Chitosan dendron-cultivated magnetic graphene oxide as novel glycodendrimer for adsorptive removal of sunset yellow from aqueous solutions
Source abstract
Abstract
This paper evaluates the adsorptive removal of sunset yellow (SY) from aqueous solutions using a new magnetic glycodendrimer (MGD). To synthesize the MGD, chitosan dendrons were cultivated on amine-functionalized magnetic graphene oxide. A number of analytical methods were employed to physicochemically characterize the synthesized MGD. Batch adsorption conditions were optimized using the Box–Behnken design. An optimized initial SY content of 633 mg/L, an optimized contact time of 33.37 min, and an optimized pH of 3.72 maximized the MGD adsorption capacity to 485 mg/g. The Langmuir isotherm was employed to describe adsorption equilibrium, while adsorption kinetics was studied via the Lagergren kinetics model. The SY adsorption onto the MGD was thermodynamically found to be spontaneous (ΔG° < 0) and exothermic (ΔH° = – 19.120 kJ/mol), leading to a decreased disorder (ΔS° = – 54.420 kJ/mol) in the solid–liquid interface. The MGD showed reusability and unique magnetic characteristics. It was concluded that the MGD could be a potential alternative for the adsorptive and magnetic removal of SY from an aqueous solution.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Dye analysis and toxicity · Adsorption and biosorption for pollutant removal · Gold and Silver Nanoparticles Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (80)
Show source-provided references
1. Abramian L, El-Rassy H (2009) Adsorption kinetics and thermodynamics of azo-dye Orange II onto highly porous titania aerogel. Chem Eng J 150(2):403–410. https://doi.org/10.1016/j.cej.2009.01.01910.1016/j.cej.2009.01.019 ↗
2. Ahmad ZU, Yao L, Wang J, Gang DD, Islam F, Lian Q, Zappi ME (2019) Neodymium embedded ordered mesoporous carbon (OMC) for enhanced adsorption of sunset yellow: Characterizations, adsorption study and adsorption mechanism. Chem Eng J 359:814–826. https://doi.org/10.1016/j.cej.2018.11.17410.1016/j.cej.2018.11.174 ↗
3. Ahmadi Y, Kim K-H (2022) Hyperbranched polymers as superior adsorbent for the treatment of dyes in water. Adv Colloid Interface Sci 302:102633. https://doi.org/10.1016/j.cis.2022.10263310.1016/j.cis.2022.102633 ↗
4. Banisheykholeslami F, Hosseini M, Najafpour Darzi G (2021) Design of PAMAM grafted chitosan dendrimers biosorbent for removal of anionic dyes: Adsorption isotherms, kinetics and thermodynamics studies. Int J Biol Macromol 177:306–316. https://doi.org/10.1016/j.ijbiomac.2021.02.11810.1016/j.ijbiomac.2021.02.118 ↗
5. Borandeh S, Abdolmaleki A, Abolmaali SS, Tamaddon AM (2018) Synthesis, structural and in-vitro characterization of β-cyclodextrin grafted L-phenylalanine functionalized graphene oxide nanocomposite: A versatile nanocarrier for pH-sensitive doxorubicin delivery. Carbohyd Polym 201:151–161. https://doi.org/10.1016/j.carbpol.2018.08.06410.1016/j.carbpol.2018.08.064 ↗
6. Chwastowski J, Staroń P, Kołoczek H, Banach M (2017) Adsorption of hexavalent chromium from aqueous solutions using Canadian peat and coconut fiber. J Mol Liq 248:981–989. https://doi.org/10.1016/j.molliq.2017.10.15210.1016/j.molliq.2017.10.152 ↗
7. de Sá FP, Cunha BN, Nunes LM (2013) Effect of pH on the adsorption of Sunset Yellow FCF food dye into a layered double hydroxide (CaAl-LDH-NO3). Chem Eng J 215–216:122–127. https://doi.org/10.1016/j.cej.2012.11.02410.1016/j.cej.2012.11.024 ↗
