Construction of Porous Organic Polymer Coordinated Palladium Nanoparticle Catalysts for Catalytic Synthesis of Coumarin Derivatives
Source abstract
Abstract
Coumarins are the backbone of numerous drugs for rare diseases, and the efficient multiphase catalytic synthesis of coumarins remains a great challenge. In this article, a dicarboxyl porous organic polymer coordinated palladium catalyst, Pd-PV-MS, was synthesized by a free radical copolymerization method. The catalyst was characterized and used in the electrophilic addition reaction of phenols and alkynoates for the synthesis of coumarin derivatives. The results demonstrated that, in most cases, high product yields could be obtained with only a small amount of the catalyst (below 2.4 mol %). The catalyst can be applied to a broad range of substrates with high catalytic performance. Moreover, the catalyst can be reused several times without loss of catalytic activity.
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Research context
OpenAlex topics: Chemical Synthesis and Reactions · Covalent Organic Framework Applications · Multicomponent Synthesis of Heterocycles
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Jiangxi Province for Environment and Energy Catalysis, School of Chemistry and Chemical Engineering, Nanchang University, Jiangxi 330031, P. R. China
School of Chemistry and Materials Science, East China University of Technology, Nanchang 330013, P. R. China
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
Funding
National Natural Science Foundation of China · Natural Science Foundation of Jiangxi Province · Key Laboratory of Nanchang City
References (42)
Show source-provided references
1. 10.1002/med.1003410.1002/med.10034 ↗
2. 10.1021/acs.chemrev.9b0014510.1021/acs.chemrev.9b00145 ↗
3. 10.1039/D1OB01876K10.1039/D1OB01876K ↗
4. 10.1016/j.tplants.2020.10.00810.1016/j.tplants.2020.10.008 ↗
5. 10.1016/j.tet.2006.04.08010.1016/j.tet.2006.04.080 ↗
6. 10.1021/ja028657310.1021/ja0286573 ↗
7. 10.1246/cl.2002.38010.1246/cl.2002.380 ↗
8. 10.1039/D1GC04564D10.1039/D1GC04564D ↗
9. 10.1055/s-2004-83482610.1055/s-2004-834826 ↗
10. 10.1007/s10311-012-0360-810.1007/s10311-012-0360-8 ↗
11. 10.2298/JSC131223027D10.2298/JSC131223027D ↗
12. 10.1021/acs.orglett.0c0228110.1021/acs.orglett.0c02281 ↗
13. 10.1246/bcsj.76.188910.1246/bcsj.76.1889 ↗
14. 10.1021/np049744710.1021/np0497447 ↗
15. 10.3724/j.issn.1000-0518.2009.09.1084108710.3724/j.issn.1000-0518.2009.09.10841087 ↗
16. 10.1246/cl.2012.70510.1246/cl.2012.705 ↗
17. 10.1002/ange.20130532610.1002/ange.201305326 ↗
18. 10.1039/C3QO00010A10.1039/C3QO00010A ↗
19. 10.1016/j.tetlet.2016.05.08710.1016/j.tetlet.2016.05.087 ↗
20. 10.1039/C8CC09785B10.1039/C8CC09785B ↗
21. 10.1039/D3OB01237A10.1039/D3OB01237A ↗
22. 10.1039/D2GC03579K10.1039/D2GC03579K ↗
23. 10.1002/anie.20201209910.1002/anie.202012099 ↗
24. 10.1021/acs.organomet.7b0064910.1021/acs.organomet.7b00649 ↗
25. 10.1039/D3MH00672G10.1039/D3MH00672G ↗
26. 10.1002/adfm.20200826510.1002/adfm.202008265 ↗
27. 10.1039/D2CY01309F10.1039/D2CY01309F ↗
28. 10.1021/accountsmr.2c0008810.1021/accountsmr.2c00088 ↗
29. 10.1016/j.ccr.2023.21519510.1016/j.ccr.2023.215195 ↗
30. 10.1039/D3SC06242B10.1039/D3SC06242B ↗
31. 10.1039/D4SC01316F10.1039/D4SC01316F ↗
32. 10.1007/s11426-024-2084-110.1007/s11426-024-2084-1 ↗
33. 10.1002/anie.20241001010.1002/anie.202410010 ↗
34. 10.1039/D4TA01716A10.1039/D4TA01716A ↗
35. 10.1016/j.carbpol.2021.11789510.1016/j.carbpol.2021.117895 ↗
36. 10.1002/aenm.20230071910.1002/aenm.202300719 ↗
37. 10.1021/jacs.4c0332010.1021/jacs.4c03320 ↗
38. 10.1038/s41467-021-22084-510.1038/s41467-021-22084-5 ↗
39. 10.1002/anie.20200961610.1002/anie.202009616 ↗
40. 10.1016/j.cej.2024.15057210.1016/j.cej.2024.150572 ↗
41. 10.1016/j.mcat.2022.11284610.1016/j.mcat.2022.112846 ↗
42. 10.1021/acsami.2c1488210.1021/acsami.2c14882 ↗