journal article·2024-09-13

Bimetallic Metal–Organic Framework-Derived Fe2O3/In2O3 Nanotubes for the Detection of Triethylamine

Changyu Duan, Nan Yang, Tao Wang, Ke Wang, Yuetong Cao, Yumin Zhang, Qingju Liu, Jin Zhang

ACS Applied Nano Materials· Volume 7· Issue 17
Publisher page

Abstract

Metal–organic frameworks (MOFs) are ideal sacrificial templates and precursors with specialized micro- and nanostructures. In this paper, bimetallic MOFs-derived Fe 2 O 3 /In 2 O 3 composites were proposed for detecting triethylamine (TEA) gas with high sensitivity and low working temperature by a simple one-step oil bath method. The samples were analyzed by XRD, SEM, TEM, and XPS for structural morphology and chemical state, and their gas performance was investigated. The findings demonstrate that Fe 2 O 3 /In 2 O 3 nanotubes exhibit remarkable sensitivity to TEA gas. The response value to 5 ppm of TEA gas is 6250 at 100 °C, which is 11.4 times higher than that of In 2 O 3 . The enhanced sensing performance can be attributed to the generation of additional chemical absorbed oxygen and the formation of heterojunctions, as evidenced by experimental and density functional theory (DFT) calculations.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Metal-Organic Frameworks: Synthesis and Applications · Advanced Chemical Sensor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Yunnan Key Laboratory for Micro/Nano Materials & Technology, National Center for International Research on Photoelectric and Energy Materials, School of Materials and Energy, Yunnan University, Kunming 650091, P. R. China

Southwest United Graduate School, Kunming 650091, P. R. China

Funding

Yunnan Key Research and Development Program · National Key Research and Development Program of China · Applied Basic Research Key Project of Yunnan Province · Young and middle-aged academic and technical leaders reserve talent project in Yunnan Province

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