat.2018.09.088 ↗
11. A. Francis, Crystallization kinetics of magnetic glass–ceramics prepared by the processing of waste materials. Mater. Res. Bull. 41 (2006), pp. 1146–1154.10.1016/j.materresbull.2005.11.002 ↗
12. P.-m. Zhan, X.-x. Zhang, Z.-h. He, J.-y. Shi, O. Gencel, N.T. Hai Yen, and G.-c. Wang, Strength, microstructure and nanomechanical properties of recycled aggregate concrete containing waste glass powder and steel slag powder. J. Cleaner Prod. 341 (2022), pp. 130892.10.1016/j.jclepro.2022.130892 ↗
13. 10.1016/j.jenvman.2020.11086910.1016/j.jenvman.2020.110869 ↗
14. 10.1016/j.powtec.2024.12047910.1016/j.powtec.2024.120479 ↗
15. W. Kushartomo, I. Bali, and B. Sulaiman, Mechanical behavior of reactive powder concrete with glass powder substitute. Procedia. Eng. 125 (2015), pp. 617–622.10.1016/j.proeng.2015.11.082 ↗
16. S. Abdallah and M. Fan, Characteristics of concrete with waste glass as fine aggregate replacement. Int. J. Eng. Tech. Res 2 (2014), pp. 11.
17. J. Chen and A. Kwan, Superfine cement for improving packing density, rheology and strength of cement paste. Cem. Concr. Compos. 34 (2012), pp. 1–10.10.1016/j.cemconcomp.2011.09.006 ↗
18. 10.1023/B:JMSC.0000025827.65956.1810.1023/B:JMSC.0000025827.65956.18 ↗
19. 10.1016/j.surfcoat.2007.09.03610.1016/j.surfcoat.2007.09.036 ↗
20. Q.-t. Zhu, J. Li, C.-b. Shi, and W.-t. Yu, Effect of quenching process on the microstructure and hardness of high-carbon martensitic stainless steel. J. Mater. Eng. Perform. 24 (2015), pp. 4313–4321.10.1007/s11665-015-1723-7 ↗
21. A.C. Souza, M.F. Pereira, and L.C. Mossin, Thermal and mechanical characterization of blindex glass powder residue® for the production of ecological coating. J. Mater. Res. Technol. 12 (2021), pp. 1794–1803.10.1016/j.jmrt.2021.03.099 ↗
22. B. Yu, Y. Du, L. Wei, X. Zhang, G. Zuo, Y. Wang, and S. Ye, Valorization of coal gangue and vanadium-titanium slag into glass-ceramic coating for oxidation resistance of 60Si2Mn spring steel at high temperature. ISIJ Int. 61 (2021), pp. 326–334.10.2355/isijinternational.ISIJINT-2020-008 ↗
23. A.N. Acar, D. Kaya, A.K. Ekşi, and A. Ekicibil, The impact of glass powder on surface and morphological properties of Alumix 431 alloy. Int. J. Mater. Eng. Technol. 4 (2021), pp. 109.
24. 10.3390/met1003038810.3390/met10030388 ↗
25. Y. Shao, V. Rostami, Z. He, and A.J. Boyd, Accelerated carbonation of Portland limestone cement. J. Mater, Civ. Eng 26 (2014), pp. 117.10.1061/(ASCE)MT.1943-5533.0000773 ↗
26. D.V. Ribeiro, J.A. Labrincha, and M.R. Morelli, Potential use of natural red mud as pozzolan for Portland cement. Mater. Res. 14 (2011), pp. 60–66.10.1590/S1516-14392011005000001 ↗
27. H. Yin, J. Zhu, X. Guan, Z. Yang, Y. Zhu, H. Zhao, Z. Zhang, A. Zhou, X. Zhang, and C. Feng, Effect of MXene (Nano-Ti3C2) on early-age hydration of cement paste. J. Nanomater 2015 (2015), pp. 430578.10.1155/2015/430578 ↗
28. E.J.P.d. Miranda Júnior, H.d.J.C.L. Bezerra, F.S. Politi, and A.E.M. Paiva, Increasing the compressive strength of Portland cement concrete using flat glass powder. Mater. Res. 17 (2014), pp. 45–50.10.1590/S1516-14392014005000058 ↗
29. W. He, R. Li, Y. Yang, Y. Zhang, and D. Nie, Kinetic and thermodynamic analysis on preparation of belite-calcium sulphoaluminate cement using electrolytic manganese residue and barium slag by TGA. Environ. Sci. Pollut. Res. 30 (2023), pp. 95901–95916.10.1007/s11356-023-29104-5 ↗
30. 10.3390/ma1617587610.3390/ma16175876 ↗
31. 10.1016/j.matchar.2010.02.00310.1016/j.matchar.2010.02.003 ↗
32. S. Popović and Ž Skoko, X-ray diffraction broadening analysis. Maced. J. Chem. Chem. Eng. 34 (2015), pp. 39–49.10.20450/mjcce.2015.642 ↗
33. 10.1002/adem.20031008610.1002/adem.200310086 ↗
