journal article·2020-12-24

Layer-by-Layer Epitaxy of Porphyrin−Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal–Organic Framework Growth

Zishu Wang, Kai Qian, Murat Anil Öner, Peter S. Deimel, Yan Wang, Shuai Zhang, Xiaoxi Zhang, Vishal Gupta, Juan Li, Hong-Jun Gao, David A. Duncan, Johannes V. Barth, Xiao Lin, Francesco Allegretti, Shixuan Du, Carlos-Andres Palma

ACS Applied Nano Materials· Volume 3· Issue 12
Publisher page

Abstract

Precisely layered molecular heterostructures are promising but still largely unexplored materials, with the potential to complement and enhance the scope of two-dimensional heterostructures. The controlled epitaxial growth of vertically stacked molecular layers connected through tailored linkers, can lead to significant development in the field. Here, we demonstrate that sequential assembly of prototypical iron porphyrins and axial ligands can be steered via temperature-programmed desorption, and monitored by mass spectrometry and by high-resolution atomic force microscopy under ultrahigh vacuum conditions. Complementary photoelectron spectroscopy analysis delivers chemical insight into the formation of layer-by-layer nanoarchitectures. Our temperature-directed methodology outlines a promising strategy for the in vacuo fabrication of precisely stacked, multicomponent (metal–organic) molecular heterostructures.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Surface Chemistry and Catalysis · Porphyrin and Phthalocyanine Chemistry · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China

School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P.R. China

Physics Department E20, Technical University of Munich, Garching 85748, Germany

School of Physics, Beijing Institute of Technology, Beijing 100081, P.R. China

Advanced Research Institute for Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, P.R. China

CAS Key Laboratory of Vacuum Physics, Chinese Academy of Sciences, Beijing 100190, P.R. China

Diamond Light Source, Harwell Science and Innovation Campus, Didcot OX11 0QX, United Kingdom

Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany

Funding

Munich-Centre for Advanced Photonics · Deutsche Forschungsgemeinschaft · H2020 Future and Emerging Technologies · Alexander von Humboldt-Stiftung · National Natural Science Foundation of China · Chinese Academy of Sciences

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