8. Depan D, Girase B, Shah JS, Misra RDK (2011) Structure–process–property relationship of the polar graphene oxide-mediated cellular response and stimulated growth of osteoblasts on hybrid chitosan network structure nanocomposite scaffolds. Acta Biomater 7(9):3432–3445. https://doi.org/10.1016/j.actbio.2011.05.01910.1016/j.actbio.2011.05.019 ↗
9. Einollahi Peer F, Bahramifar N, Younesi H (2018) Removal of Cd (II), Pb (II) and Cu (II) ions from aqueous solution by polyamidoamine dendrimer grafted magnetic graphene oxide nanosheets. J Taiwan Inst Chem Eng 87:225–240. https://doi.org/10.1016/j.jtice.2018.03.03910.1016/j.jtice.2018.03.039 ↗
10. Farjadian F, Ghasemi S, Heidari R, Mohammadi-Samani S (2017) In vitro and in vivo assessment of EDTA-modified silica nano-spheres with supreme capacity of iron capture as a novel antidote agent. Nanomedicine 13(2):745–753. https://doi.org/10.1016/j.nano.2016.10.01210.1016/j.nano.2016.10.012 ↗
11. Fu Y, Wang J, Liu Q, Zeng H (2014) Water-dispersible magnetic nanoparticle–graphene oxide composites for selenium removal. Carbon 77:710–721. https://doi.org/10.1016/j.carbon.2014.05.07610.1016/j.carbon.2014.05.076 ↗
12. Ghaedi M, Mosallanejad N (2014) Study of competitive adsorption of malachite green and sunset yellow dyes on cadmium hydroxide nanowires loaded on activated carbon. J Indus Eng Chem 20(3):1085–1096. https://doi.org/10.1016/j.jiec.2013.06.04610.1016/j.jiec.2013.06.046 ↗
13. Guan Q, Gao K, Ning P, Miao R, He L (2020) Value-added utilization of paper sludge: Preparing activated carbon for efficient adsorption of Cr(VI) and further hydrogenation of furfural. Sci Total Environ. https://doi.org/10.1016/j.scitotenv.2020.14026510.1016/j.scitotenv.2020.140265 ↗
14. Heidarinasab A, Ahmad Panahi H, Faramarzi M, Farjadian F (2016) Synthesis of thermosensitive magnetic nanocarrier for controlled sorafenib delivery. Mater Sci Eng, C 67:42–50. https://doi.org/10.1016/j.msec.2016.05.03610.1016/j.msec.2016.05.036 ↗
15. Hu XJ, Liu YG, Wang H, Chen AW, Zeng GM, Liu SM, Guo YM, Hu X, Li TT, Wang YQ, Zhou L, Liu SH (2013) Removal of Cu(II) ions from aqueous solution using sulfonated magnetic graphene oxide composite. Sep Purif Technol 108:189–195. https://doi.org/10.1016/j.seppur.2013.02.01110.1016/j.seppur.2013.02.011 ↗
16. Hussien NA, Işıklan N, Türk M (2018) Aptamer-functionalized magnetic graphene oxide nanocarrier for targeted drug delivery of paclitaxel. Mater Chem Phys 211:479–488. https://doi.org/10.1016/j.matchemphys.2018.03.01510.1016/j.matchemphys.2018.03.015 ↗
17. Jadval Ghadam FM, Faramarzi M, Panahi HA, Mousavi Parsa SA (2022) Glucuronic acid-conjugated smart cellulose nanocrystals as novel carrier for gemcitabine delivery. Mater Chem Phys. https://doi.org/10.1016/j.matchemphys.2022.12686210.1016/j.matchemphys.2022.126862 ↗
18. Jagtap S, Thakre D, Wanjari S, Kamble S, Labhsetwar N, Rayalu S (2009) New modified chitosan-based adsorbent for defluoridation of water. J Colloid Interface Sci 332(2):280–290. https://doi.org/10.1016/j.jcis.2008.11.08010.1016/j.jcis.2008.11.080 ↗
19. Jung MR, Horgen FD, Orski SV, Rodriguez C, Beers KL, Balazs GH, Jones TT, Work TM, Brignac KC, Royer SJ, Hyrenbach KD, Jensen BA, Lynch JM (2018) Validation of ATR FT-IR to identify polymers of plastic marine debris, including those ingested by marine organisms. Marine Pollut Bull 127:704–716. https://doi.org/10.1016/j.marpolbul.2017.12.06110.1016/j.marpolbul.2017.12.061 ↗
