Substrate effect on phonon in graphene layers
Source abstract
Abstract
Graphene exhibits high carrier mobility and concentration as well as other remarkable properties. Among them, the thermal behaviors of phonon modes play important roles in the application of optical and electronic devices. Here, A–A stacked graphene were proved well by Raman investigation on G and 2D modes. Temperature-dependent Raman scattering measurements on graphene with various number of layers on different substrates were conducted in the temperature range of 80–460 K. The first-order temperature coefficient of single layer graphene (SLG) on SiO2/Si substrate is obviously smaller than that on Cu foil, indicating that the substrate effect attributes a great impact on graphene phonon temperature dependence. The first-order temperature coefficients of multilayer graphene linearly decrease as the number of layers increases, attributed to the reduction of substrate effect in phonon behaviors, rather than to the anharmonic phonon–phonon (ph–ph) coupling or thermal expansion.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Graphene research and applications · Thermal properties of materials · 2D Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (52)
Show source-provided references
1. Balandin AA (2011) Thermal properties of graphene and nanostructured carbon materials. Nat Mater 10:56910.1038/nmat3064 ↗
2. Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197–20010.1038/nature04233 ↗
3. Morozov SV, Novoselov KS, Katsnelson MI, Schedin F, Elias DC, Jaszczak JA, Geim AK (2008) Giant intrinsic carrier mobilities in graphene and its bilayer. Phys Rev Lett 100:01660210.1103/PhysRevLett.100.016602 ↗
4. Sang M, Shin J, Kim K, Yu K-J (2009) Electronic and thermal properties of graphene and recent advances in graphene based electronics applications. Nanomaterials 9:37410.3390/nano9030374 ↗
5. Jeong HS, Kim J, Jo K, Kee J, Choi JH, Koo J et al (2021) Oriented wrinkle textures of free-standing graphene nanosheets: application as a high-performance lithium-ion battery anode. Carbon Lett 31:277–28510.1007/s42823-020-00163-9 ↗
6. Sohrabi SS, Mousavi H, Jalilvand S, Asshabi M (2021) Hydrogenation effects on the thermal and magnetic properties of mono- and bilayer graphene. Carbon Lett 31:1089–109610.1007/s42823-021-00227-4 ↗
7. Namnabat MS, Barzegar A, Barchiesi E, Javanbakht M (2021) Nonlinear buckling analysis of double-layered graphene nanoribbons based on molecular mechanics. Carbon Lett 31:895–91010.1007/s42823-020-00194-2 ↗
8. Chen Z-F, Chen X-Q, Tao L, Chen K, Long M-Z, Liu X-D, Yan K-Y et al (2018) Graphene controlled Brewster angle device for ultra broadband terahertz modulation. Nat Commun 9:490910.1038/s41467-018-07367-8 ↗
9. Mutlu Z, Jacobse PH, McCurdy RD, Llinas JP, Lin Y, Veber GC, Fischer FR, Crommie MF, Bokor J (2021) Bottom-up synthesized nanoporous graphene transistors. Adv Funct Mater 31:210379810.1002/adfm.202103798 ↗
10. Ebrahimi H, Roghani-Mamaqani H, Salami-Kalajahi M, Shahi S, Abdollahi A (2020) Chemical incorporation of epoxy-modified graphene oxide into epoxy/novolac matrix for the improvement of thermal characteristics. Carbon Lett 30:13–2210.1007/s42823-019-00065-5 ↗
11. Sierra JF, Neumann I, Cuppens J, Raes B, Costache MV, Valenzuela SO (2018) Thermoelectric spin voltage in graphene. Nat Nanotechnol 13:107–11110.1038/s41565-017-0015-9 ↗
12. Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK (2006) Raman spectrum of graphene and graphene layers. Phys Rev Lett 97:18740110.1103/PhysRevLett.97.187401 ↗
13. Calizo I, Balandin AA, Bao W, Miao F, Lau CN (2007) Temperature dependence of the Raman spectra of graphene and graphene multilayers. Nano Lett 7:645–264910.1021/nl071033g ↗
14. Yoon D, Son Y-W, Cheong H (2011) Negative thermal expansion coefficient of graphene measured by Raman spectroscopy. Nano Lett 11:3227–323110.1021/nl201488g ↗