34. B. Sharma, S.K. Vajpai, and K. Ameyama, Synthesis of ternary Ti-25Nb-11Sn alloy by powder metallurgy route using titanium hydride powder. Mater. Trans. 57 (2016), pp. 1440–1446.10.2320/matertrans.MH201510 ↗
35. M. El-Tahawy, P.H.R. Pereira, Y. Huang, H. Park, H. Choe, T.G. Langdon, and J. Gubicza, Exceptionally high strength and good ductility in an ultrafine-grained 316L steel processed by severe plastic deformation and subsequent annealing. Mater. Lett. 214 (2018), pp. 240–242.10.1016/j.matlet.2017.12.040 ↗
36. 10.1016/j.mtla.2021.10116110.1016/j.mtla.2021.101161 ↗
37. N. Navya K. Ribin and K. Naseema. Structural optical and morphological studies of SILAR grown ZnO thin film and double coated CBD grown ZnO thin film in Journal of Physics: Conference Series IOP Publishing 2020 p. 012022.10.1088/1742-6596/1706/1/012022 ↗
38. J. Liang, Q. Lin, X. Zhang, T. Jin, Y. Zhou, X. Sun, B. Choi, I. Kim, J. Do, and C. Jo, Effects of alumina on cristobalite crystallization and properties of silica-based ceramic cores. J. Mater. Sci. Technol. 33 (2017), pp. 204–209.10.1016/j.jmst.2016.02.012 ↗
39. Y. Shi, X. Song, X. Han, M. Zhang, and M. Dong, Influences of additives on crystal multiformity and composition in a CaO–Al2O3–MgO–SiO2–based glass–ceramics. Adv. Compos. Hybrid Mater. 4 (2021), pp. 614–628.10.1007/s42114-021-00281-6 ↗
40. D.M.A. Valderrama, J.A.G. Cuaspud, N. Taniolo, and A.R. Boccaccini, Glass-Ceramic materials obtained by sintering of vitreous powders from industrial waste: Production and properties. Constr. Mater. 1 (2021), pp. 63–79.
41. Y. Azmi, F. Ahmad, S. Razak, M. Hadi, S. Kabir, and G. Yeoh, Effects of waste glass powder filler on intumescent coating for steel structures application, in IOP conference series: Materials science and engineering, IOP Publishing, 2021, p. 012029.
42. N. Ayoob, J. Mohd Juoi, Z.M. Rosli, and N. Rosli, Characterisation and properties of sintered glass-ceramics produced from recycling glass by using pressure-less method. Key Eng. Mater. 471–472 (2011), pp. 933–938.10.4028/www.scientific.net/KEM.471-472.933 ↗
43. 10.1016/j.ceramint.2025.08.12410.1016/j.ceramint.2025.08.124 ↗
44. 10.3390/nano1509066810.3390/nano15090668 ↗
45. Y.-S. Tseng, Y.-H. Su, C.-L. Chen, J. Zhang, C.-K. Wang, D.A.H. Hanaor, and W.-F. Chen, Bioceramics in the CaMgSi2O6–Li2O system: A glass-ceramic strategy for excellent mechanical strength and enhanced bioactivity by spontaneous elemental redistribution. Adv. Mater. Interfaces 10 (2023), pp. 2202491.10.1002/admi.202202491 ↗
46. N.H. Rodríguez, S. Martínez-Ramírez, M.T. Blanco-Varela, S. Donatello, M. Guillem, J. Puig, C. Fos, E. Larrotcha, and J. Flores, The effect of using thermally dried sewage sludge as an alternative fuel on Portland cement clinker production. J. Cleaner Prod. 52 (2013), pp. 94–102.10.1016/j.jclepro.2013.02.026 ↗
47. M. Benmohamed, R. Alouani, A. Jmayai, A. Ben Haj Amara, and H. Ben Rhaiem, Morphological analysis of white cement clinker minerals: Discussion on the crystallization-related defects. Int. J. Anal. Chem. 2016 (2016), pp. 1–10.10.1155/2016/1259094 ↗
48. S.K. Al-Bahar, T.V. Bogahawatta, A.K. Al-Enezi, S.G. Ali, H.K. Kamal, S.B. Al-Fadala, A.A. Al-Othman, M.H. Bahbahani, and A.S. Al-Hazza, Evaluation of Kuwaiti argillaceous materials as a replacement of sand for Clinker production. Arab. J. Sci. Eng. 39 (2014), pp. 4485–4506.10.1007/s13369-014-1035-5 ↗
49. D. Heinz and L. Urbonas, About thaumasite formation in Portland-limestone cement pastes and mortars––effect of heat treatment at 95 °C and storage at 5 °C. Cem. Concr. Compos. 25 (2003), pp. 961–967.10.1016/S0958-9465(03)00156-2 ↗
50. Z. Brytan, L. Dobrzański, M.A. Grande, and M. Rosso, Characteristics of vacuum sintered stainless steels. J. Achiev. Mater. Manuf. Eng. 33 (2009), pp. 126.