20. Kaur R, Goyal D, Agnihotri S (2021) Chitosan/PVA silver nanocomposite for butachlor removal: Fabrication, characterization, adsorption mechanism and isotherms. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2021.11790610.1016/j.carbpol.2021.117906 ↗
21. Kazemi E, Dadfarnia S, Haji Shabani AM, Abbasi A, Rashidian Vaziri MR, Behjat A (2016) Iron oxide functionalized graphene oxide as an efficient sorbent for dispersive micro-solid phase extraction of sulfadiazine followed by spectrophotometric and mode-mismatched thermal lens spectrometric determination. Talanta 147:561–568. https://doi.org/10.1016/j.talanta.2015.10.03310.1016/j.talanta.2015.10.033 ↗
22. Kekes T, Kolliopoulos G, Tzia C (2021) Hexavalent chromium adsorption onto crosslinked chitosan and chitosan/β-cyclodextrin beads: Novel materials for water decontamination. J Environ Chem Eng. https://doi.org/10.1016/j.jece.2021.10558110.1016/j.jece.2021.105581 ↗
23. Kuo C-Y, Wu C-H, Wu J-Y (2008) Adsorption of direct dyes from aqueous solutions by carbon nanotubes: Determination of equilibrium, kinetics and thermodynamics parameters. J Colloid Interface Sci 327(2):308–315. https://doi.org/10.1016/j.jcis.2008.08.03810.1016/j.jcis.2008.08.038 ↗
24. Lee JH, Yeo Y (2015) Controlled drug release from pharmaceutical nanocarriers. Chem Eng Sci 125:75–84. https://doi.org/10.1016/j.ces.2014.08.04610.1016/j.ces.2014.08.046 ↗
25. León O, Muñoz-Bonilla A, Soto D, Pérez D, Rangel M, Colina M, Fernández-García M (2018) Removal of anionic and cationic dyes with bioadsorbent oxidized chitosans. Carbohyd Polym 194(March):375–383. https://doi.org/10.1016/j.carbpol.2018.04.07210.1016/j.carbpol.2018.04.072 ↗
26. Li M, Liu Y, Zeng G, Liu S, Hu X, Shu D, Jiang L, Tan X, Cai X, Yan Z (2017) Tetracycline absorbed onto nitrilotriacetic acid-functionalized magnetic graphene oxide: Influencing factors and uptake mechanism. J Colloid Interface Sci 485:269–279. https://doi.org/10.1016/j.jcis.2016.09.03710.1016/j.jcis.2016.09.037 ↗
27. Lima VVC, Dalla Nora FB, Peres EC, Reis GS, Lima ÉC, Oliveira MLS, Dotto GL (2019) Synthesis and characterization of biopolymers functionalized with APTES (3-aminopropyltriethoxysilane) for the adsorption of sunset yellow dye. J Environ Chem Eng 7(5):103410. https://doi.org/10.1016/j.jece.2019.10341010.1016/j.jece.2019.103410 ↗
28. Machado TS, Crestani L, Marchezi G, Melara F, de Mello JR, Dotto GL, Piccin JS (2022) Synthesis of glutaraldehyde-modified silica/chitosan composites for the removal of water-soluble diclofenac sodium. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2021.11886810.1016/j.carbpol.2021.118868 ↗
29. Mahmoud ME, Abdelfattah AM, Tharwat RM, Nabil GM (2020) Adsorption of negatively charged food tartrazine and sunset yellow dyes onto positively charged triethylenetetramine biochar: Optimization, kinetics and thermodynamic study. J Mol Liquids 318:114297. https://doi.org/10.1016/j.molliq.2020.11429710.1016/j.molliq.2020.114297 ↗
30. Malik S, Khan A, Rahman G, Ali N, Khan H, Khan S, Sotomayor MDPT (2022) Core-shell magnetic molecularly imprinted polymer for selective recognition and detection of sunset yellow in aqueous environment and real samples. Environ Res 212:113209. https://doi.org/10.1016/j.envres.2022.11320910.1016/j.envres.2022.113209 ↗