15. Chadha N, Sharma R, Saini P (2021) A new insight into the structural modulation of graphene oxide upon chemical reduction probed by Raman spectroscopy and X-ray diffraction. Carbon Lett 31:1125–113110.1007/s42823-021-00234-5 ↗
16. Melkonyan SV (2021) Coulomb mechanism of Raman radiation in graphene. Carbon Lett 31:1051–105910.1007/s42823-020-00220-3 ↗
17. Vidano RP, Fischbach B, Willis LJ, Loehr TM (1981) Observation of Raman band shifting with excitation wavelength for carbons and graphites. Solid State Commun 39:34110.1016/0038-1098(81)90686-4 ↗
18. Havener RW, Zhuang H, Brown L, Hennig RG, Park J (2012) Angle-resolved Raman imaging of interlayer rotations and interactions in twisted bilayer graphene. Nano Lett 12:3162–316710.1021/nl301137k ↗
19. Bonini N, Lazzeri M, Marzari N, Mauri F (2007) Phonon anharmonicities in graphite and graphene. Phys Rev Lett 99:17680210.1103/PhysRevLett.99.176802 ↗
20. Liu H-N, Cong X, Lin M-L, Tan P-H (2019) The intrinsic temperature-dependent raman spectra of graphite in the temperature range from 4K to 1000K. Carbon 152:451–45810.1016/j.carbon.2019.05.016 ↗
21. Guo X, Tian Q-W, Wang Y-S, Liu J-X, Jia G-P, Dou W-D, Song F, Zhang L-J, Qin Z-J, Huang H (2022) Phonon anharmonicities in 7-armchair graphene nanoribbons. Carbon 190:312–31810.1016/j.carbon.2022.01.029 ↗
22. Efthimiopoulos I, Mayanna S, Stavrou E, Torode A, Wang Y (2020) Extracting the anharmonic properties of the G-band in graphene nanoplatelets. J Phys Chem C 124:4835–484210.1021/acs.jpcc.9b10875 ↗
23. Shi B-Y, Cao Q-J, Wang Q, Han X, Wu H-F, Chu L-Q, Fang Z-B, Huang H, Tang J-X, Dou W-D (2019) Asymmetric growth of tetragon-shaped single-crystalline graphene flakes on copper foil by annealing treatment under oxygen-free conditions. J Phys Chem C 123:2642–265010.1021/acs.jpcc.8b11897 ↗
24. Cao Q-J, Shi B-Y, Dou W-D, Tang J-X, Mao H-Y (2018) Background pressure does matter for the growth of graphene single crystal on copper foil: key roles of oxygen partial pressure. Carbon 138:458–46410.1016/j.carbon.2018.07.072 ↗
25. Horcas I, Fernández R, Gómez-Rodríguez JM, Colchero J, Gómez-Herrero J, Baro AM (2007) WSXM: a software for scanning probe microscopy and a tool for nanotechnology. Rev Sci Instrum 78:01370510.1063/1.2432410 ↗
26. Lu A-Y, Wei S-Y, Wu C-Y, Hernandez Y, Chen T-Y et al (2012) Decoupling of CVD graphene by controlled oxidation of recrystallized Cu. RSC Adv 2:3008–301310.1039/c2ra01281b ↗
27. Phan H-D, Jung J, Kim Y, Huynh VN, Lee C (2016) Large-area single-crystal graphene grown on a recrystallized Cu(111) surface by using a hole-pocket method. Nanoscale 8:13781–1378910.1039/C6NR04416F ↗
28. Akhtar S, Laoui T, Ibrahim A, Kumar AM, Ahmed J, Toor IH (2019) Few-layers graphene film and copper surface morphology for improved corrosion protection of copper. J Mater Eng Perform 28:5541–555010.1007/s11665-019-04268-9 ↗
29. Zheng H, Smith RK, Jun Y-W, Kisielowski C, Dahmen U, Paul Alivisatos A (2009) Observation of single colloidal platinum nanocrystal growth trajectories. Science 324:1309–131210.1126/science.1172104 ↗
30. Meca E, Lowengrub J, Kim H, Mattevi C, Shenoy VB (2013) Epitaxial graphene growth and shape dynamics on copper: phase-field modeling and experiments. Nano Lett 13:5692–569710.1021/nl4033928 ↗
31. Gillen R, Mohr M, Maultzsch J (2010) Raman-active modes in graphene nanoribbons. Phys Status Solidi B 247:2941–294410.1002/pssb.201000354 ↗
32. Calizo I, Ghosh S, Bao W-Z, Miao F, Lau CN, Balandin AA (2009) Raman nanometrology of graphene: temperature and substrate effects. Solid State Commun 149:1132–113510.1016/j.ssc.2009.01.036 ↗
33. Malard LM, Pimenta MA, Dresselhaus G, Dresselhaus MS (2009) Raman spectroscopy in graphene. Phys Rep 493:51–8710.1016/j.physrep.2009.02.003 ↗