51. R. Subramanian, H. Tripathy, A.K. Rai, R.N. Hajra, S. Saibaba, T. Jayakumar, and E.R. Kumar, Thermal expansion characteristics of Fe–9Cr–0.12C–0.56Mn–0.24V–1.38W–0.06Ta (wt.%) reduced activation ferritic–martensitic steel. J. Nucl. Mater. 459 (2015), pp. 150–158.10.1016/j.jnucmat.2015.01.026 ↗
52. 10.3390/met1002018710.3390/met10020187 ↗
53. A.N. Acar, D. Kaya, A.K. Ekşi, and A. Ekicibil, Corrosion, hardness and thermal analysis of martensitic stainless steel composites with glass and cement additives. J. Mater. Eng. Perform (2025), pp. 1–16.
54. C. Geng, X. Wu, X. Yao, C. Wang, Z. Mei, and T. Jiang, Reusing waste glass powder to improve the strength stability of cement at HTHP. J. Petr. Sci. Eng. 213 (2022), pp. 110394.10.1016/j.petrol.2022.110394 ↗
55. 10.1016/j.conbuildmat.2012.09.07810.1016/j.conbuildmat.2012.09.078 ↗
56. A. Monshi and M.K. Asgarani, Producing Portland cement from iron and steel slags and limestone. Cem. Concr. Res. 29 (1999), pp. 1373–1377.10.1016/S0008-8846(99)00028-9 ↗
57. 10.1016/j.jclepro.2021.12907410.1016/j.jclepro.2021.129074 ↗
58. 10.1021/acs.inorgchem.2c0038710.1021/acs.inorgchem.2c00387 ↗
59. K. Thieme, S. Selle, L. Ortmann, and C. Thieme, Crystallization behaviour and stability of β-cristobalite in the system CaO-Al2O3-SiO2. J. Non-Cryst. Solids 668 (2025), pp. 123777.10.1016/j.jnoncrysol.2025.123777 ↗
60. A.S. Rizkalla, D.W. Jones, D.B. Clarke, and G.C. Hall, Crystallization of experimental bioactive glass compositions. J. Biomed. Mater. Res. 32 (1996), pp. 119–124.10.1002/(SICI)1097-4636(199609)32:1<119::AID-JBM14>3.0.CO;2-H ↗
61. N. Lonnroth and Y.-Z. Yue, Structural order and crystallization of an iron-rich aluminosilicate liquid under oxidizing condition. J. Non-Cryst. Solids 354 (2008), pp. 1190.10.1016/j.jnoncrysol.2006.10.082 ↗
62. A. Rafferty, R.G. Hill, and D. Wood, An investigation into the amorphous phase separation characteristics of an ionomer glass series and a sodium-boro-silicate glass system. J. Mater. Sci. 38 (2003), pp. 2311–2319.10.1023/A:1023972127593 ↗
63. 10.1016/S0008-8846(99)00128-310.1016/S0008-8846(99)00128-3 ↗
64. T.-P. Chang, J.-Y. Shih, K.-M. Yang, and T.-C. Hsiao, Material properties of Portland cement paste with nano-montmorillonite. J. Mater. Sci. 42 (2007), pp. 7478–7487.10.1007/s10853-006-1462-0 ↗
65. S. Chhaiba, M.T. Blanco-Varela, and A. Diouri, Moroccan oil Shale and Coal Waste as Alternative raw Materials in Portland Cement Clinker Manufacture. Clinkerisation Reactions and Clinker Characterisation, Consejo Superior de Investigaciones Científicas (España), 2018.