31. Monajati M, Borandeh S, Hesami A, Mansouri D (2018) Immobilization of L -asparaginase on aspartic acid functionalized graphene oxide nanosheet : Enzyme kinetics and stability studies. Chem Eng J 354:1153–1163. https://doi.org/10.1016/j.cej.2018.08.05810.1016/j.cej.2018.08.058 ↗
32. Niu C, Zhang N, Hu C, Zhang C, Zhang H, Xing Y (2021) Preparation of a novel citric acid-crosslinked Zn-MOF/chitosan composite and application in adsorption of chromium(VI) and methyl orange from aqueous solution. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2021.11764410.1016/j.carbpol.2021.117644 ↗
33. Ortega-Aguirre S, Díaz-Nava MC, Solache-Ríos M, Muro C, Alvarado Y, García-Sánchez JJ, Pinedo-Hernández SY (2022) Effect of alginate on the removal of yellow 6 by a biopolymer-ferric zeolite composite. Separ Purific Technol 292:120971. https://doi.org/10.1016/j.seppur.2022.12097110.1016/j.seppur.2022.120971 ↗
34. Rebekah A, Sivaselvam S, Viswanathan C, Prabhu D, Gautam R, Ponpandian N (2021) Colloids and Surfaces A : Physicochemical and Engineering Aspects Magnetic nanoparticle-decorated graphene oxide-chitosan composite as an efficient nanocarrier for protein delivery. Colloids Surfaces A Physicochem Eng Aspects 610:125913. https://doi.org/10.1016/j.colsurfa.2020.12591310.1016/j.colsurfa.2020.125913 ↗
35. Roosta M, Ghaedi M, Sahraei R, Purkait MK (2015) Ultrasonic assisted removal of sunset yellow from aqueous solution by zinc hydroxide nanoparticle loaded activated carbon: Optimized experimental design. Mater Sci Eng, C 52:82–89. https://doi.org/10.1016/j.msec.2015.03.03610.1016/j.msec.2015.03.036 ↗
36. Safaviyan M, Faramarzi M, Parsa SAM, Karimi H (2022) Tetraethylenepentamine-enriched magnetic graphene oxide as a novel Cr(VI) removal adsorbent. React Funct Polymers 180:105410. https://doi.org/10.1016/j.reactfunctpolym.2022.10541010.1016/j.reactfunctpolym.2022.105410 ↗
37. Salzano de Luna M, Castaldo R, Altobelli R, Gioiella L, Filippone G, Gentile G, Ambrogi V (2017) Chitosan hydrogels embedding hyper-crosslinked polymer particles as reusable broad-spectrum adsorbents for dye removal. Carbohyd Polym 177:347–354. https://doi.org/10.1016/j.carbpol.2017.09.00610.1016/j.carbpol.2017.09.006 ↗
38. Saravanan A, Karishma S, Jeevanantham S, Jeyasri S, Kiruthika AR, Kumar PS, Yaashikaa PR (2020) Optimization and modeling of reactive yellow adsorption by surface modified Delonix regia seed: Study of nonlinear isotherm and kinetic parameters. Surfaces and Interfaces 20:100520. https://doi.org/10.1016/j.surfin.2020.10052010.1016/j.surfin.2020.100520 ↗
39. Saya L, Gautam D, Malik V, Singh WR, Hooda S (2021) Natural polysaccharide based graphene oxide nanocomposites for removal of dyes from wastewater: a review. J Chem Eng Data 66(1):11–37. https://doi.org/10.1021/acs.jced.0c0074310.1021/acs.jced.0c00743 ↗
40. Sirajudheen P, Poovathumkuzhi NC, Vigneshwaran S, Chelaveettil BM, Meenakshi S (2021) Applications of chitin and chitosan based biomaterials for the adsorptive removal of textile dyes from water — A comprehensive review. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2021.11860410.1016/j.carbpol.2021.118604 ↗
41. Soltani A, Faramarzi M, Farjadian F, Parsa SAM, Panahi HA (2022) pH-responsive glycodendrimer as a new active targeting agent for doxorubicin delivery. Int J Biol Macromol 221(September):508–522. https://doi.org/10.1016/j.ijbiomac.2022.09.03710.1016/j.ijbiomac.2022.09.037 ↗