34. Gupta A, Chen G, Joshi P, Tadigadapa S, Eklund PC (2006) Raman scattering from high-frequency phonons in supported n-graphene layer films. Nano Lett 6:2667–267310.1021/nl061420a ↗
35. Ogawa Y, Hu B, Orofeo CM, Tsuji M, Ikeda KI, Mizuno S, Hibino H, Ago H (2012) Domain structure and boundary in single-layer graphene grown on Cu(111) and Cu(100) films. J Phys Chem Lett 3:219–22610.1021/jz2015555 ↗
36. He R, Zhao L-Y, Petrone N, Kim KS, Roth M, Hone J, Kim P, Pasupathy A, Pinczuk A (2012) Large physisorption strain in chemical vapor deposition of graphene on copper substrates. Nano Lett 12:2408–241310.1021/nl300397v ↗
37. Zouboulis ES, Grimsditch M (1990) Raman scattering in diamond up to 1900 K. Phys Rev B 43:1249010.1103/PhysRevB.43.12490 ↗
38. Wang Y-S, Chen F-M, Guo X, Liu J-X, Jiang J-J, Zheng X-M, Wang Z-H et al (2021) In-plane phonon anisotropy and anharmonicity in exfoliated natural black arsenic. J Phys Chem Lett 12:10753–1076010.1021/acs.jpclett.1c03218 ↗
39. Papanai GS, Singh J, Sharma ND, Ansari SG, Gupta BK (2021) Temperature dependent Raman scattering of directly grown twisted bilayer graphene film using LPCVD method. Carbon 177:366–37610.1016/j.carbon.2021.02.083 ↗
40. Chen S-S, Li Q-Y, Zhang Q-M, Qu Y, Ji H-X, Ruoff RS, Cai W-W (2012) Thermal conductivity measurements of suspended graphene with and without wrinkles by micro-Raman mapping. Nanotechnology 23:36570110.1088/0957-4484/23/36/365701 ↗
41. Zhao H, Lin Y-C, Yeh CH, Tian H, Chen Y-C, Xie D, Yang Y, Suenaga K, Ren TL, Chiu PW (2014) Growth and Raman spectra of single-crystal trilayer graphene with different stacking orientations. ACS Nano 8:10766–1077310.1021/nn5044959 ↗
42. Scheitz S, Glier TE, Nweze C, Heek W, Moch I, Zierold R et al (2022) Carrier injection observed by interface-enhanced Raman scattering from topological insulators on gold substrates. ACS Appl Mater Inter 14:32625–3263310.1021/acsami.2c04380 ↗
43. Muniz AR, Maroudas D (2012) Opening and tuning of band gap by the formation of diamond superlattices in twisted bilayer graphene. Phys Rev B 86:07540410.1103/PhysRevB.86.075404 ↗
44. Jiang J-W, Tang H, Wang B-S, Su Z (2008) Raman and infrared properties and layer dependence of the phonon dispersions in multilayered graphene. Phys Rev B 77:23542110.1103/PhysRevB.77.235421 ↗
45. Gong C, Floresca HC, Hinojos D, McDonnell S, Qin X et al (2013) Rapid selective etching of PMMA residues from transferred graphene by carbon dioxide. J Phys Chem C 117:23000–2300810.1021/jp408429v ↗
46. Forster F, Molina-Sanchez A, Engels S, Epping A, Watanabe K, Taniguchi T et al (2013) Dielectric screening of the Kohn anomaly of graphene on hexagonal boron nitride. Phys Rev B 88:08541910.1103/PhysRevB.88.085419 ↗
47. Postmus C, Fzrraro JR, Mitra SS (1968) Pressure dependence of infrared eigen frequencies of KCl and KBr. Phys Rep 174:98310.1103/PhysRev.174.983 ↗
48. Tsujimoto M, Tanimura M, Tachibana M (2020) Temperature dependence of the Raman spectra of multilayer graphene nanoribbons fabricated by unzipping method. Diam Relat Mater 109:10804710.1016/j.diamond.2020.108047 ↗
49. Mohiuddin TMG, Lombardo A, Nair RR, Bonetti A, Savini G, Jalil R, Bonini N, Basko DM, Galiotis C et al (2009) Uniaxial strain in graphene by Raman spectroscopy: G peak splitting, Grüneisen parameters, and sample orientation. Phys Rev B 79:20543310.1103/PhysRevB.79.205433 ↗
50. Andres PL, Guinea F, Katsnelson MI (2012) Anharmonic effects, and thermal expansion coefficient in single-layer and multilayer graphene. Phys Rev B 86:14410310.1103/PhysRevB.86.144103 ↗
51. Tsang DKL, Marsden BJ, Fok SL, Hall G (2005) Graphite thermal expansion relationship for different temperature ranges. Carbon 43:2902–290610.1016/j.carbon.2005.06.009 ↗
52. Chen X, Tian F, Persson C, Duan W, Chen N-X (2013) Interlayer interactions in graphites. Sci Rep 3:0304610.1038/srep03046 ↗