66. M. Alonso, J.R. Fernández, and J.C. Abanades, Kinetic study of belite formation in cement raw meals used in the calcium looping CO2capture process. Ind. Eng. Chem. Res. 58 (2019), pp. 5445–5454.10.1021/acs.iecr.9b00813 ↗
67. J. Zheng, S. Wei, Q. Wang, X. Li, and S. Ma, Kinetics of alite formation and ye’elimite decomposition in alite-ye’elimite cement clinker. Chem. Pap. 75 (2021), pp. 5983–5993.10.1007/s11696-021-01781-x ↗
68. 10.1016/j.tca.2011.09.00110.1016/j.tca.2011.09.001 ↗
69. H. Fang, M. Wong, and Y. Bai, Heating rate effect on the thermophysical properties of steel in fire. J. Constr. Steel Res. 128 (2017), pp. 611–617.10.1016/j.jcsr.2016.09.016 ↗
70. J. Blumm, A. Lindemann, B. Niedrig, and R. Campbell, Measurement of selected thermophysical properties of the NPL certified reference material stainless steel 310. Int. J. Thermophys. 28 (2007), pp. 674–682.10.1007/s10765-007-0177-z ↗
71. B. Lothenbach, F. Winnefeld, C. Alder, E. Wieland, and P. Lunk, Effect of temperature on the pore solution, microstructure and hydration products of Portland cement pastes. Cem. Concr. Res. 37 (2007), pp. 483–491.10.1016/j.cemconres.2006.11.016 ↗
72. 10.1016/j.jmrt.2017.05.00110.1016/j.jmrt.2017.05.001 ↗
73. O.J. Eddine, M.E. Bouchti, O. Cherkaoui, H. Hannache, and S. Gmouh, Elaboration and characterization of new phosphate glasses based on natural phosphate and red clay: Influence of the chemical composition on the chemical durability. Mediterr. J. Chem. 9 (2019), pp. 222–235.10.13171/mjc93191012614sg ↗
74. K. Racka, A. Ślawska-Waniewska, A. Krzyżewski, M. Gich, A. Roig, E.A. Shafranovsky, and Y.I. Petrov, Magnetic behaviour of Fe–Cr nanoparticle systems. J. Magn. Magn. Mater. 320 (2008), pp. e683–e687.10.1016/j.jmmm.2008.04.032 ↗
75. G. Shen, D. Jiang, F. Lin, W. Shi, X. Ma, S. Cao, and J. Zhang, Glassy magnetism in mechanically alloyed FexCr90−xMn10 (x = 18 and 35). Phys. B 366 (2005), pp. 162–167.10.1016/j.physb.2005.05.029 ↗
76. M. Romero-Perez, J.M. Rincón, C.J.R.G. Oliver, C. D’Ovidio, and D. Esparza, Magnetic properties of glasses with high iron oxide content. Mater. Res. Bull. 36 (2001), pp. 1513–1520.10.1016/S0025-5408(01)00630-4 ↗
77. P. Auric, N. Van Dang, A.K. Bandyopadhyay, and J. Zarzycki, Superparamagnetism and ferrimagnetism of the small particles of magnetite in a silicate matrix. J. Non-Cryst. Solids 50 (1982), pp. 97–106.10.1016/0022-3093(82)90203-4 ↗
78. J. Bas, J. Calero, M. Dougan, and J. Magn, Sintered soft magnetic materials. Properties and applications. J. Magn. Magn. Mater. 254–255 (2003), pp. 391–398.10.1016/S0304-8853(02)00934-4 ↗
79. W. Ding, L. Jiang, Y. Liao, J. Song, B. Li, G. Wu, and J. Magn, Effect of iron particle size and volume fraction on the magnetic properties of Fe/silicate glass soft magnetic composites. J. Magn. Magn. Mater. 378 (2015), pp. 232–238.10.1016/j.jmmm.2014.09.019 ↗
80. S.A. Abdel-Hameed and A.M. El Kady, Effect of different additions on the crystallization behavior and magnetic properties of magnetic glass–ceramic in the system Fe2O3–ZnO–CaO–SiO2. J. Adv. Res. 3 (2012), pp. 167.10.1016/j.jare.2011.07.001 ↗