42. Turnbull WB, Stoddart JF (2002) Design and synthesis of glycodendrimers. Rev Mol Biotechnol 90(3–4):231–255. https://doi.org/10.1016/S1389-0352(01)00062-910.1016/S1389-0352(01)00062-9 ↗
43. Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, Gholami Z, Amouzgar P (2014) Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review. Carbohyd Polym 113:115–130. https://doi.org/10.1016/j.carbpol.2014.07.00710.1016/j.carbpol.2014.07.007 ↗
44. Vasques ÉDC, Carpiné D, Dagostin JLA, Canteli AMD, Igarashi-Mafra L, Mafra MR, Scheer ADP (2014) Modelling studies by adsorption for the removal of sunset yellow azo dye present in effluent from a soft drink plant. Environ Technol 35(12):1532–1540. https://doi.org/10.1080/09593330.2013.87219710.1080/09593330.2013.872197 ↗
45. Wang G, Ma Y, Wei Z, Qi M (2016) Development of multifunctional cobalt ferrite / graphene oxide nanocomposites for magnetic resonance imaging and controlled drug delivery. Chem Eng J 289:150–160. https://doi.org/10.1016/j.cej.2015.12.07210.1016/j.cej.2015.12.072 ↗
46. Wang H, Liu Y, Zeng G, Hu X, Hu X, Li T, Li H, Wang Y, Jiang L (2014) Grafting of β-cyclodextrin to magnetic graphene oxide via ethylenediamine and application for Cr(VI) removal. Carbohyd Polym 113:166–173. https://doi.org/10.1016/j.carbpol.2014.07.01410.1016/j.carbpol.2014.07.014 ↗
47. Wawrzkiewicz M (2011) Sorption of Sunset Yellow dye by weak base anion exchanger – kinetic and equilibrium studies. Environ Technol 32(4):455–465. https://doi.org/10.1080/09593330.2010.50218810.1080/09593330.2010.502188 ↗
48. Wojtoniszak M, Chen X, Kalenczuk RJ, Wajda A, Łapczuk J, Kurzewski M, Drozdzik M, Chu PK, Borowiak-Palen E (2012) Synthesis, dispersion, and cytocompatibility of graphene oxide and reduced graphene oxide. Colloids Surfaces B Biointerfaces 89:79–85. https://doi.org/10.1016/j.colsurfb.2011.08.02610.1016/j.colsurfb.2011.08.026 ↗
49. Xu D, Kong Q, Wang X, Lou T (2022) Preparation of carboxymethyl cellulose/chitosan-CuO giant vesicles for the adsorption and catalytic degradation of dyes. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2022.11963010.1016/j.carbpol.2022.119630 ↗
50. Xue H, Gao X, Seliem MK, Mobarak M, Dong R, Wang X, Fu K, Li Q, Li Z (2023) Efficient adsorption of anionic azo dyes on porous heterostructured MXene/biomass activated carbon composites: Experiments, characterization, and theoretical analysis via advanced statistical physics models. Chem Eng J 451:138735. https://doi.org/10.1016/j.cej.2022.13873510.1016/j.cej.2022.138735 ↗
51. Yagub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: A review. Adv Coll Interface Sci 209:172–184. https://doi.org/10.1016/j.cis.2014.04.00210.1016/j.cis.2014.04.002 ↗
52. Yakout AA, Mahmoud ME (2018) Fabrication of magnetite-functionalized-graphene oxide and hexadecyltrimethyl ammonium bromide nanocomposite for efficient nanosorption of sunset yellow. Mater Sci Eng C. https://doi.org/10.1016/j.msec.2018.06.06010.1016/j.msec.2018.06.060 ↗
53. Yayayürük O, Erdem Yayayürük A, Özmen P, Karagöz B (2020) PDMAEMA grafted microspheres as an efficient adsorbent for the removal of Sunset yellow from pharmaceutical preparations, beverages and waste water. Eur Polym J 141:110089. https://doi.org/10.1016/j.eurpolymj.2020.11008910.1016/j.eurpolymj.2020.110089 ↗
54. Yin M, Li X, Liu Y, Ren X (2021) Functional chitosan/glycidyl methacrylate-based cryogels for efficient removal of cationic and anionic dyes and antibacterial applications. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2021.11812910.1016/j.carbpol.2021.118129 ↗
55. Zhu X, Li J, Luo J, Jin Y, Zheng D (2017) Removal of cadmium (II) from aqueous solution by a new adsorbent of fluor-hydroxyapatite composites. J Taiwan Inst Chem Eng 70:200–208. https://doi.org/10.1016/j.jtice.2016.10.04910.1016/j.jtice.2016.10.049 ↗
56. Ranjbari S, Ayati A, Niknam Shahrak M, Tanhaei B, Hamidi Tabrizi S (2023) Design of [BmIm] 3PW12O40 ionic liquid encapsulated-ZIF-8 nanocomposite for cationic dye adsorptive removal: modeling by response surface methodology. Indust Eng Chem Res. https://doi.org/10.1021/acs.iecr.2c0294310.1021/acs.iecr.2c02943 ↗
57. Shahinpour A, Tanhaei B, Ayati A, Beiki H, Sillanpää M (2022) Binary dyes adsorption onto novel designed magnetic clay-biopolymer hydrogel involves characterization and adsorption performance: Kinetic, equilibrium, thermodynamic, and adsorption mechanism. J Mol Liq 366:12030310.1016/j.molliq.2022.120303 ↗
58. Karimi F, Ayati A, Tanhaei B, Sanati AL, Afshar S, Kardan A, Karaman C (2022) Removal of metal ions using a new magnetic chitosan nano-bio-adsorbent; A powerful approach in water treatment. Environ Res 203:11175310.1016/j.envres.2021.111753 ↗
59. Karimi-Maleh H, Ayati A, Davoodi R, Tanhaei B, Karimi F, Malekmohammadi S, Sillanpää M (2021) Recent advances in using of chitosan-based adsorbents for removal of pharmaceutical contaminants: A review. J Clean Product 291:12588010.1016/j.jclepro.2021.125880 ↗
60. Taghavi R, Rostamnia S, Farajzadeh M, Karimi-Maleh H, Wang J, Kim D, Shokouhimehr M (2022) Magnetite metal-organic frameworks: applications in environmental remediation of heavy metals, organic contaminants, and other pollutants. Inorganic Chem 61(40):15747–1578310.1021/acs.inorgchem.2c01939 ↗
61. Alamgholiloo H, Pesyan NN, Mohammadi R, Rostamnia S, Shokouhimehr M (2021) Synergistic advanced oxidation process for the fast degradation of ciprofloxacin antibiotics using a GO/CuMOF-magnetic ternary nanocomposite. J Environ Chem Eng 9(4):10548610.1016/j.jece.2021.105486 ↗
62. Alamgholiloo H, Rostamnia S, Zhang K, Lee TH, Lee YS, Varma RS, Shokouhimehr M (2020) Boosting aerobic oxidation of alcohols via synergistic effect between TEMPO and a composite Fe3O4/Cu-BDC/GO nanocatalyst. ACS Omega 5(10):5182–519110.1021/acsomega.9b04209 ↗
63. Dolatyari L, Yaftian MR, Rostamnia S (2016) Removal of uranium (VI) ions from aqueous solutions using Schiff base functionalized SBA-15 mesoporous silica materials. J Environ Manage 169:8–1710.1016/j.jenvman.2015.12.005 ↗
64. Dolatyari L, Yaftian MR, Rostamnia S (2016) Adsorption characteristics of Eu (III) and Th (IV) ions onto modified mesoporous silica SBA-15 materials. J Taiwan Inst Chem Eng 60:174–18410.1016/j.jtice.2015.11.004 ↗
65. Dindar MH, Yaftian MR, Pilehvari M, Rostamnia S (2015) SBA-15 mesoporous materials decorated with organic ligands: use as adsorbents for heavy metal ions. J Iran Chem Soc 12:561–57210.1007/s13738-014-0513-8 ↗
66. Kadhim MM, Rheima AM, Abbas ZS, Jlood HH, Hachim SK, Kadhum WR (2023) Evaluation of a biosensor-based graphene oxide-DNA nanohybrid for lung cancer. RSC Adv 13(4):2487–250010.1039/D2RA05808A ↗
67. Smaisim GF, Abed AM, Al-Madhhachi H et al (2023) Graphene-based important carbon structures and nanomaterials for energy storage applications as chemical capacitors and supercapacitor electrodes: a review. BioNanoSci 13:219–248. https://doi.org/10.1007/s12668-022-01048-z10.1007/s12668-022-01048-z ↗
68. Abdelbasset WK, Jasim SA, Bokov DO et al (2022) Comparison and evaluation of the performance of graphene-based biosensors. Carbon Lett 32:927–951. https://doi.org/10.1007/s42823-022-00338-610.1007/s42823-022-00338-6 ↗
69. Salahdin OD, Sayadi H, Solanki R et al (2022) Graphene and carbon structures and nanomaterials for energy storage. Appl Phys A 128:703. https://doi.org/10.1007/s00339-022-05789-210.1007/s00339-022-05789-2 ↗
70. Zhang L, Han Y, Shu H, Zhang L, Han Z, Yang X, Chen Y (2022) Effect of bimetallic modification on blast furnace slag and its application in low-temperature selective catalytic reduction. J Chem Technol Biotechnol. https://doi.org/10.1002/jctb.729810.1002/jctb.7298 ↗
71. Wang Z, Liu X, Ni S, Zhuang X, Lee T (2021) Nano zero-valent iron improves anammox activity by promoting the activity of quorum sensing system. Water Res 202:117491. https://doi.org/10.1016/j.watres.2021.11749110.1016/j.watres.2021.117491 ↗
72. Liu W, Huang F, Liao Y, Zhang J, Ren G, Zhuang Z, Wang C (2008) Treatment of CrVI-Containing Mg(OH)2 Nanowaste. Angewandte Chemie (International ed.) 47(30):5619–5622. https://doi.org/10.1002/anie.20080017210.1002/anie.200800172 ↗
73. Peng X, Zheng J, Liu Q, Hu Q, Sun X, Li J, Lin Z (2021) Efficient removal of iron from red gypsum via synergistic regulation of gypsum phase transformation and iron speciation. Sci Total Environ 791:148319. https://doi.org/10.1016/j.scitotenv.2021.14831910.1016/j.scitotenv.2021.148319 ↗
74. Wang Y, Sun T, Tong L, Gao Y, Zhang H, Zhang Y, Zhu S (2023) Non-free Fe dominated PMS activation for enhancing electro-Fenton efficiency in neutral wastewater. J Electroanalyt Chem 928:117062. https://doi.org/10.1016/j.jelechem.2022.11706210.1016/j.jelechem.2022.117062 ↗
75. Zhang L, Li Y, Guo J, Kan Z, Jia Y (2023) Catalytic ozonation mechanisms of Norfloxacin using Cu–CuFe2O4. Environ Res 216:114521. https://doi.org/10.1016/j.envres.2022.11452110.1016/j.envres.2022.114521 ↗
76. Shi M, Wang R, Li L, Chen N, Xiao P, Yan C, Yan X (2022) Redox-active polymer integrated with MXene for ultra-stable and fast aqueous proton storage. Adv Fun Mater. https://doi.org/10.1002/adfm.20220977710.1002/adfm.202209777 ↗
77. Bai B, Bai F, Sun S (2023) Adsorption mechanism of shell powders on heavy metal ions Pb2+/Cd2+ and the purification efficiency for contaminated soils. Front Earth Sci. https://doi.org/10.3389/feart.2022.107122810.3389/feart.2022.1071228 ↗
78. Bai B, Rao D, Chang T, Guo Z (2019) A nonlinear attachment-detachment model with adsorption hysteresis for suspension-colloidal transport in porous media. J Hydrol (Amsterdam) 578:124080. https://doi.org/10.1016/j.jhydrol.2019.12408010.1016/j.jhydrol.2019.124080 ↗
79. Zhang Z, Yang F, Zhang H, Zhang T, Wang H, Xu Y, Ma Q (2021) Influence of CeO2 addition on forming quality and microstructure of TiCx-reinforced CrTi4-based laser cladding composite coating. Mater Character. https://doi.org/10.1016/j.matchar.2020.11073210.1016/j.matchar.2020.110732 ↗
80. Sun S, Deng P, Peng C, Ji H, Mao L, Peng L (2022) Selenium-modified chitosan induces HepG2 Cell apoptosis and differential protein analysis. Cancer Manag Res. https://doi.org/10.2147/CMAR.S38254610.2147/CMAR.S382546 ↗